2 results
Search Results
Now showing 1 - 2 of 2
- ItemPolymeric Coatings for AR-Glass Fibers in Cement-Based Matrices: Effect of Nanoclay on the Fiber-Matrix Interaction(Basel : MDPI, 2021) Bompadre, Francesca; Scheffler, Christina; Utech, Toni; Donnini, JacopoPolymeric coatings are widely used to enhance the load bearing capacity and chemical durability of alkali-resistant glass (AR-glass) textile in cement-based composites. The contact zone between coated yarns and concrete matrix plays a major role to enable the stress transfer and has still to be improved for the full exploitation of the mechanical behavior of the composite. As a new approach, this paper studies how the addition of nanoclay particles in the polymer coating formulation can increase the chemical bond between organic coating and inorganic matrix. This includes the description of the water-based coating preparation by dispersing sodium montmorillonites, whereby the resulting coating nanostructure is characterized by X-ray diffraction and energy dispersive X-ray spectroscopy. Single glass fibers were treated by dip-coating. Atomic force microscopy was used to determine the surface roughness, and the effect on the fiber tensile properties was studied. Moreover, the morphological and chemical characteristics of the coatings were compared with the results obtained from single fiber pull-out (SFPO) tests. It was shown that the incorporation of nanoclays leads to increased interfacial shear strength arising from the ability of nanoclay particles to nucleate hydration products in the fiber-matrix contact zone.
- ItemInductive heating using a high-magnetic-field pulse to initiate chemical reactions to generate composite materials(Basel : MDPI, 2019) Zimmerer, Cordelia; Salazar Mejia, Catalina; Utech, Toni; Arnhold, Kerstin; Janke, Andreas; Wosnitza, JoachimInduction heating is efficient, precise, cost-effective, and clean. The heating process is coupled to an electrically conducting material, usually a metal. As most polymers are dielectric and non-conducting, induction heating is not applicable. In order to transfer energy from an electromagnetic field into polymer induction structures, conducting materials or materials that absorb the radiation are required. This report gives a brief overview of induction heating processes used in polymer technology. In contrast to metals, most polymer materials are not affected by electromagnetic fields. However, an unwanted temperature rise of the polymer can occur when a radio frequency field is applied. The now available high-field magnetic sources provide a new platform for induction heating at very low frequencies, avoiding unwanted thermal effects within the material. Using polycarbonate and octadecylamine as an example, it is demonstrated that induction heating performed by a magnetic-field pulse with a maximum flux density of 59 T can be used to initiate chemical reactions. A 50 nm thick Ag loop, with a mean diameter of 7 mm, placed in the polymer-polymer interface acts as susceptor and a resistive heating element. The formation of urethane as a linker compound was examined by infrared spectroscopic imaging and differential scanning calorimetry.