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- ItemHighly Efficient and Atom Economic Route for the Production of Methyl Acrylate and Acetic Acid from a Biorefinery Side Stream(Washington, DC : American Chemical Society, 2020) El Ouahabi F.; Polyakov M.; Van Klink G.P.M.; Wohlrab S.; Tin S.; De Vries J.G.We report a highly efficient and 100% atom economic synthesis of methyl acrylate and acetic acid via gas phase pyrolysis of methyl 3-acetoxypropionate at 600 °C. The latter can be produced in a single step from methyl levulinate, a side product of Avantium's FDCA process. Copyright © 2020 American Chemical Society.