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Author: Peitz, S. × Start date: 2010 × Type: Text × Version: publishedVersion × WGL Institute: LIKAT ×

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Now showing 1 - 4 of 4
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    [2,2-Bis(diphenylphosphanyl)propane κ2P,P0] tetracarbonylchromium(0)dichloromethane monosolvate
    (Chester : International Union of Crystallography, 2010) Peulecke, N.; Peitz, S.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, [Cr(C27H26P2)(CO) 4]·CH2Cl2, was obtained by the reaction of Ph2PCMe2PPh2 with Cr(CO)6 in refluxing toluene by substitution of two carbonyl ligands. The CrC 4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 70.27 (2)°.
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    (Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide
    (Chester : International Union of Crystallography, 2011) Peulecke, N.; Peitz, S.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, C 16H 21NP +· I -, was obtained by the reaction of PH 2PN( iPr)P(Ph)N( iPr)H with MeI involving cleavage of one of the P - N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor-acceptor N - H⋯I inter-action is observed.
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    Bis[μ-N,N'-bis(2,6-diisopropylphenyl)ethene-1,2-diamido]-1, 4(η2);1:2κ4 N:N;3:4κ4 N:N-bis(diethyl ether)-1κO,4κO-di-μ- ydrido-2: 3κ4 H:H-2,3-dichromium(II)-1,4-dilithium(I) pentane hemisolvate
    (Chester : International Union of Crystallography, 2010) Peitz, S.; Peulecke, N.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, [Cr2Li2(C26H 36N2)2(μ-H)2(C4H 10O)2]·0.5C5H12, is a binuclear chromium complex bridged by two hydrogen atoms. Each chromium atom is coordinated in a distorted square-planar geometry by one chelating bis-(2,6-diisopropyl-phen-yl) ethene-1,2-diamido ligand via its two N atoms. Additionally, two diametrically opposed lithium ether adducts coordinate in an η4 mode on the backbone of the ligands. There is a crystallographic inversion center in the middle of the Cr2H2 ring. One of the isopropyl groups is disordered over two positions in a 0.567 (7):0.433 (7) ratio. Disorder is also observed in the pentane hemisolvate molecule.
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    [Bis(diphenylphosphanyl)dimethylsilane κ2P,P′] tetracarbonylchromium(0)
    (Chester : International Union of Crystallography, 2010) Peulecke, N.; Peitz, S.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, [Cr(C26H26P2Si)(CO) 4], was obtained by the reaction of Ph2PSiMe 2PPh2 with Cr(CO)6 in refluxing toluene by ligand exchange. The CrC4P2 coordination geometry at the Cr atom is distorted octa-hedral, with a P - Cr - P bite angle of 80.27 (1)°.