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- ItemCovalent Organic Frameworks for Efficient Energy Electrocatalysis: Rational Design and Progress(Weinheim : Wiley-VCH, 2021) Zhang, Hua; Zhu, Minshen; Schmidt, Oliver G.; Chen, Shuillang; Zhang, KaiAn efficient catalyst with a precisely designed and predictable structure is highly desired to optimize its performance and understand the mechanism beyond the catalytic activity. Covalent organic frameworks (COFs), as an emerging class of framework materials linked by strong covalent bonds, simultaneously allow precise structure design with predictable synthesis and show advantages of large surface areas, tunable pore sizes, and unique molecular architectures. Although the research on COF‐based electrocatalysts is at an early age, significant progress has been made. Herein, the recent significant progress in the design and synthesis of COFs as highly efficient electrocatalysts for the oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER) is summarized. Design principles for COFs as efficient electrocatalysts are discussed by considering essential factors for catalyzing the OER, ORR, and HER processes at the molecular level. Herein, a summary on the in‐depth understanding of the catalytic mechanism and kinetics limitations of COFs provides a general instruction for further exploring their vast potential for designing highly efficient electrocatalysts.
- ItemArchitecture engineering of carbonaceous anodes for high‐rate potassium‐ion batteries(Hoboken, NJ : Wiley, 2021) Wu, Tianlai; Zhang, Weicai; Yang, Jiaying; Lu, Qiongqiong; Peng, Jing; Zheng, Mingtao; Xu, Fei; Liu, Yingliang; Liang, YeruThe limited lithium resource in earth's crust has stimulated the pursuit of alternative energy storage technologies to lithium‐ion battery. Potassium‐ion batteries (KIBs) are regarded as a kind of promising candidate for large‐scale energy storage owing to the high abundance and low cost of potassium resources. Nevertheless, further development and wide application of KIBs are still challenged by several obstacles, one of which is their fast capacity deterioration at high rates. A considerable amount of effort has recently been devoted to address this problem by developing advanced carbonaceous anode materials with diverse structures and morphologies. This review presents and highlights how the architecture engineering of carbonaceous anode materials gives rise to high‐rate performances for KIBs, and also the beneficial conceptions are consciously extracted from the recent progress. Particularly, basic insights into the recent engineering strategies, structural innovation, and the related advances of carbonaceous anodes for high‐rate KIBs are under specific concerns. Based on the achievements attained so far, a perspective on the foregoing, and proposed possible directions, and avenues for designing high‐rate anodes, are presented finally.
- ItemA new method for correcting temperature log profiles in low-enthalpy plays(Berlin ; Heidelberg [u.a.] : Springer Open, 2020) Schumacher, Sandra; Moeck, IngaTemperature logs recorded shortly after drilling operations can be the only temperature information from deep wells. However, these measurements are still influenced by the thermal disturbance caused by drilling and therefore do not represent true rock temperatures. The magnitude of the thermal disturbance is dependent on many factors such as drilling time, logging procedure or mud temperature. However, often old well reports lack this crucial information so that conventional corrections on temperature logs cannot be performed. This impedes the re-evaluation of well data for new exploration purposes, e.g. for geothermal resources. This study presents a new method to correct log temperatures in low-enthalpy play types which only requires a knowledge of the final depth of the well as an input parameter. The method was developed and verified using existing well data from an intracratonic sedimentary basin, the eastern part of the North German Basin. It can be transferred to other basins with little or no adjustment. © 2020, The Author(s).
