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- ItemMini-Workshop: Gibbs Measures for Nonlinear Dispersive Equations(Zürich : EMS Publ. House, 2018) Schlein, Benjamin; Sohinger, VedranIn this mini-workshop we brought together leading experts working on the application of Gibbs measures to the study of nonlinear PDEs. This framework is a powerful tool in the probabilistic study of solutions to nonlinear dispersive PDEs, in many ways alternative or complementary to deterministic methods. Among the special topics discussed were the construction of the measures, applications to dynamics, as well as the microscopic derivation of Gibbs measures from many-body quantum mechanics.
- ItemSelf-Regenerating Soft Biophotovoltaic Devices(Washington, DC : ACS Publications, 2018) Qiu, Xinkai; Castañeda Ocampo, Olga; de Vries, Hendrik W.; van Putten, Maikel; Loznik, Mark; Herrmann, Andreas; Chiechi, Ryan C.This paper describes the fabrication of soft, stretchable biophotovoltaic devices that generate photocurrent from photosystem I (PSI) complexes that are self-assembled onto Au electrodes with a preferred orientation. Charge is collected by the direct injection of electrons into the Au electrode and the transport of holes through a redox couple to liquid eutectic gallium-indium (EGaIn) electrodes that are confined to microfluidic pseudochannels by arrays of posts. The pseudochannels are defined in a single fabrication step that leverages the non-Newtonian rheology of EGaIn. This strategy is extended to the fabrication of reticulated electrodes that are inherently stretchable. A simple shadow evaporation technique is used to increase the surface area of the Au electrodes by a factor of approximately 106 compared to planar electrodes. The power conversion efficiency of the biophotovoltaic devices decreases over time, presumably as the PSI complexes denature and/or detach from the Au electrodes. However, by circulating a solution of active PSI complexes the devices self-regenerate by mass action/self-assembly. These devices leverage simple fabrication techniques to produce complex function and prove that photovoltaic devices comprising PSI can retain the ability to regenerate, one of the most important functions of photosynthetic organisms. © 2018 American Chemical Society.
- ItemMineral dust in Central Asia: Combining lidar and other measurements during the Central Asian dust experiment (CADEX)(Les Ulis : EDP Sciences, 2018) Althausen, Dietrich; Hofer, Julian; Abdullaev, Sabur; Makhmudov, Abduvosit; Baars, Holger; Engelmann, Ronny; Wadinga Fomba, Khanneh; Müller, Konrad; Schettler, Georg; Klüser, Lars; Kandler, Konrad; Nicolae, D.; Makoto, A.; Vassilis, A.; Balis, D.; Behrendt, A.; Comeron, A.; Gibert, F.; Landulfo, E.; McCormick, M.P.; Senff, C.; Veselovskii, I.; Wandinger, U.Mineral dust needs to be characterized comprehensively since it contributes to the climate change in Tajikistan / Central Asia. Lidar results from the measurements of mineral dust during CADEX are compared with results of sun photometer measurements, satellite-based measurements, and chemical analysis of ground samples. Although the dust is often advected from far-range sources, it impacts on the local conditions considerably.
- ItemSeeded Growth Synthesis of Gold Nanotriangles: Size Control, SAXS Analysis, and SERS Performance(Washington, DC : Soc., 2018) Kuttner, Christian; Mayer, Martin; Dulle, Martin; Moscoso, Ana; López-Romero, Juan Manuel; Förster, Stephan; Fery, Andreas; Pérez-Juste, Jorge; Contreras-Cáceres, RafaelWe studied the controlled growth of triangular prismatic Au nanoparticles with different beveled sides for surface-enhanced Raman spectroscopy (SERS) applications. First, in a seedless synthesis using 3-butenoic acid (3BA) and benzyldimethylammonium chloride (BDAC), gold nanotriangles (AuNTs) were synthesized in a mixture with gold nanooctahedra (AuNOCs) and separated by depletion-induced flocculation. Here, the influence of temperature, pH, and reducing agent on the reaction kinetics was initially investigated by UV–vis and correlated to the size and yield of AuNT seeds. In a second step, the AuNT size was increased by seed-mediated overgrowth with Au. We show for the first time that preformed 3BA-synthesized AuNT seeds can be overgrown up to a final edge length of 175 nm and a thickness of 80 nm while maintaining their triangular shape and tip sharpness. The NT morphology, including edge length, thickness, and tip rounding, was precisely characterized in dispersion by small-angle X-ray scattering and in dry state by transmission electron microscopy and field-emission scanning electron microscopy. For sensor purposes, we studied the size-dependent SERS performance of AuNTs yielding analytical enhancement factors between 0.9 × 104 and 5.6 × 104 and nanomolar limit of detection (10–8–10–9 M) for 4-mercaptobenzoic acid and BDAC. These results confirm that the 3BA approach allows the fabrication of AuNTs in a whole range of sizes maintaining the NT morphology. This enables tailoring of localized surface plasmon resonances between 590 and 740 nm, even in the near-infrared window of a biological tissue, for use as colloidal SERS sensing agents or for optoelectronic applications.
