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- ItemGaia Early Data Release 3: Gaia photometric science alerts(Les Ulis : EDP Sciences, 2021) Hodgkin, S.T.; Harrison, D.L.; Breedt, E.; Wevers, T.; Rixon, G.; Delgado, A.; Yoldas, A.; Kostrzewa-Rutkowska, Z.; Wyrzykowski, Ł.; van Leeuwen, M.; Blagorodnova, N.; Serraller, I.; Steeghs, D.; Sullivan, M.; Szabados, L.; Szegedi-Elek, E.; Tisserand, P.; Tomasella, L.; van Velzen, S.; Whitelock, P.A; Wilson, R.W.; Campbell, H.; Young, D.R.; Eappachen, D.; Fraser, M.; Ihanec, N.; Koposov, S.E.; Kruszyńska, K.; Marton, G.; Rybicki, K.A.; Brown, A.G.A.; Burgess, P. W.; Busso, G.; Cowell, S.; De Angeli, F.; Diener, C.; Evans, D.W.; Gilmore, G.; Holland, G.; Jonker, P.G.; van Leeuwen, F.; Mignard, F.; Osborne, P.J.; Portell, J.; Prusti, T.; Richards, P.J.; Riello, M.; Seabroke, G.M.; Walton, N.A.; Ábrahám, Péter; Altavilla, G.; Baker, S.G.; Bastian, U.; O'Brien, P.; de Bruijne, J.; Butterley, T.; Carrasco, J.M.; Castañeda, J.; Clark, J.S.; Clementini, G.; Copperwheat, C.M.; Cropper, M.; Damljanovic, G.; Davidson, M.; Davis, C.J.; Dennefeld, M.; Dhillon, V.S.; Dolding, C.; Dominik, M.; Esquej, P.; Eyer, L.; Fabricius, C.; Fridman, M.; Froebrich, D.; Garralda, N.; Gomboc, A.; González-Vidal, J.J.; Guerra, R.; Hambly, N.C.; Hardy, L.K.; Holl, B.; Hourihane, A.; Japelj, J.; Kann, D.A.; Kiss, C.; Knigge, C.; Kolb, U.; Komossa, S.; Kóspál, Á.; Kovács, G.; Kun, M.; Leto, G.; Lewis, F.; Littlefair, S.P.; Mahabal, A.A.; Mundell, C.G.; Nagy, Z.; Padeletti, D.; Palaversa, L.; Pigulski, A.; Pretorius, M.L.; van Reeven, W.; Ribeiro, V.A.R.M.; Roelens, M.; Rowell, N.; Schartel, N.; Scholz, A.; Schwope, A.; Sipőcz, B.M.; Smartt, S.J.; Smith, M.D.Context. Since July 2014, the Gaia mission has been engaged in a high-spatial-resolution, time-resolved, precise, accurate astrometric, and photometric survey of the entire sky. Aims. We present the Gaia Science Alerts project, which has been in operation since 1 June 2016. We describe the system which has been developed to enable the discovery and publication of transient photometric events as seen by Gaia. Methods. We outline the data handling, timings, and performances, and we describe the transient detection algorithms and filtering procedures needed to manage the high false alarm rate. We identify two classes of events: (1) sources which are new to Gaia and (2) Gaia sources which have undergone a significant brightening or fading. Validation of the Gaia transit astrometry and photometry was performed, followed by testing of the source environment to minimise contamination from Solar System objects, bright stars, and fainter near-neighbours. Results. We show that the Gaia Science Alerts project suffers from very low contamination, that is there are very few false-positives. We find that the external completeness for supernovae, CE = 0.46, is dominated by the Gaia scanning law and the requirement of detections from both fields-of-view. Where we have two or more scans the internal completeness is CI = 0.79 at 3 arcsec or larger from the centres of galaxies, but it drops closer in, especially within 1 arcsec. Conclusions. The per-Transit photometry for Gaia transients is precise to 1% at G = 13, and 3% at G = 19. The per-Transit astrometry is accurate to 55 mas when compared to Gaia DR2. The Gaia Science Alerts project is one of the most homogeneous and productive transient surveys in operation, and it is the only survey which covers the whole sky at high spatial resolution (subarcsecond), including the Galactic plane and bulge. © S. T. Hodgkin et al. 2021.
