Search Results
Current Advances in TiO2-Based Nanostructure Electrodes for High Performance Lithium Ion Batteries
2018-2-6, Madian, Mahmoud, Eychmüller, Alexander, Giebeler, Lars
The lithium ion battery (LIB) has proven to be a very reliably used system to store electrical energy, for either mobile or stationary applications. Among others, TiO2-based anodes are the most attractive candidates for building safe and durable lithium ion batteries with high energy density. A variety of TiO2 nanostructures has been thoroughly investigated as anodes in LIBs, e.g., nanoparticles, nanorods, nanoneedles, nanowires, and nanotubes discussed either in their pure form or in composites. In this review, we present the recent developments and breakthroughs demonstrated to synthesize safe, high power, and low cost nanostructured titania-based anodes. The reader is provided with an in-depth review of well-oriented TiO2-based nanotubes fabricated by anodic oxidation. Other strategies for modification of TiO2-based anodes with other elements or materials are also highlighted in this report.
Multiscale Spatiotemporal Analysis of Extreme Events in the Gomati River Basin, India
2021, Kalyan, AVS, Ghose, Dillip Kumar, Thalagapu, Rahul, Guntu, Ravi Kumar, Agarwal, Ankit, Kurths, Jürgen, Rathinasamy, Maheswaran
Accelerating climate change is causing considerable changes in extreme events, leading to immense socioeconomic loss of life and property. In this study, we investigate the characteristics of extreme climate events at a regional scale to ‐understand these events’ propagation in the near fu-ture. We have considered sixteen extreme climate indices defined by the World Meteorological Or-ganization’s Expert Team on Climate Change Detection and Indices from a long‐term dataset (1951– 2018) of 53 locations in Gomati River Basin, North India. We computed the present and future spatial variation of theses indices using the Sen’s slope estimator and Hurst exponent analysis. The periodicities and non‐stationary features were estimated using the continuous wavelet transform. Bivariate copulas were fitted to estimate the joint probabilities and return periods for certain com-binations of indices. The study results show different variation in the patterns of the extreme climate indices: D95P, R95TOT, RX5D, and RX showed negative trends for all stations over the basin. The number of dry days (DD) showed positive trends over the basin at 36 stations out of those 17 stations are statistically significant. A sustainable decreasing trend is observed for D95P at all stations, indi-cating a reduction in precipitation in the future. DD exhibits a sustainable decreasing trend at almost all the stations over the basin barring a few exceptions highlight that the basin is turning drier. The wavelet power spectrum for D95P showed significant power distributed across the 2–16‐year bands, and the two‐year period was dominant in the global power spectrum around 1970–1990. One interest-ing finding is that a dominant two‐year period in D95P has changed to the four years after 1984 and remains in the past two decades. The joint return period’s resulting values are more significant than values resulting from univariate analysis (R95TOT with 44% and RTWD of 1450 mm). The difference in values highlights that ignoring the mutual dependence can lead to an underestimation of extremes. © 2021 by the author. Licensee MDPI, Basel, Switzerland.
Surface-Enhanced Raman Spectroscopy to Characterize Different Fractions of Extracellular Vesicles from Control and Prostate Cancer Patients
2021, Osei, Eric Boateng, Paniushkina, Liliia, Wilhelm, Konrad, Popp, Jürgen, Nazarenko, Irina, Krafft, Christoph
Extracellular vesicles (EVs) are membrane-enclosed structures ranging in size from about 60 to 800 nm that are released by the cells into the extracellular space; they have attracted interest as easily available biomarkers for cancer diagnostics. In this study, EVs from plasma of control and prostate cancer patients were fractionated by differential centrifugation at 5000× g, 12,000× g and 120,000× g. The remaining supernatants were purified by ultrafiltration to produce EV-depleted free-circulating (fc) fractions. Spontaneous Raman and surface-enhanced Raman spectroscopy (SERS) at 785 nm excitation using silver nanoparticles (AgNPs) were employed as label-free techniques to collect fingerprint spectra and identify the fractions that best discriminate between control and cancer patients. SERS spectra from 10 µL droplets showed an enhanced Raman signature of EV-enriched fractions that were much more intense for cancer patients than controls. The Raman spectra of dehydrated pellets of EV-enriched fractions without AgNPs were dominated by spectral contributions of proteins and showed variations in S-S stretch, tryptophan and protein secondary structure bands between control and cancer fractions. We conclude that the AgNPs-mediated SERS effect strongly enhances Raman bands in EV-enriched fractions, and the fractions, EV12 and EV120 provide the best separation of cancer and control patients by Raman and SERS spectra.
Can Green Plants Mitigate Ammonia Concentration in Piglet Barns?
