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    A Giant Bulk-Type Dresselhaus Splitting with 3D Chiral Spin Texture in IrBiSe
    (Weinheim : Wiley-VCH, 2020) Liu, Zhonghao; Thirupathaiah, Setti; Yaresko, Alexander N.; Kushwaha, Satya; Gibson, Quinn; Xia, Wei; Guo, Yanfeng; Shen, Dawei; Cava, Robert J.; Borisenko, Sergey V.
    Materials with giant spin splitting are desired for spintronic applications. The fabrications of spintronic devices from half metals with one spin direction are often hampered, however, by stray magnetic fields, domain walls, short spin coherence times, scattering on magnetic atoms or magnetically active interfaces, and other characteristics that come along with the magnetism. The surfaces of topological insulators, or Dirac/Weyl semimetals, could be an alternative, but production of high-quality thin films without the presence of the bulk states at the Fermi energy remains very challenging. Here, by utilizing angle-resolved photoemission spectroscopy, a record-high Dresselhaus spin–orbit splitting of the bulk state in the nonmagnetic IrBiSe is found. The band structure calculations indicate that the splitting band is fully spin-polarized with 3D chiral spin texture. As a source of spin-polarized electrons, lightly doped IrBiSe is expected to generate electric-field-controlled spin-polarized currents, free from back scattering, and could host triplet and Fulde–Ferrel–Larkin–Ovchinnikov (FFLO) superconductivity. © 2020 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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    Tunable positions of Weyl nodes via magnetism and pressure in the ferromagnetic Weyl semimetal CeAlSi
    ([London] : Nature Publishing Group UK, 2024) Cheng, Erjian; Yan, Limin; Shi, Xianbiao; Lou, Rui; Fedorov, Alexander; Behnami, Mahdi; Yuan, Jian; Yang, Pengtao; Wang, Bosen; Cheng, Jin-Guang; Xu, Yuanji; Xu, Yang; Xia, Wei; Pavlovskii, Nikolai; Peets, Darren C.; Zhao, Weiwei; Wan, Yimin; Burkhardt, Ulrich; Guo, Yanfeng; Li, Shiyan; Felser, Claudia; Yang, Wenge; Büchner, Bernd
    The noncentrosymmetric ferromagnetic Weyl semimetal CeAlSi with simultaneous space-inversion and time-reversal symmetry breaking provides a unique platform for exploring novel topological states. Here, by employing multiple experimental techniques, we demonstrate that ferromagnetism and pressure can serve as efficient parameters to tune the positions of Weyl nodes in CeAlSi. At ambient pressure, a magnetism-facilitated anomalous Hall/Nernst effect (AHE/ANE) is uncovered. Angle-resolved photoemission spectroscopy (ARPES) measurements demonstrated that the Weyl nodes with opposite chirality are moving away from each other upon entering the ferromagnetic phase. Under pressure, by tracing the pressure evolution of AHE and band structure, we demonstrate that pressure could also serve as a pivotal knob to tune the positions of Weyl nodes. Moreover, multiple pressure-induced phase transitions are also revealed. These findings indicate that CeAlSi provides a unique and tunable platform for exploring exotic topological physics and electron correlations, as well as catering to potential applications, such as spintronics.
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    Dispersibility of vapor phase oxygen and nitrogen functionalized multi-walled carbon nanotubes in various organic solvents
    (London : Nature Publishing Group, 2016) Khazaee, Maryam; Xia, Wei; Lackner, Gerhard; Mendes, Rafael G.; Rümmeli, Mark; Muhler, Martin; Lupascu, Doru C.
    The synthesis and characterization of gas phase oxygen- and nitrogen-functionalized multi-walled carbon nanotubes (OMWCNTs and NMWCNTs) and the dispersibility of these tubes in organic solvents were investigated. Recently, carbon nanotubes have shown supreme capacity to effectively enhance the efficiency of organic solar cells (OSCs). A critical challenge is to individualize tubes from their bundles in order to provide homogenous nano-domains in the active layer of OSCs. OMWCNTs and NMWCNTs were synthesized via HNO3 vapor and NH3 treatments, respectively. Surface functional groups and the structure of the tubes were analyzed by temperature-programmed desorption, Fourier transform infrared spectroscopy, transmission electron microscopy, and Raman spectroscopy which confirmed the formation of functional groups on the tube surface and the enhancement of surface defects. Elemental analysis demonstrated that the oxygen and nitrogen content increased with increasing treatment time of the multi-walled carbon nanotube (MWCNT) in HNO3 vapor. According to ultra-violet visible spectroscopy, modification of the MWCNT increased the extinction coefficients of the tubes owing to enhanced compatibility of the functionalized tubes with organic matrices.