- ItemStatistical Analysis of Scanning Fluorescence Correlation Spectroscopy Data Differentiates Free from Hindered Diffusion(Washington, DC : Soc., 2018-7-20) Schneider, Falk; Waithe, Dominic; Lagerholm, B. Christoffer; Shrestha, Dilip; Sezgin, Erdinc; Eggeling, Christian; Fritzsche, MarcoCells rely on versatile diffusion dynamics in their plasma membrane. Quantification of this often heterogeneous diffusion is essential to the understanding of cell regulation and function. Yet such measurements remain a major challenge in cell biology, usually due to low sampling throughput, a necessity for dedicated equipment, sophisticated fluorescent label strategies, and limited sensitivity. Here, we introduce a robust, broadly applicable statistical analysis pipeline for large scanning fluorescence correlation spectroscopy data sets, which uncovers the nanoscale heterogeneity of the plasma membrane in living cells by differentiating free from hindered diffusion modes of fluorescent lipid and protein analogues.
- ItemTemporal Role Annotation for Named Entities(Amsterdam [u.a.] : Elsevier, 2018) Koutraki, Maria; Bakhshandegan-Moghaddam, Farshad; Sack, Harald; Fensel, Anna; de Boer, Victor; Pellegrini, Tassilo; Kiesling, Elmar; Haslhofer, Bernhard; Hollink, Laura; Schindler, AlexanderNatural language understanding tasks are key to extracting structured and semantic information from text. One of the most challenging problems in natural language is ambiguity and resolving such ambiguity based on context including temporal information. This paper, focuses on the task of extracting temporal roles from text, e.g. CEO of an organization or head of a state. A temporal role has a domain, which may resolve to different entities depending on the context and especially on temporal information, e.g. CEO of Microsoft in 2000. We focus on the temporal role extraction, as a precursor for temporal role disambiguation. We propose a structured prediction approach based on Conditional Random Fields (CRF) to annotate temporal roles in text and rely on a rich feature set, which extracts syntactic and semantic information from text. We perform an extensive evaluation of our approach based on two datasets. In the first dataset, we extract nearly 400k instances from Wikipedia through distant supervision, whereas in the second dataset, a manually curated ground-truth consisting of 200 instances is extracted from a sample of The New York Times (NYT) articles. Last, the proposed approach is compared against baselines where significant improvements are shown for both datasets.
- ItemLong-time resistivity monitoring of a freshwater/saltwater transition zone using the vertical electrode system SAMOS(Les Ulis : EDP Sciences, 2018) Grinat, Michael; Epping, Dieter; Meyer, Robert; Szymkiewicz, Adam; Sadurski, A.; Jaworska-Szulc, B.In September 2009 two newly developed vertical electrode systems were installed in boreholes in the water catchment areas Waterdelle and Ostland at the North Sea island Borkum to monitor possible changes of the transition zone between the freshwater lens and the underlying saltwater. The vertical electrode systems, which were both installed between 44 m and 65 m below ground level, are used for geoelectrical multi-electrode measurements carried out automatically several times per day; the measurements are still ongoing. The whole system consisting of a vertical electrode system in a borehole and the measuring unit at ground level is called SAMOS (Saltwater Monitoring System). At both locations the data show a clear resistivity decrease that indicates the transition zone between freshwater and saltwater. The depth of the transition zone as well as the kind of resistivity decrease is very stable since 2010. Temporal changes are visible if single depths are considered. In 2015 Miriam Ibenthal used a vertical 2D density-dependent groundwater flow model to explain the long-term resistivity measurements and showed that the temporal changes at CLIWAT 2 (Ostland) could be explained by variations of the groundwater level, changing groundwater recharge rates and changing pumping rates of the nearby located drinking water supply wells.
