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- ItemCrystal structure of tricarbonyl(N-diphenylphosphanyl-N,N'-diisopropyl-P-phenylphosphonous diamide-κ2 P,P')cobalt(I) tetracarbonylcobaltate(-I) toluene 0.25-solvate(Chester : International Union of Crystallography, 2014) Dura, L.; Spannenberg, A.; Beweries, T.The asymmetric unit of the title compound, [Co(C24H30N2P2)(CO)3][Co(CO)4]·0.25C7H8, consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene molecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the CoI atom, which displays a distorted trigonal-bipyramidal coordination geometry. Weak interionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)4]- anions.
- ItemCrystal structure of (1S, 2R,4S)-1-((phenylamino)methyl)-4-(prop-1-en-2-yl) cyclohexane-1,2-diol), C16H23NO2(Heidelberg : Springer, 2011) Outouch, R.; Boualy, B.; El Firdoussi, L.; Ali, M.A.; Rizzoli, C.; Spannenberg, A.C16H23NO2, orthorhombic, P2 12121 (no. 19), a = 5.9637(3) Å, b = 8.8317(5) Å, c = 27.809(1) Å, V = 1464.7 Å3, Z = 4, Rgt(F) = 0.026, wRref(F2) = 0.040, T= 150 K.