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- ItemBiogas crops grown in energy crop rotations: Linking chemical composition and methane production characteristics(Amsterdam : Elsevier, 2016) Herrmann, Christiane; Idler, Christine; Heiermann, MonikaMethane production characteristics and chemical composition of 405 silages from 43 different crop species were examined using uniform laboratory methods, with the aim to characterise a wide range of crop feedstocks from energy crop rotations and to identify main parameters that influence biomass quality for biogas production. Methane formation was analysed from chopped and over 90 days ensiled crop biomass in batch anaerobic digestion tests without further pre-treatment. Lignin content of crop biomass was found to be the most significant explanatory variable for specific methane yields while the methane content and methane production rates were mainly affected by the content of nitrogen-free extracts and neutral detergent fibre, respectively. The accumulation of butyric acid and alcohols during the ensiling process had significant impact on specific methane yields and methane contents of crop silages. It is proposed that products of silage fermentation should be considered when evaluating crop silages for biogas production.
- ItemA European aerosol phenomenology-5: Climatology of black carbon optical properties at 9 regional background sites across Europe(Amsterdam : Elsevier, 2016) Zanatta, M.; Gysel, M.; Bukowiecki, N.; Müller, T.; Weingartner, E.; Areskoug, H.; Fiebig, M.; Yttri, K.E.; Mihalopoulos, N.; Kouvarakis, G.; Beddows, D.; Harrison, R.M.; Cavalli, F.; Putaud, J.P.; Spindler, G.; Wiedensohler, A.; Alastuey, A.; Pandolfi, M.; Sellegri, K.; Swietlicki, E.; Jaffrezo, J.L.; Baltensperger, U.; Laj, P.A reliable assessment of the optical properties of atmospheric black carbon is of crucial importance for an accurate estimation of radiative forcing. In this study we investigated the spatio-temporal variability of the mass absorption cross-section (MAC) of atmospheric black carbon, defined as light absorption coefficient (σap) divided by elemental carbon mass concentration (mEC). σap and mEC have been monitored at supersites of the ACTRIS network for a minimum period of one year. The 9 rural background sites considered in this study cover southern Scandinavia, central Europe and the Mediterranean. σap was determined using filter based absorption photometers and mEC using a thermal-optical technique. Homogeneity of the data-set was ensured by harmonization of all involved methods and instruments during extensive intercomparison exercises at the European Center for Aerosol Calibration (ECAC). Annual mean values of σap at a wavelength of 637 nm vary between 0.66 and 1.3 Mm−1 in southern Scandinavia, 3.7–11 Mm−1 in Central Europe and the British Isles, and 2.3–2.8 Mm−1 in the Mediterranean. Annual mean values of mEC vary between 0.084 and 0.23 μg m−3 in southern Scandinavia, 0.28–1.1 in Central Europe and the British Isles, and 0.22–0.26 in the Mediterranean. Both σap and mEC in southern Scandinavia and Central Europe have a distinct seasonality with maxima during the cold season and minima during summer, whereas at the Mediterranean sites an opposite trend was observed. Annual mean MAC values were quite similar across all sites and the seasonal variability was small at most sites. Consequently, a MAC value of 10.0 m2 g−1 (geometric standard deviation = 1.33) at a wavelength of 637 nm can be considered to be representative of the mixed boundary layer at European background sites, where BC is expected to be internally mixed to a large extent. The observed spatial variability is rather small compared to the variability of values in previous literature, indicating that the harmonization efforts resulted in substantially increased precision of the reported MAC. However, absolute uncertainties of the reported MAC values remain as high as ± 30–70% due to the lack of appropriate reference methods and calibration materials. The mass ratio between elemental carbon and non-light-absorbing matter was used as a proxy for the thickness of coatings around the BC cores, in order to assess the influence of the mixing state on the MAC of BC. Indeed, the MAC was found to increase with increasing values of the coating thickness proxy. This provides evidence that coatings do increase the MAC of atmospheric BC to some extent, which is commonly referred to as lensing effect.
- ItemHydrothermal carbonization (HTC): Near infrared spectroscopy and partial least-squares regression for determination of selective components in HTC solid and liquid products derived from maize silage(Amsterdam : Elsevier, 2014) Reza, M. Toufiq; Becker, Wolfgang; Sachsenheimer, Kerstin; Mumme, JanNear-infrared (NIR) spectroscopy was evaluated as a rapid method of predicting fiber components (hemicellulose, cellulose, lignin, and ash) and selective compounds of hydrochar and corresponding process liquor produced by hydrothermal carbonization (HTC) of maize silage. Several HTC reaction times and temperatures were applied and NIR spectra of both HTC solids and liquids were obtained and correlated with concentration determined from van-Soest fiber analysis, IC, and UHPLC. Partial least-squares regression was applied to calculate models for the prediction of selective substances. The model developed with the spectra had the best performance in 3–7 factors with a correlation coefficient, which varied between 0.9275–0.9880 and 0.9364–0.9957 for compounds in solid and liquid, respectively. Calculated root mean square errors of prediction (RMSEP) were 0.42–5.06 mg/kg. The preliminary results indicate that NIR, a widely applied technique, might be applied to determine chemical compounds in HTC solid and liquid.
