Search Results
Trend detection in river flow indices in Poland
2018, Piniewski, Mikołaj, Marcinkowski, Paweł, Kundzewicz, Zbigniew W.
The issue of trend detection in long time series of river flow records is of vast theoretical interest and considerable practical relevance. Water management is based on the assumption of stationarity; hence, it is crucial to check whether taking this assumption is justified. The objective of this study is to analyse long-term trends in selected river flow indices in small- and medium-sized catchments with relatively unmodified flow regime (semi-natural catchments) in Poland. The examined indices describe annual and seasonal average conditions as well as annual extreme conditions—low and high flows. The special focus is on the spatial analysis of trends, carried out on a comprehensive, representative data set of flow gauges. The present paper is timely, as no spatially comprehensive studies (i.e. covering the entire Poland or its large parts) on trend detection in time series of river flow have been done in the recent 15 years or so. The results suggest that there is a strong random component in the river flow process, the changes are weak and the spatial pattern is complex. Yet, the results of trend detection in different indices of river flow in Poland show that there exists a spatial divide that seems to hold quite generally for various indices (annual, seasonal, as well as low and high flow). Decreases of river flow dominate in the northern part of the country and increases usually in the southern part. Stations in the central part show mostly ‘no trend’ results. However, the spatial gradient is apparent only for the data for the period 1981–2016 rather than for 1956–2016. It seems also that the magnitude of increases of river flow is generally lower than that of decreases.
Formation mechanism for stable hybrid clusters of proteins and nanoparticles
2015, Moerz, Sebastian T., Kraegeloh, Annette, Chanana, Munish, Kraus, Tobias
Citrate-stabilized gold nanoparticles (AuNP) agglomerate in the presence of hemoglobin (Hb) at acidic pH. The extent of agglomeration strongly depends on the concentration ratio [Hb]/[AuNP]. Negligible agglomeration occurs at very low and very high [Hb]/[AuNP]. Full agglomeration and precipitation occur at [Hb]/[AuNP] corresponding to an Hb monolayer on the AuNP. Ratios above and below this value lead to the formation of an unexpected phase: stable, microscopic AuNP–Hb agglomerates. We investigated the kinetics of agglomeration with dynamic light scattering and the adsorption kinetics of Hb on planar gold with surface-acoustic wave-phase measurements. Comparing agglomeration and adsorption kinetics leads to an explanation of the complex behavior of this nanoparticle–protein mixture. Agglomeration is initiated either when Hb bridges AuNP or when the electrostatic repulsion between AuNP is neutralized by Hb. It is terminated when Hb has been depleted or when Hb forms multilayers on the agglomerates that stabilize microscopic clusters indefinitely.
Multiple lobes in the far-field distribution of terahertz quantum-cascade lasers due to self-interference
2016, Röben, B., Wienold, M., Schrottke, L., Grahn, H.T.
The far-field distribution of the emission intensity of terahertz (THz) quantumcascade lasers (QCLs) frequently exhibits multiple lobes instead of a single-lobed Gaussian distribution. We show that such multiple lobes can result from selfinterference related to the typically large beam divergence of THz QCLs and the presence of an inevitable cryogenic operation environment including optical windows. We develop a quantitative model to reproduce the multiple lobes. We also demonstrate how a single-lobed far-field distribution can be achieved.
Thermal annealing studies of GeTe-Sb2Te3 alloys with multiple interfaces
2017, Bragaglia, Valeria, Mio, Antonio M., Calarco, Raffaella
A high degree of vacancy ordering is obtained by annealing amorphous GeTe-Sb2Te3 (GST) alloys deposited on a crystalline substrate, which acts as a template for the crystallization. Under annealing the material evolves from amorphous to disordered rocksalt, to ordered rocksalt with vacancies arranged into (111) oriented layers, and finally converts into the stable trigonal phase. The role of the interface in respect to the formation of an ordered crystalline phase is studied by comparing the transformation stages of crystalline GST with and without a capping layer. The capping layer offers another crystallization interface, which harms the overall crystalline quality.
Changes of snow cover in Poland
2017, Szwed, Małgorzata, Pin´skwar, Iwona, Kundzewicz, Zbigniew W., Graczyk, Dariusz, Mezghani, Abdelkader
The present paper examines variability of characteristics of snow cover (snow cover depth, number of days with snow cover and dates of beginning and end of snow cover) in Poland. The study makes use of a set of 43 long time series of observation records from the stations in Poland, from 1952 to 2013. To describe temporal changes in snow cover characteristics, the intervals of 1952–1990 and of 1991–2013 are compared and trends in analysed data are sought (e.g., using the Mann–Kendall test). Observed behaviour of time series of snow-related variables is complex and not easy to interpret, for instance because of the location of the research area in the zone of transitional moderate climate, where strong variability of climate events is one of the main attributes. A statistical link between the North Atlantic Oscillation (NAO) index and the snow cover depth, as well as the number of snow cover days is found.
Label free sensing of creatinine using a 6 GHz CMOS near-field dielectric immunosensor
2015, Guha, S., Warsinke, A., Tientcheu, Ch.M., Schmalz, K., Meliani, C., Wenger, Ch.
