2017, Heintzenberg, Jost, Hermann, Markus, Weigelt, Andreas, Kapustin, Vladimir, Anderson, Bruce, Thornhill, Kenneth, Van Velthoven, Peter, Zahn, Andreas, Brenninkmeijer, Carl

This study extrapolates aerosol data of the CARIBIC project from 1997 until June 2008 in along trajectories to compose large-scale maps and vertical profiles of submicrometre particle concentrations in the upper troposphere and lowermost stratosphere (UT/LMS). The extrapolation was validated by comparing extrapolated values with CARIBIC data measured near the respective trajectory position and by comparing extrapolated CARIBIC data to measurements by other experiments near the respective trajectory positions. Best agreement between extrapolated and measured data is achieved with particle lifetimes longer than the maximum length of used trajectories. The derived maps reveal regions of strong and frequent new particle formation, namely the Tropical Central and Western Africa with the adjacent Atlantic, South America, the Caribbean and Southeast Asia. These regions of particle formation coincide with those of frequent deep convective clouds. Vertical particle concentration profiles for the troposphere and the stratosphere confirm statistically previous results indicating frequent new particle formation in the tropopause region. There was no statistically significant increase in Aitken mode particle concentration between the first period of CARIBIC operation, 1997–2002, and the second period, 2004–2009. However, a significant increase in concentration occurred within the latter period when considering it in isolation.

2000, James, P.M., Peters, D., Waugh, D.W.

The large-scale ozone distribution over the northern hemisphere undergoes strong fluctuationseach winter on timescales of up to a few weeks. This is closely linked to changes in the stratosphericpolar vortex, whose shape, intensity and location vary with time. Elliptical diagnosticparameters provide an empirical description of the daily character of the polar vortex. Theseparameters are used as an objective measure to define two characteristic wintertime vortexdisplacements, towards northern Europe and Canada, respectively. The large-scale structuresin both the stratosphere and troposphere and the 3D ozone structures are determined for bothvortex displacement scenarios. A linear ozone transport model shows that the contribution ofhorizontal ozone advection dominates locally in the middle stratosphere. Nevertheless, thelargest contribution is due to vertical advection around the ozone layer maximum. The findingsare in agreement with an EOF analysis which reveals significant general modes of ozone variabilitylinked to polar vortex displacement and to phase-shifted large-scale tropospheric waves.When baroclinic waves travel through the regions of vortex-related ozone reduction, the combinedeffect is to produce transient synoptic-scale areas of exceptionally low ozone; namelydynamically induced strong ozone mini-holes.