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Now showing 1 - 10 of 17
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    Overcoming the shortcomings of the Nernst-Planck model
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2012) Dreyer, Wolfgang; Guhlke, Clemens; Müller, Rüdiger
    This is a study on electrolytes that takes a thermodynamically consistent coupling between mechanics and diffusion into account. It removes some inherent deficiencies of the popular Nernst-Planck model. A boundary problem for equilibrium processes is used to illustrate the new features of our model.
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    Asymptotic analyses and error estimates for a Cahn-Hilliard type phase field system modelling tumor growth
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2015) Colli, Pierluigi; Gilardi, Gianni; Rocca, Elisabetta; Sprekels, Jürgen
    This paper is concerned with a phase field system of Cahn-Hilliard type that is related to a tumor growth model and consists of three equations in gianni terms of the variables order parameter, chemical potential and nutrient concentration. This system has been investigated in the recent papers citeCGH and citeCGRS gianni from the viewpoint of well-posedness, long time bhv and asymptotic convergence as two positive viscosity coefficients tend to zero at the same time. Here, we continue the analysis performed in citeCGRS by showing two independent sets of results as just one of the coefficents tends to zero, the other remaining fixed. We prove convergence results, uniqueness of solutions to the two resulting limit problems, and suitable error estimates
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    Vanishing viscosities and error estimate for a Cahn-Hilliard type phase field system related to tumor growth
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2015) Colli, Pierluigi; Gilardi, Gianni; Rocca, Elisabetta; Sprekels, Jürgen
    In this paper we perform an asymptotic analysis for two different vanishing viscosity coefficients occurring in a phase field system of Cahn--Hilliard type that was recently introduced in order to approximate a tumor growth model. In particular, we extend some recent results obtained in [Colli-Gilardi-Hilhorst 2015], letting the two positive viscosity parameters tend to zero independently from each other and weakening the conditions on the initial data in such a way as to maintain the nonlinearities of the PDE system as general as possible. Finally, under proper growth conditions on the interaction potential, we prove an error estimate leading also to the uniqueness result for the limit system.
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    Rational modeling of electrochemical double-layers and derivation of Butler-Volmer equations
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2013) Dreyer, Wolfgang; Guhlke, Clemens; Müller, Rüdiger
    We derive the boundary conditions for the contact between an electrolyte and a solid electrode. At first we revisit the thermodynamic consistent complete model that resolves the actual electrodeelectrolyte interface and its adjacent boundary layers. The width of these layers is controlled by the Debye length that is typically very small, leading to strongly different length scales in the system. We apply the method of asymptotic analysis to derive a simpler reduced model that does not resolve the boundary layers but instead incorporates the electrochemical properties of the layers into a set of new boundary conditions. This approach fully determines the relation of bulk quantities to the boundary conditions of the reduced model. In particular, the Butler-Volmer equations for electrochemical reactions, which are still under discussion in the literature, are rational consequences of our approach. For illustration and to compare with the literature, we consider a simple generic reaction.
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    Rational modeling of electrochemical double layers in thermodynamic non-equilibrium
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2014) Dreyer, Wolfgang; Guhlke, Clemens; Müller, Rüdiger
    We consider the contact between an electrolyte and a solid electrode. At first we formulate a thermodynamic consistent model that resolves boundary layers at interfaces. The model includes charge transport, diffusion, chemical reactions, viscosity, elasticity and polarization under isothermal conditions. There is a coupling between these phenomena that particularly involves the local pressure in the electrolyte. Therefore the momentum balance is of major importance for the correct description of the layers. The width of the boundary layers is typically very small compared to the macroscopic dimensions of the system. In a second step we thus apply the method of asymptotic analysis to derive a simpler reduced model that does not resolve the boundary layers but instead incorporates the electrochemical properties of the layers into a set of new boundary conditions. For a metal-electrolyte interface, we derive a qualitative description of the double layer capacitance without the need to resolve space charge layers.