- ItemExpansion of the (BB)Ru metallacycle with coinage metal cations: Formation of B-M-Ru-B (M = Cu, Ag, Au) dimetalacyclodiboryls(Cambridge : Royal Society of Chemistry, 2018) Eleazer, B.J.; Smith, M.D.; Popov, A.A.; Peryshkov, D.V.In this work, we introduce a novel approach for the selective assembly of heterometallic complexes by unprecedented coordination of coinage metal cations to strained single ruthenium-boron bonds on a surface of icosahedral boron clusters. M(i) cations (M = Cu, Ag, and Au) insert into B-Ru bonds of the (BB)-carboryne complex of ruthenium with the formation of four-membered B-M-Ru-B metalacycles. Results of theoretical calculations suggest that bonding within these metalacycles can be best described as unusual three-center-two-electron B-M⋯Ru interactions that are isolobal to B-H⋯Ru borane coordination for M = Cu and Ag, or the pairs of two-center-two electron B-Au and Au-Ru interactions for M = Au. These transformations comprise the first synthetic route to exohedral coinage metal boryl complexes of icosahedral closo-{C2B10} clusters, which feature short Cu-B (2.029(2) Å) and Ag-B (2.182(3) Å) bonds and the shortest Au-B bond (2.027(2) Å) reported to date. The reported heterometallic complexes contain Cu(i) and Au(i) centers in uncharacteristic square-planar coordination environments. These findings pave the way to rational construction of a broader class of multimetallic architectures featuring M-B bonds.
- ItemStructural and luminescence imaging and characterisation of semiconductors in the scanning electron microscope(Bristol : IOP Publ., 2020) Trager-Cowan, C.; Alasmari, A.; Avis, W.; Bruckbauer, J.; Edwards, P.R.; Ferenczi, G.; Hourahine, B.; Kotzai, A.; Kraeusel, S.; Kusch, G.; Martin, R.W.; McDermott, R.; Naresh-Kumar, G.; Nouf-Allehiani, M.; Pascal, E.; Thomson, D.; Vespucci, S.; Smith, M.D.; Parbrook, P.J.; Enslin, J.; Mehnke, F.; Kuhn, C.; Wernicke, T.; Kneissl, M.; Hagedorn, S.; Knauer, A.; Walde, S.; Weyers, M.; Coulon, P.-M.; Shields, P.A.; Bai, J.; Gong, Y.; Jiu, L.; Zhang, Y.; Smith, R.M.; Wang, T.; Winkelmann, A.The scanning electron microscopy techniques of electron backscatter diffraction (EBSD), electron channelling contrast imaging (ECCI) and cathodoluminescence (CL) hyperspectral imaging provide complementary information on the structural and luminescence properties of materials rapidly and non-destructively, with a spatial resolution of tens of nanometres. EBSD provides crystal orientation, crystal phase and strain analysis, whilst ECCI is used to determine the planar distribution of extended defects over a large area of a given sample. CL reveals the influence of crystal structure, composition and strain on intrinsic luminescence and/or reveals defect-related luminescence. Dark features are also observed in CL images where carrier recombination at defects is non-radiative. The combination of these techniques is a powerful approach to clarifying the role of crystallography and extended defects on a material's light emission properties. Here we describe the EBSD, ECCI and CL techniques and illustrate their use for investigating the structural and light emitting properties of UV-emitting nitride semiconductor structures. We discuss our investigations of the type, density and distribution of defects in GaN, AlN and AlGaN thin films and also discuss the determination of the polarity of GaN nanowires. © 2020 The Author(s). Published by IOP Publishing Ltd.