- ItemPredictability and controlling factors of overpressure in the North Alpine Foreland Basin, SE Germany: an interdisciplinary post-drill analysis of the Geretsried GEN-1 deep geothermal well(Berlin ; Heidelberg [u.a.] : Springer Open, 2020) Drews, Michael C.; Hofstetter, Peter; Zosseder, Kai; Shipilin, Vladimir; Stollhofen, HaraldThe North Alpine Foreland Basin in SE Germany is Germany’s most active deep geothermal province. However, in its southern and eastern part the basin is considerably overpressured, which is a significant challenge for drilling deep geothermal wells. In this study, we combine drilling data and velocity-based pore pressure analyses with 3D basin modeling to assess the predictability and controlling factors of overpressure in the sub-regional context (area of 80 km × 50 km) around the Geretsried GEN-1 well, a deep geothermal exploration well in the southern part of the North Alpine Foreland Basin in SE Germany. Drilling data and velocity-based pore pressure analyses indicate overpressure maxima in the Lower Oligocene (Rupelian and Schoeneck Formation) and up to mild overpressure in the Upper Oligocene (Chattian) and Upper Cretaceous, except for the hydrostatically pressured northwestern part of the study area. 3D basin modeling calibrated to four hydrocarbon wells surrounding the Geretsried GEN-1 well demonstrates the dominating role of disequilibrium compaction and low permeability units related to overpressure generation in the North Alpine Foreland Basin. However, secondary overpressure generation mechanisms are likely contributing. Also, the impact of Upper Cretaceous shales, which are eroded in the northwestern part of the study area, on overpressure maintenance is investigated. The calibrated basin model is tested against the drilling history and velocity (VSP) data-based pore pressure estimate of the Geretsried GEN-1 well and reveals that pore pressure prediction is generally possible using 3D basin modeling in the North Alpine Foreland Basin, but should be improved with more detailed analysis of lateral drainage systems and facies variations in the future. The results of the study are of relevance to future well planning and drilling as well as to geomechanical modeling of subsurface stresses and deep geothermal production in the North Alpine Foreland Basin. © 2020, The Author(s).
- ItemIon dynamics in Al-Stabilized Li7La3Zr2O12 single crystals – Macroscopic transport and the elementary steps of ion hopping(Amsterdam : Elsevier, 2020) Posch, Patrick; Lunghammer, Sarah; Berendts, Stefan; Ganschow, Steffen; Redhammer, Günther J.; Wilkening, Alexandra; Lerch, Martin; Gadermaier, Bernhard; Rettenwander, Daniel; Wilkening, H. Martin R.Li7La3Zr2O12 (LLZO) garnet-type ceramics are considered as very promising candidates for solid electrolytes and have been extensively studied in the past few years. Several studies report on an increase in ionic conductivity by doping with ions, such as Al3+ and Ga3+, to stabilize the cubic modification of LLZO. Unfortunately, so far ion dynamics have mainly been studied using powdered samples. Such studies may suffer from chemical heterogeneities concerning Al distribution. Here, we took advantage of Al-stabilized LLZO single crystals to throw light on the elementary steps of ion hopping. We used 7Li nuclear magnetic resonance (NMR) spin-lattice relaxation measurements and conductivity spectroscopy to probe dynamic parameters from both a microscopic and macroscopic point of view. At 293 K the total conductivity turned out to be 0.082 mS cm−1, which is remarkably good for LLZO exhibiting an Al-content of only 0.37 wt%. Most importantly, 7Li NMR spin-lock transients revealed two overlapping diffusion-induced processes. Overall, activation energies from spin-lock NMR excellently agree with that from conductivity measurements; both techniques yield values around 0.36 eV. The corresponding diffusion coefficients deduced from NMR and conductivity measurements almost coincide. The magnetic spin fluctuations sensed by NMR provide an in-depth look at the elementary jump processes, which can barely be revealed by macroscopic impedance spectroscopy providing average values. In particular, we were able to precisely measure the local hopping barrier (0.20 eV) characterizing forward-backward jumps between the sites 24d and 96h. © 2019 The Author(s)
- ItemAssessment of Socio-Economic and Climate Change Impacts on Water Resources in Four European Lagoon Catchments(New York, NY : Springer, 2019) Stefanova, Anastassi; Hesse, Cornelia; Krysanova, Valentina; Volk, MartinThis study demonstrates the importance of considering potential land use and management changes in climate impact research. By taking into account possible trends of economic development and environmental awareness, we assess effects of global warming on water availability and quality in the catchments of four European lagoons: Ria de Aveiro (Portugal), Mar Menor (Spain), Vistula Lagoon (Poland and Russia), and Tyligulskyi Liman (Ukraine). Different setups of the process-based soil and water integrated model (SWIM), representing one reference and four socio-economic scenarios for each