- ItemSaltwater intrusion under climate change in North-Western Germany - mapping, modelling and management approaches in the projects TOPSOIL and go-CAM(Les Ulis : EDP Sciences, 2018) Wiederhold, Helga; Scheer, Wolfgang; Kirsch, Reinhard; Azizur Rahman, M.; Ronczka, Mathias; Szymkiewicz, Adam; Sadurski, A.; Jaworska-Szulc, B.Climate change will result in rising sea level and, at least for the North Sea region, in rising groundwater table. This leads to a new balance at the fresh–saline groundwater boundary and a new distribution of saltwater intrusions with strong regional differentiations. These effects are investigated in several research projects funded by the European Union and the German Federal Ministry of Education and Research (BMBF). Objectives and some results from the projects TOPSOIL and go-CAM are presented in this poster.
- ItemStructural and mechanical characterization of heterogeneities in a CuZr-based bulk metallic glass processed by high pressure torsion(Amsterdam [u.a.] : Elsevier Science, 2018) Ebner, Christian; Escher, Benjamin; Gammer, Christoph; Eckert, Jürgen; Pauly, Simon; Rentenberger, ChristianCu45Zr45Al5Ag5 bulk metallic glass samples, processed by high pressure torsion (HPT) under various conditions, were characterized using synchrotron X-ray diffraction, nanoindentation, differential scanning calorimetry, atomic force and transmission electron microscopy. The experimental results clearly show that HPT modifies the amorphous structure by increasing the mean atomic volume. The level of rejuvenation, correlated with the excess mean atomic volume, is enhanced at higher shear strains as inferred from relaxation enthalpies. By mapping of structural and mechanical quantities, the strain-induced rejuvenated state is characterized on cross-sectional HPT samples on a local scale. A clear correlation both between elastic and plastic softening and between softening and excess mean atomic volume is obtained. But also the heterogeneity of the HPT induced rejuvenation is revealed, resulting in the formation of highly strain-softened regions next to less-deformed ones. A hardness drop of up to 20% is associated with an estimated increase of the mean atomic volume of up to 0.75%. Based on synchrotron X-ray diffraction and nanoindentation measurements it is concluded that elastic fluctuations are enhanced in the rejuvenated material on different length scales down to atomic scale. Furthermore, the calculated flexibility volume and the corresponding average mean square atomic displacement is increased. The plastic response during nanoindentation indicates that HPT processing promotes a more homogeneous-like deformation.
- ItemStatistics for Data with Geometric Structure(Zürich : EMS Publ. House, 2018) Hotz, Thomas; Huckemann, Stephan; Miller, EzraStatistics for data with geometric structure is an active and diverse topic of research. Applications include manifold spaces in directional data or symmetric positive definite matrices and some shape representations. But in some cases, more involved metric spaces like stratified spaces play a crucial role in different ways. On the one hand, phylogenetic trees are represented as points in a stratified data space, whereas branching trees, for example of veins, are data objects, whose stratified structure is of essential importance. For the latter case, one important tool is persistent homology, which is currently a very active area of research. As data sets become not only larger but also more complex, the need for theoretical and methodological progress in dealing with data on non-Euclidean spaces or data objects with nontrivial geometric structure is growing. A number of fundamental results have been achieved recently and the development of new methods for refined, more informative data representation is ongoing. Two complimentary approaches are pursued: on the one hand developing sophisticated new parameters to describe the data, like persistent homology, and on the other hand achieving simpler representations in terms of given parameters, like dimension reduction. Some foundational works in stochastic process theory on manifolds open the doors to this field and stochastic analysis on manifolds, thus enabling a well-founded treatment of non-Euclidean dynamic data. The results presented in the workshop by leading experts in the field are great accomplishments of collaboration between mathematicians from statistics, geometry and topology and the open problems which were discussed show the need for an expansion of this interdisciplinary effort, which could also tie in more closely with computer science.