- ItemA conceptual framework for analysing and measuring land-use intensity(Amsterdam : Elsevier, 2013) Erb, Karl-Heinz; Haberl, Helmut; Jepsen, Martin Rudbeck; Kuemmerle, Tobias; Lindner, Marcus; Müller, Daniel; Verburg, Peter H.; Reenberg, AnetteLarge knowledge gaps currently exist that limit our ability to understand and characterise dynamics and patterns of land-use intensity: in particular, a comprehensive conceptual framework and a system of measurement are lacking. This situation hampers the development of a sound understanding of the mechanisms, determinants, and constraints underlying changes in land-use intensity. On the basis of a review of approaches for studying land-use intensity, we propose a conceptual framework to quantify and analyse land-use intensity. This framework integrates three dimensions: (a) input intensity, (b) output intensity, and (c) the associated system-level impacts of land- based production (e.g. changes in carbon storage or biodiversity). The systematic development of indicators across these dimensions would provide opportunities for the systematic analyses of the trade-offs, synergies and opportunity costs of land-use intensification strategies.
- ItemCohesive detachment of an elastic pillar from a dissimilar substrate(Amsterdam : Elsevier, 2017) Fleck, Norman A.; Khaderi, Syed Nizamuddin; McMeeking, Robert M.; Arzt, EduardThe adhesion of micron-scale surfaces due to intermolecular interactions is a subject of in- tense interest spanning electronics, biomechanics and the application of soft materials to engineering devices. The degree of adhesion is sensitive to the diameter of micro-pillars in addition to the degree of elastic mismatch between pillar and substrate. Adhesion- strength-controlled detachment of an elastic circular cylinder from a dissimilar substrate is predicted using a Dugdale-type of analysis, with a cohesive zone of uniform tensile strength emanating from the interface corner. Detachment initiates when the opening of the cohesive zone attains a critical value, giving way to crack formation. When the cohe- sive zone size at crack initiation is small compared to the pillar diameter, the initiation of detachment can be expressed in terms of a critical value H c of the corner stress inten- sity. The estimated pull-offforce is somewhat sensitive to the choice of stick/slip boundary condition used on the cohesive zone, especially when the substrate material is much stiffer than the pillar material. The analysis can be used to predict the sensitivity of detachment force to the size of pillar and to the degree of elastic mismatch between pillar and sub- strate.
- ItemDatasets from a vapor diffusion mineral precipitation protocol for Dictyostelium stalks(Amsterdam : Elsevier, 2016) Eder, Magdalena; Muth, Christina; Weiss, Ingrid M.Datasets from a slow carbonate vapor diffusion and mineral precipitation protocol for Dictyostelium ECM and cellulose stalks show examples for composite materials obtained by an in vitro approach, which differs substantially from the in vivo approach reported in The Journal of Structural Biology, doi: 10.1016/j.jsb.2016.03.015 [1]. Methods for obtaining the datasets include bright field transmitted light microscopy, fluorescence microscopy, LC-PolScope birefringence microscopy, variable pressure scanning electron microscopy (VP-SEM/ESEM), and Raman imaging spectroscopy.
- ItemImpact of chars and readily available carbon on soil microbial respiration and microbial community composition in a dynamic incubation experiment(Amsterdam : Elsevier, 2016) Lanza, Giacomo; Rebensburg, Philip; Kern, Jürgen; Lentzsch, Peter; Wirth, StephanThe carbonisation of biomass and organic residues is discussed as an opportunity to store stabilised carbon compounds in soil and to reduce mineralisation and the emission of CO2. In this study, pyrolysis char (600 °C, 30 min) and hydrothermal carbonisation char (HTC char; 210 °C, 23 bar, 8 h), both derived from maize silage, were investigated in a short-term incubation experiment of soil mixtures with or without readily available carbon (glucose) in order to reveal impacts on soil microbial respiration and community composition. In contrast to pyrolysis char, the addition of HTC char increased respiration and enhanced the growth of fungi. The addition of glucose to soil-char mixtures containing either pyrolysis or HTC char induced an additional increase of respiration, but was 35% and 39% lower compared to soil-glucose mixtures, respectively, providing evidence for a negative priming effect. No significant difference was observed comparing the soil mixtures containing pyrolysis char + glucose and HTC char + glucose. The addition of glucose stimulated the growth of most microbial taxa under study, especially of Actinobacteria at the expense of fungi. Adding pyrolysis or HTC char to soil induced a decline of all microbial taxa but did not modify the microbial community structure significantly. Addition of pyrolysis or HTC char in combination with glucose however, increased the abundance of Actinobacteria and reduced the relative abundance of Acidobacteria and Betaproteobacteria while fungi were further increased in case of HTC char. We conclude that both chars hold the potential to bring about specific impacts on soil microbial activities and microbial community structure, and that they may compensate the variations induced by the addition of readily available carbon.