study area: the “business as usual”, “crisis”, “managed horizons”, and “set-aside” scenarios are driven by sets of 15 climate scenarios for a reference (1971–2000) and near future (2011–2040) scenario period. Modeling results suggest a large spatial variability of potential impacts across the study areas, due to differences in the projected precipitation trends and the current environmental and socio-economic conditions. While climate change may reduce water and nutrients input to the Ria de Aveiro and Tyligulsyi Liman and increase water inflow to the Vistula Lagoon the socio-economic scenarios and their implications may balance out or reverse these trends. In the intensely managed Mar Menor catchment, climate change has no notable direct impact on water resources, but changes in land use and water management may certainly aggravate the current environmental problems. The great heterogeneity among results does not allow formulating adaptation or mitigation measures at pan-European level, as initially intended by this study. It rather implies the need of a regional approach in coastal zone management. © 2019, The Author(s).
- ItemDesign and quality criteria for archetype analysis(Wolfville, Nova Scotia : Resilience Alliance, 2019) Eisenack, Klaus; Villamayor-Tomas, Sergio; Epstein, Graham; Kimmich, Christian; Magliocca, Nicholas; Manuel-Navarrete, David; Oberlack, Christoph; Roggero, Matteo; Sietz, DianaA key challenge in addressing the global degradation of natural resources and the environment is to effectively transfer successful strategies across heterogeneous contexts. Archetype analysis is a particularly salient approach in this regard that helps researchers to understand and compare patterns of (un)sustainability in heterogeneous cases. Archetype analysis avoids traps of overgeneralization and ideography by identifying reappearing but nonuniversal patterns that hold for well-defined subsets of cases. It can be applied by researchers working in inter-or transdisciplinary settings to study sustainability issues from a broad range of theoretical and methodological standpoints. However, there is still an urgent need for quality standards to guide the design of theoretically rigorous and practically useful archetype analyses. To this end, we propose four quality criteria and corresponding research strategies to address them: (1) specify the domain of validity for each archetype, (2) ensure that archetypes can be combined to characterize single cases, (3) explicitly navigate levels of abstraction, and (4) obtain a fit between attribute configurations, theories, and empirical domains of validity. These criteria are based on a stocktaking of current methodological challenges in archetypes research, including: to demonstrate the validity of the analysis, delineate boundaries of archetypes, and select appropriate attributes to define them. We thus contribute to a better common understanding of the approach and to the improvement of the research design of future archetype analyses. © 2019 by the author(s).
- ItemArchetype analysis in sustainability research: meanings, motivations, and evidence-based policy making(Wolfville, Nova Scotia : Resilience Alliance, 2019) Oberlack, Christoph; Sietz, Diana; Bürgi Bonanomi, Elisabeth; de Bremond, Ariane; Dell'Angelo, Jampel; Eisenack, Klaus; Ellis, Erle C.; Epstein, Graham; Giger, Markus; Heinimann, Andreas; Kimmich, Christian; Kok, Marcel TJ; Manuel-Navarrete, David; Messerli, Peter; Meyfroidt, Patrick; Václavík, Tomáš; Villamayor-Tomas, SergioArchetypes are increasingly used as a methodological approach to understand recurrent patterns in variables and processes that shape the sustainability of social-ecological systems. The rapid growth and diversification of archetype analyses has generated variations, inconsistencies, and confusion about the meanings, potential, and limitations of archetypes. Based on a systematic review, a survey, and a workshop series, we provide a consolidated perspective on the core features and diverse meanings of archetype analysis in sustainability research, the motivations behind it, and its policy relevance. We identify three core features of archetype analysis: Recurrent patterns, multiple models, and intermediate abstraction. Two gradients help to apprehend the variety of meanings of archetype analysis that sustainability researchers have developed: (1) understanding archetypes as building blocks or as case typologies and (2) using archetypes for pattern recognition, diagnosis, or scenario development. We demonstrate how archetype analysis has been used to synthesize results from case studies, bridge the gap between global narratives and local realities, foster methodological interplay, and transfer knowledge about sustainability strategies across cases. We also critically examine the potential and limitations of archetype analysis in supporting evidence-based policy making through context-sensitive generalizations with case-level empirical validity. Finally, we identify future priorities, with a view to leveraging the full potential of archetype analysis for supporting sustainable development. © 2019 by the author(s).
