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Fabrication of a new photo-sensitized solar cell using TiO2\ZnO Nanocomposite synthesized via a modified sol-gel Technique
The current research synthesized was carried out using a modified solgel Technique for titanium dioxide ( TiO2) and zinc oxide (ZnO) nanocomposite. The morphology and optical properties of the synthesized nanocomposite were examined using a transmission electron microscope ( TEM) and UV-Visible spectroscopy. The structure of the synthesized nanocomposite was proved using X-ray Diffraction(XRD). The particle size of the ZnO/TiO2 nanocomposites was found to be range between 11 to 27.37 nm. The product of TEM has proof of the inclusion in the ZnO matrix of spherical TiO2particles. Also found were TiO2 sections attached to the ZnO-like rodlike particles., the ZnO/TiO2 Nanocomposites had better optical absorbing properties. The nanocomposite has been used to create a new photosensitizer solar cell with the efficiency of energy conversion of approximately 4.6%, using (E)-ethyl 4- ((4-nitrobenzylidene)) aminobenzoate as organic photo-sensitized (OPS) by (ITO/TiO2\ZnO nanocomposite/POS/iodine/silver (Ag) nanofilm/ITO).
Advances in electron channelling contrast imaging and electron backscatter diffraction for imaging and analysis of structural defects in the scanning electron microscope
In this article we describe the scanning electron microscopy (SEM) techniques of electron channelling contrast imaging and electron backscatter diffraction. These techniques provide information on crystal structure, crystal misorientation, grain boundaries, strain and structural defects on length scales from tens of nanometres to tens of micrometres. Here we report on the imaging and analysis of dislocations and sub-grains in nitride semiconductor thin films (GaN and AlN) and tungsten carbide-cobalt (WC-Co) hard metals. Our aim is to illustrate the capability of these techniques for investigating structural defects in the SEM and the benefits of combining these diffraction-based imaging techniques.
Exponential Moments for Planar Tessellations
In this paper we show existence of all exponential moments for the total edge length in a unit disk for a family of planar tessellations based on stationary point processes. Apart from classical tessellations such as the Poisson–Voronoi, Poisson–Delaunay and Poisson line tessellation, we also treat the Johnson–Mehl tessellation, Manhattan grids, nested versions and Palm versions. As part of our proofs, for some planar tessellations, we also derive existence of exponential moments for the number of cells and the number of edges intersecting the unit disk.
Robust transverse structures in rescattered photoelectron wavepackets and their consequences
Initial-state symmetry has been under-appreciated in strong-field spectroscopies, where laser fields dominate the dynamics. We demonstrate numerically that the transverse photoelectron phase structure, arising from the initial-state symmetry, is robust in strong-field rescattering, and has pronounced effects on strong-field photoelectron spectra. Interpretation of rescattering experiments need to take these symmetry effects into account. In turn, robust transverse photoelectron phase structures may enable attosecond sub-Ångström super-resolution imaging with structured electron beams.
Photobiomodulation of lymphatic drainage and clearance: Perspective strategy for augmentation of meningeal lymphatic functions
There is a hypothesis that augmentation of the drainage and clearing function of the meningeal lymphatic vessels (MLVs) might be a promising therapeutic target for preventing neurological diseases. Here we investigate mechanisms of photobiomodulation (PBM, 1267 nm) of lymphatic drainage and clearance. Our results obtained at optical coherence tomography (OCT) give strong evidence that low PBM doses (5 and 10 J/cm2) stimulate drainage function of the lymphatic vessels via vasodilation (OCT data on the mesenteric lymphatics) and stimulation of lymphatic clearance (OCT data on clearance of gold nanorods from the brain) that was supported by confocal imaging of clearance of FITC-dextran from the cortex via MLVs. We assume that PBM-mediated relaxation of the lymphatic vessels can be possible mechanisms underlying increasing the permeability of the lymphatic endothelium that allows molecules transported by the lymphatic vessels and explain PBM stimulation of lymphatic drainage and clearance. These findings open new strategies for the stimulation of MLVs functions and non-pharmacological therapy of brain diseases.