- ItemThe MiLA tool: Modeling greenhouse gas emissions and cumulative energy demand of energy crop cultivation in rotation(Amsterdam : Elsevier, 2016) Peter, Christiane; Specka, Xenia; Aurbacher, Joachim; Peter Kornatz, Peter Kornatz; Herrmann, Christiane; Heiermann, Monika; Müller, Janine; Nendel, ClaasCrop rotations are part of current agricultural practice, since they and their effects can contribute to a sustainable agricultural cropping system. However, in current Life Cycle Assessment (LCA) studies, crop rotation effects are insufficiently considered, since these effects are difficult to measure. LCA studies from crop production typically take only one vegetation period into account. As a result, the consideration of how the assessed crop is influenced by the previous crop (crop rotation effects) including: (1) nutrient carryover, (2) reduction in operational requirements and (3) different intensity and timing of farming activities, is outside of the system boundary. However, ignoring these effects may lead to incorrect interpretation of LCA results and consequently to poor agricultural management as well as poor policy decisions. A new LCA tool called the “Model for integrative Life Cycle Assessment in Agriculture (MiLA)” is presented in this work. MiLA has been developed to assess GHG emissions and cumulative energy demands (CED) of cropping systems by taking the characteristics of crop cultivation in rotation into account. This tool enables the user to analyze cropping systems at farm level in order to identify GHG mitigation options and energy-efficient cropping systems. The tool was applied to a case study, including two crop rotations in two different regions in Germany with the goal of demonstrating the effectiveness of this tool on LCA results. Results show that including crop rotation effects can influence the GHG emission result of the individual crop by − 34% up to + 99% and the CED by − 16 up to + 89%. Expanding the system boundary by taking the whole crop rotation into account as well as providing the results based on different functional units improves LCA of energy crop production and helps those making the assessment to draw a more realistic picture of the interactions between crops while increasing the reliability of the LCA results.
- ItemOn the process of co-deformation and phase dissolution in a hard-soft immiscible CuCo alloy system during high-pressure torsion deformation(Amsterdam : Elsevier, 2016) Bachmaier, Andrea; Schmauch, Jörg; Aboulfadl, Hisham; Verch, Andreas; Motz, ChristianIn this study, dual phase Cusingle bondCo composites with a total immiscibility in the solid state and a very different initial phase strength are deformed by severe plastic deformation. Nanocrystalline supersaturated solid solutions are reached in all Cusingle bondCo composites independent of the initial composition. The deformation and mechanical mixing process is studied thoroughly by combining scanning electron microscopy, transmission electron microscopy, three-dimensional atom probe tomography and nanoindentation. The indentation hardness of the Cu and Co phase and its evolution as a function of the applied strain is linked to deformation and mechanical mixing process to gain a better understanding how the phase strength mismatch of the Cu and Co phase effects the amount of co-deformation and deformation-induced mixing. Our results show that co-deformation is not a necessary requirement to achieve mechanical mixing.
- ItemDirect production of lactic acid based on simultaneous saccharification and fermentation of mixed restaurant food waste(Amsterdam : Elsevier, 2016) Pleissner, Daniel; Demichelis, Francesca; Mariano, Silvia; Fiore, Silvia; Gutiérrez, Ivette Michelle Navarro; Schneider, Roland; Venus, JoachimThis study introduces to a one-step process for the fermentative production of L(+)-lactic acid from mixed restaurant food waste. Food waste was used as carbon and nitrogen source in simultaneous saccharification and fermentation (SSF) using Lactobacillus sp. or Streptococcus sp. strains for L(+)-lactic acid production. Waste consisted of (w/w) 33.5% starch, 14.8% proteins, 12.9% fat and 8.5% free sugars. Lactobacillus sp. strains showed a productivity of 0.27–0.53 g L−1 h−1 and a yield of 0.07–0.14 g g−1 of theoretically available sugars, while Streptococcus sp. more efficiently degraded the food waste material and produced lactic acid at a maximum rate of 2.16 g L−1 h−1 and a yield of 0.81 g g−1. For SSF, no enzymes were added or other hydrolytic treatments were carried out. Outcomes revealed a linear relationship between lactic acid concentration and solid-to-liquid ratio when Streptococcus sp. was applied. Statistically, from a 20% (w/w) dry food waste blend 52.4 g L−1 lactic acid can be produced. Experimentally, 58 g L−1 was achieved in presence of 20% (w/w), which was the highest solid-to-liquid ratio that could be treated using the equipment applied. Irrespective if SSF was performed at laboratory or technical scale, or under non-sterile conditions, Streptococcus sp. efficiently liquefied food waste and converted the released nutrients directly into lactic acid without considerable production of other organic acids, such as acetic acid. Downstream processing including micro- and nanofiltration, electrodialysis, chromatography and distillation gave a pure 702 g L−1 L(+)-lactic acid formulation.