In this work we present a CMOS high frequency direct immunosensor operating at 6 GHz (C-band) for label free determination of creatinine. The sensor is fabricated in standard 0.13 μm SiGe:C BiCMOS process. The report also demonstrates the ability to immobilize creatinine molecules on a Si3N4 passivation layer of the standard BiCMOS/CMOS process, therefore, evading any further need of cumbersome post processing of the fabricated sensor chip. The sensor is based on capacitive detection of the amount of non-creatinine bound antibodies binding to an immobilized creatinine layer on the passivated sensor. The chip bound antibody amount in turn corresponds indirectly to the creatinine concentration used in the incubation phase. The determination of creatinine in the concentration range of 0.88–880 μM is successfully demonstrated in this work. A sensitivity of 35 MHz/10 fold increase in creatinine concentration (during incubation) at the centre frequency of 6 GHz is gained by the immunosensor. The results are compared with a standard optical measurement technique and the dynamic range and sensitivity is of the order of the established optical indication technique. The C-band immunosensor chip comprising an area of 0.3 mm2 reduces the sensing area considerably, therefore, requiring a sample volume as low as 2 μl. The small analyte sample volume and label free approach also reduce the experimental costs in addition to the low fabrication costs offered by the batch fabrication technique of CMOS/BiCMOS process.
Analysis of fatty acids and triacylglycerides by Pd nanoparticle-assisted laser desorption/ionization mass spectrometry
2015, Silina, Yuliya E., Fink-Straube, Claudia, Hayen, Heiko, Volmer, Dietrich A.
In this study, we propose a simple and rapid technique for characterization of free fatty acids and triacylglycerides (TAG) based on palladium nanoparticular (Pd-NP) surface-assisted laser desorption/ionization (SALDI) mass spectrometry (MS). The implemented Pd-NP material allowed detection of free fatty acids and TAGs exclusively as [M + K]+ ions in positive ion mode. Under negative ionization conditions, unusual trimetric structures were generated for free fatty acids, while TAGs underwent irreproducible degradation reactions. Importantly, the mass spectra obtained from Pd-NP targets in positive ion mode were very clean without interferences from matrix-derived ions in the low m/z range and readily enabled the detection of intact TAGs in vegetable oils without major fragmentation reactions as compared to conventional MALDI-MS, requiring only a minimal amount of sample preparation.
What can we learn from the projections of changes of flow patterns? Results from Polish case studies
2017, Piniewski, Mikołaj, Meresa, Hadush Kidane, Romanowicz, Renata, Osuch, Marzena, Szczes´niak, Mateusz, Kardel, Ignacy, Okruszko, Tomasz, Mezghani, Abdelkader, Kundzewicz, Zbigniew W.
River flow projections for two future time horizons and RCP 8.5 scenario, generated by two projects (CHASE-PL and CHIHE) in the Polish-Norwegian Research Programme, were compared. The projects employed different hydrological models over different spatial domains. The semi-distributed, process-based, SWAT model was used in the CHASE-PL project for the entire Vistula and Odra basins area, whilst the lumped, conceptual, HBV model was used in the CHIHE project for eight Polish catchments, for which the comparison study was made. Climate projections in both studies originated from the common EURO-CORDEX dataset, but they were different, e.g. due to different bias correction approaches. Increases in mean annual and seasonal flows were projected in both studies, yet the magnitudes of changes were largely different, in particular for the lowland catchments in the far future. The HBV-based increases were significantly higher in the latter case than the SWAT-based increases in all seasons except winter. Uncertainty in projections is high and creates a problem for practitioners.
High spatial and temporal resolution cell manipulation techniques in microchannels
2016, Novo, Pedro, Dell’Aica, Margherita, Janasek, Dirk, Zahedi, René P.
The advent of microfluidics has enabled thorough control of cell manipulation experiments in so called lab on chips. Lab on chips foster the integration of actuation and detection systems, and require minute sample and reagent amounts. Typically employed microfluidic structures have similar dimensions as cells, enabling precise spatial and temporal control of individual cells and their local environments. Several strategies for high spatio-temporal control of cells in microfluidics have been reported in recent years, namely methods relying on careful design of the microfluidic structures (e.g. pinched flow), by integration of actuators (e.g. electrodes or magnets for dielectro-, acousto- and magneto-phoresis), or integrations thereof. This review presents the recent developments of cell experiments in microfluidics divided into two parts: an introduction to spatial control of cells in microchannels followed by special emphasis in the high temporal control of cell-stimulus reaction and quenching. In the end, the present state of the art is discussed in line with future perspectives and challenges for translating these devices into routine applications.
Fulleretic well-defined scaffolds: Donor–fullerene alignment through metal coordination and its effect on photophysics
2016, Williams, Derek E., Dolgopolova, Ekaterina A., Godfrey, Danielle C., Ermolaeva, Evgeniya D., Pellechia, Perry J., Greytak, Andrew B., Smith, Mark D., Avdoshenko, Stanislav M., Popov, Alexey A., Shustova, Natalia B.
Herein, we report the first example of a crystalline metal–donor–fullerene framework, in which control of the donor–fullerene mutual orientation was achieved through chemical bond formation, in particular, by metal coordination. The 13C cross‐polarization magic‐angle spinning NMR spectroscopy, X‐ray diffraction, and time‐resolved fluorescence spectroscopy were performed for comprehensive structural analysis and energy‐transfer (ET) studies of the fulleretic donor–acceptor scaffold. Furthermore, in combination with photoluminescence measurements, the theoretical calculations of the spectral overlap function, Förster radius, excitation energies, and band structure were employed to elucidate the photophysical and ET processes in the prepared fulleretic material. We envision that the well‐defined fulleretic donor–acceptor materials could contribute not only to the basic science of fullerene chemistry but would also be used towards effective development of organic photovoltaics and molecular electronics.