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- ItemThe influence of partial replacement of Cu with Ga on the corrosion behavior of Ti40Zr10Cu36PD14 metallic glasses(Bristol : IOP Publishing, 2019) Wei, Qi; Gostin, Petre Flaviu; Addison, Owen; Reed, Daniel; Calin, Mariana; Bera, Supriya; Ramasamy, Parthiban; Davenport, AlisonTiZrCuPdGa metallic glasses are under consideration for small dental biomedical implants. There is interest in replacing some of the Cu with Ga to improve the glass-forming ability and biocompatibility. Ti40Zr10Cu36-xPd14Gax (x = 0, 1, 2, 4, 8 and 10 at.%) metallic glasses in rod and ribbon forms were fabricated by mould casting and melt spinning, respectively, and electrochemically tested in a 0.9wt.% NaCl (0.154 M) solution. It has been shown that for both rod and ribbon samples Ga levels up to 8% have no significant effect on passive current density, pitting potential or cathodic reactivity in 0.9% NaCl at 37°C. Different pitting potential and corrosion potential values were found when ribbon and rod samples of the same composition were compared for all compositions apart from the one containing the highest Ga level (10%). This was attributed to structural relaxation occurring as a result of the slower cooling rates during casting rods compared with melt-spinning ribbons. Substitution of Ga for Cu in these metallic glasses therefore expected to have no significant effect on corrosion susceptibility. © The Author(s) 2019.
- ItemBoundary conditions for electrochemical interfaces(Bristol : IOP Publishing, 2017) Landstorfer, ManuelConsistent boundary conditions for electrochemical interfaces, which cover double layer charging, pseudo-capacitive effects and transfer reactions, are of high demand in electrochemistry and adjacent disciplines. Mathematical modeling and optimization of electrochemical systems is a strongly emerging approach to reduce cost and increase efficiency of super-capacitors, batteries, fuel cells, and electro-catalysis. However, many mathematical models which are used to describe such systems lack a real predictive value. Origin of this shortcoming is the usage of oversimplified boundary conditions. In this work we derive the boundary conditions for some general electrode-electrolyte interface based on non-equilibrium thermodynamics for volumes and surfaces. The resulting equations are widely applicable and cover also tangential transport. The general framework is then applied to a specific material model which allows the deduction of a current-voltage relation and thus a comparison to experimental data. Some simplified 1D examples show the range of applicability of the new approach.
- ItemControlled growth of transition metal dichalcogenide monolayers using Knudsen-type effusion cells for the precursors(Bristol : IOP Publishing, 2019) George, Antony; Neumann, Christof; Kaiser, David; Mupparapu, Rajeshkumar; Lehnert, Tibor; Hübner, Uwe; Tang, Zian; Winter, Andreas; Kaiser, Ute; Staude, Isabelle; Turchanin, AndreyControlling the flow rate of precursors is essential for the growth of high quality monolayer single crystals of transition metal dichalcogenides (TMDs) by chemical vapor deposition. Thus, introduction of an excess amount of the precursors affects reproducibility of the growth process and results in the formation of TMD multilayers and other unwanted deposits. Here we present a simple method for controlling the precursor flow rates using the Knudsen-type effusion cells. This method results in a highly reproducible growth of large area and high density TMD monolayers. The size of the grown crystals can be adjusted between 10 and 200 μm. We characterized the grown MoS2 and WS2 monolayers by optical, atomic force and transmission electron microscopies as well as by x-ray photoelectron, Raman and photoluminescence spectroscopies, and by electrical transport measurements showing their high optical and electronic quality based on the single crystalline nature.
- ItemRecent global and regional trends in burned area and their compensating environmental controls(Bristol : IOP Publishing, 2019) Forkel, Matthias; Dorigo, Wouter; Lasslop, Gitta; Chuvieco, Emilio; Hantson, Stijn; Heil, Angelika; Teubner, Irene; Thonicke, Kirsten; Harrison, Sandy P.The apparent decline in the global incidence of fire between 1996 and 2015, as measured by satellite-observations of burned area, has been related to socioeconomic and land use changes. However, recent decades have also seen changes in climate and vegetation that influence fire and fire-enabled vegetation models do not reproduce the apparent decline. Given that the satellite-derived burned area datasets are still relatively short (<20 years), this raises questions both about the robustness of the apparent decline and what causes it. We use two global satellite-derived burned area datasets and a data-driven fire model to (1) assess the spatio-temporal robustness of the burned area trends and (2) to relate the trends to underlying changes in temperature, precipitation, human population density and vegetation conditions. Although the satellite datasets and simulation all show a decline in global burned area over ~20 years, the trend is not significant and is strongly affected by the start and end year chosen for trend analysis and the year-to-year variability in burned area. The global and regional trends shown by the two satellite datasets are poorly correlated for the common overlapping period (2001–2015) and the fire model simulates changes in global and regional burned area that lie within the uncertainties of the satellite datasets. The model simulations show that recent increases in temperature would lead to increased burned area but this effect is compensated by increasing wetness or increases in population, both of which lead to declining burned area. Increases in vegetation cover and density associated with recent greening trends lead to increased burned area in fuel-limited regions. Our analyses show that global and regional burned area trends result from the interaction of compensating trends in controls of wildfire at regional scales.