2021, Menardo, Simona, Berg, Werner, Grüneberg, Heiner, Jakob, Martina
For animal welfare and for farmers’ health, the concentration of ammonia (NH3 ) in animal houses should be as low as possible. Plants can remove various atmospheric contaminants through the leaf stomata. This study examined the effect of ornamental plants installed inside a piglet barn on the NH3 concentration in the air. Gas measurements of the air in the ‘greened’ compartment (P) and a control compartment (CTR) took place over two measuring periods (summer–autumn and winter). Differences between the NH3 emissions were calculated based on the ventilation rates according to the CO2 balance. Fairly low mean NH3 concentrations between 2 and 4 ppm were measured. The NH3 emissions were about 20% lower (p < 0.01) in P than in CTR, in summer–autumn and in winter period. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.
Auger- and X-ray Photoelectron Spectroscopy at Metallic Li Material: Chemical Shifts Related to Sample Preparation, Gas Atmosphere, and Ion and Electron Beam Effects
2022, Oswald, Steffen
Li-based batteries are a key element in reaching a sustainable energy economy in the near future. The understanding of the very complex electrochemical processes is necessary for the optimization of their performance. X-ray photoelectron spectroscopy (XPS) is an accepted method used to improve understanding around the chemical processes at the electrode surfaces. Nevertheless, its application is limited because the surfaces under investigation are mostly rough and inhomogeneous. Local elemental analysis, such as Auger electron spectroscopy (AES), could assist XPS to gain more insight into the chemical processes at the surfaces. In this paper, some challenges in using electron spectroscopy are discussed, such as binding energy (BE) referencing for the quantitative study of chemical shifts, gas atmospheric influences, or beam damage (including both AE and XP spectroscopy). Carefully prepared and surface-modified metallic lithium material is used as model surface, considering that Li is the key element for most battery applications.
Plasma-derived reactive species shape a differentiation profile in human monocytes
2019, Freund, Eric, Moritz, Juliane, Stope, Matthias, Seebauer, Christian, Schmidt, Anke, Bekeschus, Sander
Background: Monocyte-derived macrophages are key regulators and producers of reactive oxygen and nitrogen species (ROS/RNS). Pre-clinical and clinical studies suggest that cold physical plasma may be beneficial in the treatment of inflammatory conditions via the release of ROS/RNS. However, it is unknown how plasma treatment affects monocytes and their differentiation profile. Methods: Naïve or phorbol-12-myristate-13-acetate (PMA)-pulsed THP-1 monocytes were exposed to cold physical plasma. The cells were analyzed regarding their metabolic activity as well as flow cytometry (analysis of viability, oxidation, surface marker expression and cytokine secretion) and high content imaging (quantitative analysis of morphology. Results: The plasma treatment affected THP-1 metabolisms, viability, and morphology. Furthermore, a significant modulation CD55, CD69, CD271 surface-expression and increase of inflammatory IL1β, IL6, IL8, and MCP1 secretion was observed upon plasma treatment. Distinct phenotypical changes in THP-1 cells arguing for a differentiation profile were validated in primary monocytes from donor blood. As a functional outcome, plasma-treated monocytes decreased the viability of co-cultured melanoma cells to a greater extent than their non-treated counterparts. Conclusions: Our results suggest plasma-derived ROS/RNS shaped a differentiation profile in human monocytes as evidenced by their increased inflammatory profile (surface marker and cytokines) as well as functional outcome (tumor toxicity). © 2019 by the authors.
Switchable Adhesion Surfaces with Enhanced Performance Against Rough Counterfaces
2016, Prieto-López, Lizbeth, Williams, John
In a recent study, we demonstrated that the pressurization of micro-fluidic features introduced in the subsurface of a soft polymer can be used to actively modify the magnitude of the adhesion to a harder counterface by changing its waviness or long wavelength undulations. In that case, both contacting surfaces had very smooth finishes with root-mean-square roughnesses of less than 20 nm. These values are far from those of many engineering surfaces, which usually have a naturally occurring roughness of between ten and a hundred times this value. In this work, we demonstrate that appropriate surface features, specifically relatively slender “fibrils”, can enhance the ability of a such a soft surface to adhere to a hard, but macroscopically rough, counterface, while still maintaining the possibility of switching the adhesion force from one level to another. Conversely, stiffer more conical surface features can suppress adhesion even against a smooth counterface. Examples of each form of topography can be found in the natural world.
