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- ItemResistive switching in polycrystalline YMnO3 thin films(New York, NY : American Inst. of Physics, 2014) Bogusz, A.; Müller, A.D.; Blaschke, D.; Skorupa, I.; Bürger, D.; Scholz, A.; Schmidt, O.G.; Schmidt, H.We report a unipolar, nonvolatile resistive switching in polycrystalline YMnO3 thin films grown by pulsed laser deposition and sandwiched between Au top and Ti/Pt bottom electrodes. The ratio of the resistance in the OFF and ON state is larger than 103. The observed phenomena can be attributed to the formation and rupture of conductive filaments within the multiferroic YMnO3 film. The generation of conductive paths under applied electric field is discussed in terms of the presence of grain boundaries and charged domain walls inherently formed in hexagonal YMnO3. Our findings suggest that engineering of the ferroelectric domains might be a promising route for designing and fabrication of novel resistive switching devices.
- ItemCompact SAW aerosol generator(Heidelberg : Springer, 2017) Winkler, A.; Harazim, S.; Collins, D.J.; Brünig, R.; Schmidt, H.; Menzel, S.B.In this work, we discuss and demonstrate the principle features of surface acoustic wave (SAW) aerosol generation, based on the properties of the fluid supply, the acoustic wave field and the acoustowetting phenomena. Furthermore, we demonstrate a compact SAW-based aerosol generator amenable to mass production fabricated using simple techniques including photolithography, computerized numerical control (CNC) milling and printed circuit board (PCB) manufacturing. Using this device, we present comprehensive experimental results exploring the complexity of the acoustic atomization process and the influence of fluid supply position and geometry, SAW power and fluid flow rate on the device functionality. These factors in turn influence the droplet size distribution, measured here, that is important for applications including liquid chromatography, pulmonary therapies, thin film deposition and olfactory displays.
- ItemTransport in ZnCoO thin films with stable bound magnetic polarons(New York, NY : American Inst. of Physics, 2014) Kaspar, T.; Fiedler, J.; Skorupa, I.; Bürger, D.; Schmidt, O.G.; Schmidt, H.Diluted magnetic ZnCoO films with 5 at.% Co have been fabricated by pulsed laser deposition on c-plane sapphire substrates and Schottky and Ohmic contacts have been prepared in top-top configuration. The diode current is significantly reduced after the diode has been subjected to an external magnetic field. In the reverse bias range the corresponding positive magnetoresistance is persistent and amounts to more than 1800% (50 K), 240% (30 K), and 50% (5 K). This huge magnetoresistance can be attributed to the large internal magnetic field in depleted ZnCoO with ferromagnetic exchange between stable bound magnetic polarons.
- ItemSemidiurnal solar tide differences between fall and spring transition times in the Northern Hemisphere(Göttingen : Copernicus GmbH, 2018) Conte, J.F.; Chau, J.L.; Laskar, F.I.; Stober, G.; Schmidt, H.; Brown, P.We present a study of the semidiurnal solar tide (S2) during the fall and spring transition times in the Northern Hemisphere. The tides have been obtained from wind measurements provided by three meteor radars located at Andenes (69° N, 16° E), Juliusruh (54° N, 13° E) and Tavistock (42° N, 81° W). During the fall, S2 is characterized by a sudden and pronounced decrease occurring every year and at all height levels. The spring transition also shows a decrease in S2, but not sudden and that ascends from lower to higher altitudes during an interval of ∼ 15 to 40 days. To assess contributions of different semidiurnal tidal components, we have examined a 20-year free-run simulation by the Hamburg Model of the Neutral and Ionized Atmosphere (HAMMONIA). We found that the differences exhibited by the S2 tide between equinox times are mainly due to distinct behaviors of the migrating semidiurnal and the non-migrating westward-propagating wave number 1 tidal components (SW2 and SW1, respectively). Specifically, during the fall both SW2 and SW1 decrease, while during the springtime SW2 decreases but SW1 remains approximately constant or decreases only slightly. The decrease shown by SW1 during the fall occurs later than that of SW2 and S2, which indicates that the behavior of S2 is mainly driven by the migrating component. Nonetheless, the influence of SW1 is necessary to explain the behavior of S2 during the spring. In addition, a strong shift in the phase of S2 (of SW2 in the simulations) is also observed during the fall. Our meteor radar wind measurements show more gravity wave activity in the fall than during the spring, which might be indicating that the fall decrease is partly due to interactions between SW2 and gravity waves. © 2018 Author(s).