Ambient noise analysis for characterizing sub-surface dynamic parameters
Ambient noise analysis of horizontal to vertical spectral ratio (HVSR) method has been used widely to provide reliable estimates of the site fundamental frequency and to constrain the inversion of near-surface shear wave velocity. The present paper focuses on the site measurement using the aforementioned analysis by means of the HVSR method for characterizing sub-surface dynamic parameters in the City of Banda Aceh, Indonesia. A Guralp CMG-6TD broadband seismometer was used in this study to cover a wide frequency range from 0.033 Hz to 50 Hz in standard operation. The instrument was deployed at two different sites (i.e. Location#1 of Blang Padang and Location#2 of Stadion Dirmutala) in the City of Banda Aceh for at least 2 hours for ambient noise recording. This continuous of 2 hours' microtremor time series was separated into 30 minutes record from which the site fundamental frequency and shear wave velocity of the measured site were deduced. The later sub-surface dynamic parameter was validated using another technique of reflection seismic. This investigation suggests the fundamental frequency of 0.45 Hz at Location#1 and of 0.65 Hz at Location#2. The estimated shear wave velocity of the top 30 m, Vs,30 of this investigation is 165 m/s at Location#1 and 156 m/s at Location#2. Both the site fundamental frequency and shear wave velocity are important for infrastructure design in the high seismic region of Banda Aceh, Indonesia.
Dynamical Phase Transitions for Flows on Finite Graphs
We study the time-averaged flow in a model of particles that randomly hop on a finite directed graph. In the limit as the number of particles and the time window go to infinity but the graph remains finite, the large-deviation rate functional of the average flow is given by a variational formulation involving paths of the density and flow. We give sufficient conditions under which the large deviations of a given time averaged flow is determined by paths that are constant in time. We then consider a class of models on a discrete ring for which it is possible to show that a better strategy is obtained producing a time-dependent path. This phenomenon, called a dynamical phase transition, is known to occur for some particle systems in the hydrodynamic scaling limit, which is thus extended to the setting of a finite graph.
Autofluorescence guided welding of heart tissue by laser pulse bursts at 1550 nm
Wound healing and other surgical technologies traditionally solved by suturing and stapling have recently been enhanced by the application of laser tissue welding. The usage of high energy laser radiation to anastomose tissues eliminates a foreign body reaction, reduces scar formation, and allows for the creation of watertight closure. In the current work, we show that an ultrafast pulsed fibre laser beam with 183 µJ·cm−2 energy fluence at 1550 nm provides successful welding of dissected chicken heart walls with the tensile strength of 1.03±0.12 kg·cm−2 equal to that of native tissue. The welding process was monitored employing fluorescence spectroscopy that detects the biochemical composition of tissues. We believe that fluorescence spectroscopy guided laser tissue welding is a promising approach for decreasing wound healing times and the avoiding risks of postoperative complications.
Bio-inspired deposition of electrochemically exfoliated graphene layers for electrical resistance heating applications
Electrochemically exfoliated graphene (eeG) layers possess a variety of potential applications, e.g. as susceptor material for contactless induction heating in dynamic electro-magnetic fields, and as flexible and transparent electrode or resistivity heating elements. Spray coating of eeG dispersions was investigated in detail as a simple and fast method to deposit both, thin conducting layers and ring structures on polycarbonate substrates. The spray coating process was examined by systematic variation of dispersion concentration and volume applied to heated substrates. Properties of the obtained layers were characterized by UV-VIS spectroscopy, SEM and Confocal Scanning Microscopy. Electrical conductivity of eeG ring structures was measured using micro-four-point measurements. Modification of eeG with poly(dopamine) and post-thermal treatment yields in the reduction of the oxidized graphene proportion, an increase in electrical conductivity, and mechanical stabilization of the deposited thin layers. The chemical composition of modified eeG layer was analyzed via x-ray photoelectron spectroscopy pointing to the reductive behavior of poly(dopamine). Application oriented experiments demonstrate the direct electric current heating (Joule-Heating) effect of spray-coated eeG layers.
Modeling of Chemical Reaction Systems with Detailed Balance Using Gradient Structures
We consider various modeling levels for spatially homogeneous chemical reaction systems, namely the chemical master equation, the chemical Langevin dynamics, and the reaction-rate equation. Throughout we restrict our study to the case where the microscopic system satisfies the detailed-balance condition. The latter allows us to enrich the systems with a gradient structure, i.e. the evolution is given by a gradient-flow equation. We present the arising links between the associated gradient structures that are driven by the relative entropy of the detailed-balance steady state. The limit of large volumes is studied in the sense of evolutionary Γ-convergence of gradient flows. Moreover, we use the gradient structures to derive hybrid models for coupling different modeling levels.