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    Modelling compressible electrolytes with phase transition
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2014) Dreyer, Wolfgang; Giesselmann, Jan; Kraus, Christiane
    A novel thermodynamically consistent diffuse interface model is derived for compressible electrolytes with phase transitions. The fluid mixtures may consist of N constituents with the phases liquid and vapor, where both phases may coexist. In addition, all constituents may consist of polarizable and magnetizable matter. Our introduced thermodynamically consistent diffuse interface model may be regarded as a generalized model of Allen-Cahn/Navier-Stokes/Poisson type for multi-component flows with phase transitions and electrochemical reactions. For the introduced diffuse interface model, we investigate physically admissible sharp interface limits by matched asymptotic techniques. We consider two scaling regimes, i.e. a non-coupled and a coupled regime, where the coupling takes place between the smallness parameter in the Poisson equation and the width of the interface. We recover in the sharp interface limit a generalized Allen-Cahn/Euler/Poisson system for mixtures with electrochemical reactions in the bulk phases equipped with admissible interfacial conditions. The interfacial conditions satisfy, for instance, a generalized Gibbs-Thomson law and a dynamic Young-Laplace law.
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    A quasi-incompressible diffuse interface model with phase transition
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2012) Aki, Gonca; Dreyer, Wolfgang; Giesselmann, Jan; Kraus, Christine
    This work introduces a new thermodynamically consistent diffuse model for two-component flows of incompressible fluids. For the introduced diffuse interface model, we investigate physically admissible sharp interface limits by matched asymptotic techniques. To this end, we consider two scaling regimes where in one case we recover the Euler equations and in the other case the Navier-Stokes equations in the bulk phases equipped with admissible interfacial conditions. For the Navier-Stokes regime, we further assume the densities of the fluids are close to each other in the sense of a small parameter which is related to the interfacial thickness of the diffuse model.
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    A compressible mixture model with phase transition
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2013) Dreyer, Wolfgang; Giesselmann, Jan; Kraus, Christiane
    We introduce a new thermodynamically consistent diffuse interface model of AllenCahn/NavierStokes type for multi-component flows with phase transitions and chemical reactions. For the introduced diffuse interface model, we investigate physically admissible sharp interface limits by matched asymptotic techniques. We consider two scaling regimes, i.e. a non-dissipative and a dissipative regime, where we recover in the sharp interface limit a generalized Allen-Cahn/Euler system for mixtures with chemical reactions in the bulk phases equipped with admissible interfacial conditions. The interfacial conditions satify, for instance, a YoungLaplace and a Stefan type law.
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    Asymptotics for the spectrum of a thin film equation in a singular limit
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2010) Kitavtsev, Georgy; Recke, Lutz; Wagner, Barbara
    In this paper the linear stability properties of the steady states of a no-slip lubrication equation are studied. The steady states are configurations of droplets and arise during the late-phase dewetting process under the influence of both destabilizing van der Waals and stabilizing Born intermolecular forces, which in turn give rise to the minimum thickness eps of the remaining film connecting the droplets. The goal of this paper is to give an asymptotic description of the eigenvalues and eigenfunctions of the problem, linearized about the one-droplet solutions, as epsto 0. For this purpose, corresponding asymptotic eigenvalue problems with piecewise constant coefficients are constructed, such that their eigenvalue asymptotics can be determined analytically. A comparison with numerically computed eigenvalues and eigenfunctions shows good agreement with the asymptotic results and the existence of a spectrum gap to a single exponentially small eigenvalue for sufficiently small eps.
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    Thin film models for an active gel
    (Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2017) Kitavtsev, Georgy; Münch, Andreas; Wagner, Barbara
    In this study we present a free-boundary problem for an active liquid crystal based on the Beris-Edwards theory that uses a tensorial order parameter and includes active contributions to the stress tensor to analyse the rich defect structure observed in applications such as the Adenosinetriphosphate (ATP) driven motion of a thin film of an actin filament network. The small aspect ratio of the film geometry allows for an asymptotic approximation of the free-boundary problem in the limit of weak elasticity of the network and strong active terms. The new thin film model captures the defect dynamics in the bulk as well as wall defects and thus presents a significant extension of previous models based on the Leslie-Erickson-Parodi theory. Analytic expressions are derived that reveal the interplay of anchoring conditions, film thickness and active terms and their control of transitions of flow structure.