- ItemThe global aerosol-climate model echam6.3-ham2.3 -Part 1: Aerosol evaluation(Göttingen : Copernicus GmbH, 2019) Tegen, I.; Neubauer, D.; Ferrachat, S.; Drian, C.S.-L.; Bey, I.; Schutgens, N.; Stier, P.; Watson-Parris, D.; Stanelle, T.; Schmidt, H.; Rast, S.; Kokkola, H.; Schultz, M.; Schroeder, S.; Daskalakis, N.; Barthel, S.; Heinold, B.; Lohmann, U.We introduce and evaluate aerosol simulations with the global aerosol-climate model ECHAM6.3-HAM2.3, which is the aerosol component of the fully coupled aerosol-chemistry-climate model ECHAM-HAMMOZ. Both the host atmospheric climate model ECHAM6.3 and the aerosol model HAM2.3 were updated from previous versions. The updated version of the HAM aerosol model contains improved parameterizations of aerosol processes such as cloud activation, as well as updated emission fields for anthropogenic aerosol species and modifications in the online computation of sea salt and mineral dust aerosol emissions. Aerosol results from nudged and free-running simulations for the 10-year period 2003 to 2012 are compared to various measurements of aerosol properties. While there are regional deviations between the model and observations, the model performs well overall in terms of aerosol optical thickness, but may underestimate coarse-mode aerosol concentrations to some extent so that the modeled particles are smaller than indicated by the observations. Sulfate aerosol measurements in the US and Europe are reproduced well by the model, while carbonaceous aerosol species are biased low. Both mineral dust and sea salt aerosol concentrations are improved compared to previous versions of ECHAM-HAM. The evaluation of the simulated aerosol distributions serves as a basis for the suitability of the model for simulating aerosol-climate interactions in a changing climate.
- ItemDisturbing-free determination of yeast concentration in DI water and in glucose using impedance biochips(Basel : MDPI AG, 2020) Kiani, M.; Du, N.; Vogel, M.; Raff, J.; Hübner, U.; Skorupa, I.; Bürger, D.; Schulz, S.E.; Schmidt, O.G.; Blaschke, D.; Schmidt, H.Deionized water and glucose without yeast and with yeast (Saccharomyces cerevisiae) of optical density OD600 that ranges from 4 to 16 has been put in the ring electrode region of six different types of impedance biochips and impedance has been measured in dependence on the added volume (20, 21, 22, 23, 24, 25 µL). The measured impedance of two out of the six types of biochips is strongly sensitive to the addition of both liquid without yeast and liquid with yeast and modelled impedance reveals a linear relationship between the impedance model parameters and yeast concentration. The presented biochips allow for continuous impedance measurements without interrupting the cultivation of the yeast. A multiparameter fit of the impedance model parameters allows for determining the concentration of yeast (cy) in the range from cy = 3.3 × 107 to cy = 17 × 107 cells/mL. This work shows that independent on the liquid, i.e., DI water or glucose, the impedance model parameters of the two most sensitive types of biochips with liquid without yeast and with liquid with yeast are clearly distinguishable for the two most sensitive types of biochips.
- ItemThe PMIP4 contribution to CMIP6 - Part 3: The last millennium, scientific objective, and experimental design for the PMIP4 past1000 simulations(Göttingen : Copernicus GmbH, 2017) Jungclaus, J.H.; Bard, E.; Baroni, M.; Braconnot, P.; Cao, J.; Chini, L.P.; Egorova, T.; Evans, M.; Fidel González-Rouco, J.; Goosse, H.; Hurtt, G.C.; Joos, F.; Kaplan, J.O.; Khodri, M.; Klein Goldewijk, K.; Krivova, N.; Legrande, A.N.; Lorenz, S.J.; Luterbacher, J.; Man, W.; Maycock, A.C.; Meinshausen, M.; Moberg, A.; Muscheler, R.; Nehrbass-Ahles, C.; Otto-Bliesner, B.I.; Phipps, S.J.; Pongratz, J.; Rozanov, E.; Schmidt, G.A.; Schmidt, H.; Schmutz, W.; Schurer, A.; Shapiro, A.I.; Sigl, M.; Smerdon, J.E.; Solanki, S.K.; Timmreck, C.; Toohey, M.; Usoskin, I.G.; Wagner, S.; Wu, C.-J.; Leng Yeo, K.; Zanchettin, D.; Zhang, Q.; Zorita, E.The pre-industrial millennium is among the periods selected by the Paleoclimate Model Intercomparison Project (PMIP) for experiments contributing to the sixth phase of the Coupled Model Intercomparison Project (CMIP6) and the fourth phase of the PMIP (PMIP4). The past1000 transient simulations serve to investigate the response to (mainly) natural forcing under background conditions not too different from today, and to discriminate between forced and internally generated variability on interannual to centennial timescales. This paper describes the motivation and the experimental set-ups for the PMIP4-CMIP6 past1000 simulations, and discusses the forcing agents orbital, solar, volcanic, and land use/land cover changes, and variations in greenhouse gas concentrations. The past1000 simulations covering the pre-industrial millennium from 850 Common Era (CE) to 1849 CE have to be complemented by historical simulations (1850 to 2014 CE) following the CMIP6 protocol. The external forcings for the past1000 experiments have been adapted to provide a seamless transition across these time periods. Protocols for the past1000 simulations have been divided into three tiers. A default forcing data set has been defined for the Tier 1 (the CMIP6 past1000) experiment. However, the PMIP community has maintained the flexibility to conduct coordinated sensitivity experiments to explore uncertainty in forcing reconstructions as well as parameter uncertainty in dedicated Tier 2 simulations. Additional experiments (Tier 3) are defined to foster collaborative model experiments focusing on the early instrumental period and to extend the temporal range and the scope of the simulations. This paper outlines current and future research foci and common analyses for collaborative work between the PMIP and the observational communities (reconstructions, instrumental data).
