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    Optical Spectrometry to Determine Nutrient Concentrations and other Physicochemical Parameters in Liquid Organic Manures: A Review
    (Basel : MDPI, 2022) Horf, Michael; Vogel, Sebastian; Drücker, Harm; Gebbers, Robin; Olfs, Hans-Werner
    Nutrient concentrations in livestock manures and biogas digestates show a huge variability due to disparities in animal husbandry systems concerning animal species, feed composition, etc. Therefore, a nutrient estimation based on recommendation tables is not reliable when the exact chemical composition is needed. The alternative, to analyse representative fertilizer samples in a standard laboratory, is too time-and cost-intensive to be an accepted routine method for farmers. However, precise knowledge about the actual nutrient concentrations in liquid organic fertilizers is a prerequisite to ensure optimal nutrient supply for growing crops and on the other hand to avoid environmental problems caused by overfertilization. Therefore, spectrometric methods receive increasing attention as fast and low-cost alternatives. This review summarizes the present state of research based on optical spectrometry used at laboratory and field scale for predicting several parameters of liquid organic manures. It emphasizes three categories: (1) physicochemical parameters, e.g., dry matter, pH, and electrical conductivity; (2) main plant nutrients, i.e., total nitrogen, ammonium nitrogen, phosphorus, potassium, magnesium, calcium, and sulfur; and (3) micronutrients, i.e., manganese, iron, copper, and zinc. Furthermore, the commonly used sample preparation techniques, spectrometer types, measuring modes, and chemometric methods are presented. The primarily promising scientific results of the last 30 years contributed to the fact that near-infrared spectrometry (NIRS) was established in commercial laboratories as an alternative method to wet chemical standard methods. Furthermore, companies developed technical setups using NIRS for on-line applications of liquid organic manures. Thus, NIRS seems to have evolved to a competitive measurement procedure, although parts of this technique still need to be improved to ensure sufficient accuracy, especially in quality management.
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    Bibliometric Analysis of Soil and Landscape Stability, Sensitivity and Resistivity
    (Basel : MDPI, 2022) Bettoni, Manuele; Maerker, Michael; Bosino, Alberto; Schillaci, Calogero; Vogel, Sebastian
    In times of global change, it is of fundamental importance to understand the sensitivity, stability and resistivity of a landscape or ecosystem to human disturbance. Landscapes and ecosystems have internal thresholds, giving them the ability to resist such disturbance. When these thresholds are quantified, the development of countermeasures can help prevent irreversible changes and support adaptations to the negative effects of global change. The main objective of this analysis is to address the lack of recent studies defining terms like sensitivity, resistivity and stability in reference to landscapes and ecosystems through a Bibliometric analysis based on Scopus and Web of Science peer-reviewed articles. The present research also aims to quantify landscape statuses in terms of their sensitivity, stability and resistivity. The term “landscape stability” is mainly related to quantitatively measurable properties indicating a certain degree of stability. In contrast, the term “landscape sensitivity” is often related to resilience; however, this definition has not substantially changed over time. Even though a large number of quantification methods related to soil and landscape stability and sensitivity were found, these methods are rather ad hoc. This study stresses the importance of interdisciplinary studies and work groups.