2018, Zhang, Zeyu, Kruschwitz, Sabine, Weller, Andreas, Halisch, Matthias

We investigate the pore space of rock samples with respect to different petrophysical parameters using various methods, which provide data on pore size distributions, including micro computed tomography (μ-CT), mercury intrusion porosimetry (MIP), nuclear magnetic resonance (NMR), and spectral-induced polarization (SIP). The resulting cumulative distributions of pore volume as a function of pore size are compared. Considering that the methods differ with regard to their limits of resolution, a multiple-length-scale characterization of the pore space is proposed, that is based on a combination of the results from all of these methods. The approach is demonstrated using samples of Bentheimer and Röttbacher sandstone. Additionally, we compare the potential of SIP to provide a pore size distribution with other commonly used methods (MIP, NMR). The limits of resolution of SIP depend on the usable frequency range (between 0.002 and 100 Hz). The methods with similar resolution show a similar behavior of the cumulative pore volume distribution in the overlapping pore size range. We assume that μ-CT and NMR provide the pore body size while MIP and SIP characterize the pore throat size. Our study shows that a good agreement between the pore radius distributions can only be achieved if the curves are adjusted considering the resolution and pore volume in the relevant range of pore radii. The MIP curve with the widest range in resolution should be used as reference.

2021, Martin, Tina, Günther, Thomas, Weller, Andreas, Kuhn, Kerstin

Historical slag dumps are of increasing interest due to economic, environmental or archaeological reasons. Geophysical investigations can help accessing the potential reuse of slag material to recover metallic raw material or for the estimation of the hazard potential of the buried slag material due to dissolution occurrence. In our study, we have investigated various slag material in the laboratory with the spectral induced polarization (SIP) method, obtained from different historical slag dumps, located in the Harz Mountains, Germany. We also present SIP results from field measurements at a historical slag dump where most of the slag samples reveal high amounts of iron, zinc, silica, and barium. Our results reveal a discrimination between three different slag grades (low, medium, high) by using the imaginary conductivity σ″ at a medium frequency (1–10 Hz) in both laboratory and field. Furthermore, additional information is obtained by a classification based on the spectral polarization behaviour and considering the field frequency range (0.1 Hz – 100 Hz). Five different types of spectra (ascending, descending, constant, maximum and minimum type) can be discriminated and recognized in the laboratory and in distinct areas of the slag dump. Even though a direct comparison between the laboratory and field results still needs to be proven, the buried slag material can be differentiated from the surrounding material by the polarization magnitude.