- ItemIncreased static dielectric constant in ZnMnO and ZnCoO thin films with bound magnetic polarons(London : Nature Publishing Group, 2020) Vegesna, S.V.; Bhat, V.J.; Bürger, D.; Dellith, J.; Skorupa, I.; Schmidt, O.G.; Schmidt, H.A novel small signal equivalent circuit model is proposed in the inversion regime of metal/(ZnO, ZnMnO, and ZnCoO) semiconductor/Si3N4 insulator/p-Si semiconductor (MSIS) structures to describe the distinctive nonlinear frequency dependent capacitance (C-F) and conductance (G-F) behaviour in the frequency range from 50 Hz to 1 MHz. We modelled the fully depleted ZnO thin films to extract the static dielectric constant (εr) of ZnO, ZnMnO, and ZnCoO. The extracted enhancement of static dielectric constant in magnetic n-type conducting ZnCoO (εr ≥ 13.0) and ZnMnO (εr ≥ 25.8) in comparison to unmagnetic ZnO (εr = 8.3–9.3) is related to the electrical polarizability of donor-type bound magnetic polarons (BMP) in the several hundred GHz range (120 GHz for CdMnTe). The formation of donor-BMP is enabled in n-type conducting, magnetic ZnO by the s-d exchange interaction between the electron spin of positively charged oxygen vacancies Vo+ in the BMP center and the electron spins of substitutional Mn2+ and Co2+ ions in ZnMnO and ZnCoO, respectively. The BMP radius scales with the Bohr radius which is proportional to the static dielectric constant. Here we show how BMP overlap can be realized in magnetic n-ZnO by increasing its static dielectric constant and guide researchers in the field of transparent spintronics towards ferromagnetism in magnetic, n-ZnO.
- ItemNew electronic device for driving surface acoustic wave actuators(Amsterdam : Elsevier, 2009) Brünig, R.; Mensel, K.; Kunze, R.; Schmidt, H.Surface acoustic wave (SAW) actuators are driven by a high frequency signal. The frequency range for an ideal SAW-generation is usually very narrow banded and may shift depending on various environmental conditions. We present a new electronic device which self-aligns to the optimal excitation frequency within a wide range. Any kind of SAW-actuator can be used. The device continuously scans a certain frequency range and characterizes the SAW-component. The ideal excitation frequency is then determined and used to drive the SAW-device. In case of changes like loading conditions or temperature variations the device automatically readjusts to the optimal frequency and prevents possible damage of the device or actuator in case of an error. © 2009.
- ItemComplex loading and simulation of acoustic thickness shear mode resonator(Amsterdam : Elsevier, 2010) Brünig, R.; Weihnacht, M.; Guhr, G.; Schmidt, H.During the last decades thickness shear mode resonators (TSM, QCM) have been object of comprehensive research. Many approaches were made to describe the behavior and physical effects when loaded. We present a physical model that describes the TSM in the full frequency range, including overtones for a large variety of loadings (e.g. gases, liquids or solid materials). By using an automated curve fit algorithm, absolute values for the loaded material (e.g. thickness, viscosity) can be extracted. The model has been validated with a large number of experiments including liquids with complex viscosities, biomolecule interactions, electrochemisty or vacuum deposition techniques. Additionally, the appearance of layer resonances have been predicted and verified. Layer resonances are remarkable because they appear at even-numbered overtones, which have been considered to be impossible.