A coaxial dielectric barrier discharge reactor for treatment of winter wheat seeds
2020, Nishime, Thalita M. C., Wannicke, Nicola, Horn, Stefan, Weltmann, Klaus-Dieter, Brust, Henrike
Non-thermal atmospheric pressure plasmas have been recently explored for their potential usage in agricultural applications as an interesting alternative solution for a potential increase in food production with a minor impact on the ecosystem. However, the adjustment and optimization of plasma sources for agricultural applications in general is an important study that is commonly overlooked. Thus, in the present work, a dielectric barrier discharge (DBD) reactor with coaxial geometry designed for the direct treatment of seeds is presented and investigated. To ensure reproducible and homogeneous treatment results, the reactor mechanically shakes the seeds during treatment, and ambient air is admixed while the discharge runs. The DBD, operating with argon and helium, produces two different chemically active states of the system for seed modification. The temperature evolution was monitored to guarantee a safe manipulation of seeds, whereas a physiological temperature was assured by controlling the exposure time. Both treatments led to a remarkable increase in wettability and acceleration in germination. The present study showed faster germination acceleration (60% faster after 24 h) and a lower water contact angle (WCA) (82% reduction) for winter wheat seeds by using the described argon discharge (with air impurities). Furthermore, the treatment can be easily optimized by adjusting the electrical parameters. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
DNA and RNA extraction and quantitative real-time PCR-based assays for biogas biocenoses in an interlaboratory comparison
2016, Lebuhn, Michael, Derenkó, Jaqueline, Rademacher, Antje, Helbig, Susanne, Munk, Bernhard, Pechtl, Alexander, Stolze, Yvonne, Prowe, Steffen, Schwarz, Wolfgang H., Schlüter, Andreas, Liebl, Wolfgang, Klocke, Michael
Five institutional partners participated in an interlaboratory comparison of nucleic acid extraction, RNA preservation and quantitative Real-Time PCR (qPCR) based assays for biogas biocenoses derived from different grass silage digesting laboratory and pilot scale fermenters. A kit format DNA extraction system based on physical and chemical lysis with excellent extraction efficiency yielded highly reproducible results among the partners and clearly outperformed a traditional CTAB/chloroform/isoamylalcohol based method. Analytical purpose, sample texture, consistency and upstream pretreatment steps determine the modifications that should be applied to achieve maximum efficiency in the trade-off between extract purity and nucleic acid recovery rate. RNA extraction was much more variable, and the destination of the extract determines the method to be used. RNA stabilization with quaternary ammonium salts was an as satisfactory approach as flash freezing in liquid N2. Due to co-eluted impurities, spectrophotometry proved to be of limited value for nucleic acid qualification and quantification in extracts obtained with the kit, and picoGreen® based quantification was more trustworthy. Absorbance at 230 nm can be extremely high in the presence of certain chaotropic guanidine salts, but guanidinium isothiocyanate does not affect (q)PCR. Absolute quantification by qPCR requires application of a reliable internal standard for which correct PCR efficiency and Y-intercept values are important and must be reported.
Atmospheric Dynamics and Numerical Simulations of Six Frontal Dust Storms in the Middle East Region
2021, Hamzeh, Nasim Hossein, Karami, Sara, Kaskaoutis, Dimitris G., Tegen, Ina, Moradi, Mohamad, Opp, Christian
This study analyzes six frontal dust storms in the Middle East during the cold period (October–March), aiming to examine the atmospheric circulation patterns and force dynamics that triggered the fronts and the associated (pre-or post-frontal) dust storms. Cold troughs mostly located over Turkey, Syria and north Iraq played a major role in the front propagation at the surface, while cyclonic conditions and strong winds facilitated the dust storms. The presence of an upper-atmosphere (300 hPa) sub-tropical jet stream traversing from Egypt to Iran constitutes also a dynamic force accompanying the frontal dust storms. Moderate-Resolution Imaging Spectroradiometer (MODIS) and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observation (CALIPSO) observations are used to monitor the spatial and vertical extent of the dust storms, while model (Weather Research and Forecasting model coupled with Chemistry (WRF-Chem), Copernicus Atmospheric Monitoring Service (CAMS), Regional Climate Model-4 (RegCM4)) simulations are also analyzed. The WRF-Chem outputs were in better agreement with the MODIS observations compared to those of CAMS and RegCM4. The fronts were identified by WRF-Chem simulations via gradients in the potential temperature and sudden changes of wind direction in vertical cross-sections. Overall, the uncertainties in the simulations and the remarkable differences between the model outputs indicate that modelling of dust storms in the Middle East is really challenging due to the complex terrain, incorrect representation of the dust sources and soil/surface characteristics, and uncertainties in simulating the wind speed/direction and meteorological dynamics. Given the potential threat by dust storms, more attention should be directed to the dust model development in this region. © 2021 by the authors. Licensee MDPI, Basel, Switzerland.