- ItemNo Evidence for a Significant Impact of Heterogeneous Chemistry on Radical Concentrations in the North China Plain in Summer 2014(Columbus, Ohio : American Chemical Society, 2020) Tan, Zhaofeng; Hofzumahaus, Andreas; Lu, Keding; Brown, Steven S.; Holland, Frank; Huey, Lewis Gregory; Kiendler-Scharr, Astrid; Li, Xin; Liu, Xiaoxi; Ma, Nan; Min, Kyung-Eun; Rohrer, Franz; Shao, Min; Wahner, Andreas; Wang, Yuhang; Wiedensohler, Alfred; Wu, Yusheng; Wu, Zhijun; Zeng, Limin; Zhang, Yuanhang; Fuchs, HendrikThe oxidation of nitric oxide to nitrogen dioxide by hydroperoxy (HO2) and organic peroxy radicals (RO2) is responsible for the chemical net ozone production in the troposphere and for the regeneration of hydroxyl radicals, the most important oxidant in the atmosphere. In Summer 2014, a field campaign was conducted in the North China Plain, where increasingly severe ozone pollution has been experienced in the last years. Chemical conditions in the campaign were representative for this area. Radical and trace gas concentrations were measured, allowing for calculating the turnover rates of gas-phase radical reactions. Therefore, the importance of heterogeneous HO2 uptake on aerosol could be experimentally determined. HO2 uptake could have suppressed ozone formation at that time because of the competition with gas-phase reactions that produce ozone. The successful reduction of the aerosol load in the North China Plain in the last years could have led to a significant decrease of HO2 loss on particles, so that ozone-forming reactions could have gained importance in the last years. However, the analysis of the measured radical budget in this campaign shows that HO2 aerosol uptake did not impact radical chemistry for chemical conditions in 2014. Therefore, reduced HO2 uptake on aerosol since then is likely not the reason for the increasing number of ozone pollution events in the North China Plain, contradicting conclusions made from model calculations reported in the literature. © 2020 American Chemical Society.
- ItemDo Benefits from Dynamic Tariffing Rise? Welfare Effects of Real-Time Retail Pricing Under Carbon Taxation and Variable Renewable Electricity Supply(Dordrecht [u.a.] : Springer Science + Business Media B.V., 2020) Gambardella, Christian; Pahle, Michael; Schill, Wolf-PeterWe analyze the gross welfare gains from real-time retail pricing in electricity markets where carbon taxation induces investment in variable renewable technologies. Applying a stylized numerical electricity market model, we find a U-shaped association between carbon taxation and gross welfare gains. The benefits of introducing real-time pricing can accordingly be relatively low at relatively high carbon taxes and vice versa. The non-monotonous change in welfare gains can be explained by corresponding changes in the inefficiency arising from “under-consumption” during low-price periods rather than by changes in wholesale price volatility. Our results may cast doubt on the efficiency of ongoing roll-outs of advanced meters in many electricity markets, since net benefits might only materialize at relatively high carbon tax levels and renewable supply shares. © 2019, The Author(s).