Search Results
Artificial micro-cinderella based on self-propelled micromagnets for the active separation of paramagnetic particles
2013, Zhao, G., Wang, H., Sanchez, S., Schmidt, O.G., Pumera, M.
In this work, we will show that ferromagnetic microjets can pick-up paramagnetic beads while not showing any interaction with diamagnetic silica microparticles for the active separation of microparticles in solution.
Poisoning of bubble propelled catalytic micromotors: The chemical environment matters
2013, Zhao, G., Sanchez, S., Schmidt, O.G., Pumera, M.
Self-propelled catalytic microjets have attracted considerable attention in recent years and these devices have exhibited the ability to move in complex media. The mechanism of propulsion is via the Pt catalysed decomposition of H2O2 and it is understood that the Pt surface is highly susceptible to poisoning by sulphur-containing molecules. Here, we show that important extracellular thiols as well as basic organic molecules can significantly hamper the motion of catalytic microjet engines. This is due to two different mechanisms: (i) molecules such as dimethyl sulfoxide can quench the hydroxyl radicals produced at Pt surfaces and reduce the amount of oxygen gas generated and (ii) molecules containing -SH, -SSR, and -SCH3 moieties can poison the catalytically active platinum surface, inhibiting the motion of the jet engines. It is essential that the presence of such molecules in the environment be taken into consideration for future design and operation of catalytic microjet engines. We show this effect on catalytic micromotors prepared by both rolled-up and electrodeposition approaches, demonstrating that such poisoning is universal for Pt catalyzed micromotors. We believe that our findings will contribute significantly to this field to develop alternative systems or catalysts for self-propulsion when practical applications in the real environment are considered.
Comb-calibrated solar spectroscopy through a multiplexed single-mode fiber channel
2015, Probst, R.A., Wang, L., Doerr, H.-P., Steinmetz, T., Kentischer, T.J., Zhao, G., Hänsch, T.W., Udem, T., Holzwarth, R., Schmidt, W.
We investigate a new scheme for astronomical spectrograph calibration using the laser frequency comb at the Solar Vacuum Tower Telescope on Tenerife. Our concept is based upon a single-mode fiber channel, that simultaneously feeds the spectrograph with comb light and sunlight. This yields nearly perfect spatial mode matching between the two sources. In combination with the absolute calibration provided by the frequency comb, this method enables extremely robust and accurate spectroscopic measurements. The performance of this scheme is compared to a sequence of alternating comb and sunlight, and to absorption lines from Earth's atmosphere. We also show how the method can be used for radial-velocity detection by measuring the well-explored 5 min oscillations averaged over the full solar disk. Our method is currently restricted to solar spectroscopy, but with further evolving fiber-injection techniques it could become an option even for faint astronomical targets.