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Author: Rosenthal, U. × End date: 2023 × Start date: 2020 × DDC: 540 × Has files: Yes × Type: Text × Version: publishedVersion × Subject: crystal structures ×

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Now showing 1 - 7 of 7
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    Tris(η5-cyclopentadienyl)hafnium(III)
    (Chester : International Union of Crystallography, 2011) Burlakov, V.V.; Arndt, P.; Spannenberg, A.; Rosenthal, U.
    In the crystal structure of the title compound, [Hf(C5H 5)3], three cyclopentadienyl ligands surround the Hf III atom in a trigonal-planar geometry. The molecule lies on a sixfold inversion axis.
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    (Isopropyl-amino)(meth-yl)diphenyl-phospho-nium iodide
    (Chester : International Union of Crystallography, 2011) Peulecke, N.; Peitz, S.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, C 16H 21NP +· I -, was obtained by the reaction of PH 2PN( iPr)P(Ph)N( iPr)H with MeI involving cleavage of one of the P - N bonds in diethyl ether. The two phenyl rings form a dihedral angle of 82.98 (5)°. A weak donor-acceptor N - H⋯I inter-action is observed.
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    Bis(μ2-isopropylimido-κ2 N:N)bis[(η5-cyclopentadienyl)(ethenolato-κO)titanium(IV)]
    (Chester : International Union of Crystallography, 2014) Haehnel, M.; Spannenberg, A.; Rosenthal, U.
    The title dinuclear half-sandwich complex, [CpTi(OCH=CH2) (μ2-N-iPr)]2 (Cp = cyclopentadienyl; iPr = isopropyl), was obtained from the reaction of Cp2TiCl2, n-butyllithium and isopropylamine in tetrahydrofuran. Each TiIV atom is coordinated by one Cp ligand, one vinyloxy unit and two bridging imido groups in a strongly distorted tetrahedral geometry. There are two half molecules in the asymmetric unit, such that whole molecules being generated by inversion symmetry.
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    N,P,P-Triisopropyl-phosphinic amide
    (Chester : International Union of Crystallography, 2011) Peulecke, N.; Aluri, B.R.; Müller, B.H.; Spannenberg, A.; Rosenthal, U.
    The title compound, C9H22NOP, was obtained by slow diffusion of oxygen into a toluene solution of iPr2PNHiPr. In the crystal, an inter-molecular N - H⋯O hydrogen bond occurs.
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    (μ3-Hydrido)[μ3-2-(trimethylsilyl) ethylidyne-κ3C1:C1:C1] tetrakis[(η5-cyclopentadienyl)cobalt(II)]
    (Chester : International Union of Crystallography, 2013) Haehnel, M.; Spannenberg, A.; Rosenthal, U.
    In the title compound, [Co4(C5H5) 4(μ3-CCH2SiMe3)(μ3-H)], the Co atoms form a distorted tetrahedron with the ethylidyne moiety bridging three of the Co atoms as well as the hydrido ligand also bridging three of the Co atoms. The Co-Co bond lengths in the Co4tetrahedron vary from 2.3844 (4) to 2.4608 (4) Å. Each Co atom is additionally η5-bonded to a cyclopentadienyl (Cp) anion.
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    2-Vinyl-pyridine-tris-(penta-fluoro-phen-yl)borane hexane monosolvate
    (Chester : International Union of Crystallography, 2012) Klahn, M.; Spannenberg, A.; Rosenthal, U.
    The title compound, C7H7N·B(C 6F5)3·C6H14, was obtained by the stoichiometric reaction of 2-vinyl-pyridine and tris-(penta-fluoro-phen-yl) borane in toluene. The formed adduct exhibits a restricted rotation along the B-N bond resulting in an asymmetry, which can be also observed in the 19F NMR spectra. The B-N distance is equivalent to the distances found for 2-methyl-pyridine and 2-ethyl-pyridine B(C6F5)3 adducts. For the final refinement, the contributions of disordered solvent mol-ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194-201; Spek (2009). Acta Cryst. D65, 148-155].
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    Tri-tert-butylphosphonium hydroxytris-(pentafluorophenyl)borate
    (Chester : International Union of Crystallography, 2012) Klahn, M.; Spannenberg, A.; Rosenthal, U.
    The ionic title compound, C12H28P+· C18HBF15O-, was obtained by the stoichiometric reaction of tBu3P, B(C6F5) 3 and water in toluene. A weak P - H⋯O hydrogen bond is observed in the crystal structure.