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End date: 2019 × Start date: 2016 × Type: article × Sponsor: Leibniz_Fonds ×

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Now showing 1 - 6 of 6
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    A model approach for yield-zone-specific cost estimation of greenhouse gas mitigation by nitrogen fertilizer reduction
    (Basel : MDPI, 2018) Karatay, Yusuf Nadi; Meyer-Aurich, Andreas
    Nitrogen use in agriculture has been intensified to feed the growing world population, which led to concerns on environmental harms, including greenhouse gas emissions. A reduction in nitrogen fertilization can abate greenhouse gas emissions, however, it may result in crop yield penalties and, accordingly, income loss. Assessment tools are necessary to understand the dynamics of nitrogen management issues both in environmental and economic aspects and both at low and high aggregation levels. Our study presents a model approach, estimating yield-zone-specific costs of greenhouse gas mitigation by moderate reduction of mineral nitrogen fertilizer application. Comparative advantages of mitigating greenhouse gas emissions by nitrogen fertilizer reduction were simulated for five yield-zones with different soil fertility in the state of Brandenburg, Germany. The results suggest that differences in yield response to nitrogen fertilizer lead to considerable differences in greenhouse gas mitigation costs. Overall cost-efficiency of a regional greenhouse gas mitigation by nitrogen fertilizer reduction can be substantially improved, if crop and yield-zone-specific yield responses are taken into account. The output of this study shall help to design cost-efficient agro-environmental policies targeting with specific crop yield response functions at different sites.
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    Ordered states in the Kitaev-Heisenberg model: From 1D chains to 2D honeycomb
    (London : Nature Publishing Group, 2018) Agrapidis, Cliò Efthimia; van den Brink, Jeroen; Nishimoto, Satoshi
    We study the ground state of the 1D Kitaev-Heisenberg (KH) model using the density-matrix renormalization group and Lanczos exact diagonalization methods. We obtain a rich ground-state phase diagram as a function of the ratio between Heisenberg (J = cosϕ) and Kitaev (K = sinϕ) interactions. Depending on the ratio, the system exhibits four long-range ordered states: ferromagnetic-z, ferromagnetic-xy, staggered-xy, Néel-z, and two liquid states: Tomonaga-Luttinger liquid and spiral-xy. The two Kitaev points ϕ=π2 and φ=3π2 are singular. The ϕ-dependent phase diagram is similar to that for the 2D honeycomb-lattice KH model. Remarkably, all the ordered states of the honeycomb-lattice KH model can be interpreted in terms of the coupled KH chains. We also discuss the magnetic structure of the K-intercalated RuCl3, a potential Kitaev material, in the framework of the 1D KH model. Furthermore, we demonstrate that the low-lying excitations of the 1D KH Hamiltonian can be explained within the combination of the known six-vertex model and spin-wave theory.
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    Strengthening of Al-Fe3Al composites by the generation of harmonic structures
    (London : Nature Publishing Group, 2018) Shahid, R.N.; Scudino, S.
    Strengthening of alloys can be efficiently attained by the creation of harmonic structures: bimodal microstructures generated by controlled milling of the particulate precursors, which consist of coarse-grained cores embedded in a continuous fine-grained matrix. Here, we extend the concept of harmonic structures to metal matrix composites and analyze the effectiveness of such bimodal microstructures for strengthening composites consisting of a pure Al matrix reinforced with Fe3Al particles. Preferential microstructural refinement limited to the surface of the particles, where the Fe3Al phase is progressively fragmented, occurs during ball milling of the Al-Fe3Al composite powder mixtures. The refined surface becomes the continuous fine-grained matrix that encloses macro-regions with coarser reinforcing particles in the harmonic composites synthesized during subsequent powder consolidation. The generation of the bimodal microstructure has a significant influence on the strength of the harmonic composites, which exceeds that of the conventional material by a factor of 2 while retaining considerable plastic deformation. Finally, modeling of the mechanical properties indicates that the strength of the harmonic composites can be accurately described by taking into account both the volume fraction of reinforcement and the characteristic microstructural features describing the harmonic structure.
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    Measuring device for air speed in macroporous media and its application inside apple storage bins
    (Basel : MDPI, 2018) Geyer, Martin; Praeger, Ulrike; Truppel, Ingo; Scaar, Holger; Neuwald, Daniel A.; Jedermann, Reiner; Gottschalk, Klaus
    In cold storage facilities of fruit and vegetables, airflow is necessary for heat removal. The design of storage facilities influences the air speed in the surrounding of the product. Therefore, knowledge about airflow next to the product is important to plan the layout of cold stores adapted to the requirements of the products. A new sensing device (ASL, Air speed logger) is developed for omnidirectional measurement of air speed between fruit or vegetables inside storage bins or in bulk. It consists of four interconnected plastic spheres with 80 mm diameter each, adapted to the size of apple fruit. In the free space between the spheres, silicon diodes are fixed for the airflow measurement based on a calorimetric principle. Battery and data logger are mounted inside the spheres. The device is calibrated in a wind tunnel in a measuring range of 0–1.3 m/s. Air speed measurements in fruit bulks on laboratory scale and in an industrial fruit store show air speeds in gaps between fruit with high stability at different airflow levels. Several devices can be placed between stored products for determination of the air speed distribution inside bulks or bin stacks in a storage room.
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    Palladium-catalyzed synthesis of aldehydes from aryl iodides and formic acid with propylphosphonic anhydride as the activator
    (London : Nature Publishing Group, 2018) Wu, Xiao-Feng
    An interesting palladium-catalyzed carbonylative procedure for the synthesis of aromatic aldehydes from aryl iodides has been developed. By using propylphosphonic anhydride as the activator for formic acid, moderate to good yields of the corresponding aldehydes were produced with formic acid as the carbonyl and hydrogen donors. Interestingly, neither additional phosphine ligand nor inert gas protection is needed here.
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    Modulations in martensitic Heusler alloys originate from nanotwin ordering
    (London : Nature Publishing Group, 2018) Gruner, M.E.; Niemann, R.; Entel, P.; Pentcheva, R.; Rößler, U.K.; Nielsch, K.; Fähler, S.
    Heusler alloys exhibiting magnetic and martensitic transitions enable applications like magnetocaloric refrigeration and actuation based on the magnetic shape memory effect. Their outstanding functional properties depend on low hysteresis losses and low actuation fields. These are only achieved if the atomic positions deviate from a tetragonal lattice by periodic displacements. The origin of the so-called modulated structures is the subject of much controversy: They are either explained by phonon softening or adaptive nanotwinning. Here we used large-scale density functional theory calculations on the Ni2MnGa prototype system to demonstrate interaction energy between twin boundaries. Minimizing the interaction energy resulted in the experimentally observed ordered modulations at the atomic scale, it explained that a/b twin boundaries are stacking faults at the mesoscale, and contributed to the macroscopic hysteresis losses. Furthermore, we found that phonon softening paves the transformation path towards the nanotwinned martensite state. This unified both opposing concepts to explain modulated martensite.