13 results
Search Results
Now showing 1 - 10 of 13
- ItemSemi-Interpenetrating Polymer Networks Based on N-isopropylacrylamide and 2-acrylamido-2-methylpropane Sulfonic Acid for Intramolecular Force-Compensated Sensors(Bristol : IOP Publishing, 2021) Binder, Simon; Zschoche, Stefan; Voit, Brigitte; Gerlach, GeraldStimulus-responsive hydrogels are swellable polymers that take up a specific volume depending on a measured variable present in solution. Hydrogel-based chemical sensors make use of this ability by converting the resulting swelling pressure, which depends on the measured variable, into an electrical value. Due to the tedious swelling processes, the measuring method of intramolecular force compensation is used to suppress these swelling processes and, thus, significantly increase the sensor's response time. However, intramolecular force compensation requires a bisensitive hydrogel. In addition to the sensitivity of the measured variable the gel has to provide a second sensitivity for intrinsic compensation of the swelling pressure. At the same time, this hydrogel has to meet further requirements, e.g. high compressive strength. Until now, interpenetrating polymer networks (IPN) have been used for such a force-compensatory effective hydrogel, which are complex to manufacture. In order to significantly simplify the sensor design and production, a simpler synthesis of the bisensitive hydrogel is desirable. This paper presents a new bisensitive hydrogel based on semi-interpenetrating polymer networks. It is based on a copolymer network consisting of N-isopropylacrylamide (NiPAAm) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) and long PAMPS strands that permeate it. Measurements show, that this hydrogel meets all essential requirements for intramolecular force compensation and is at the same time much easier to synthesize than previously used IPN hydrogels. © 2021 The Author(s).
- ItemModeling Polycrystalline Electrode-electrolyte Interfaces: The Differential Capacitance(Bristol : IOP Publishing, 2020) Müller, Rüdiger; Fuhrmann, Jürgen; Landstorfer, ManuelWe present and analyze a model for polycrystalline electrode surfaces based on an improved continuum model that takes finite ion size and solvation into account. The numerical simulation of finite size facet patterns allows to study two limiting cases: While for facet size diameter dfacet →0 we get the typical capacitance of a spatially homogeneous but possible amorphous or liquid surface, in the limit 1[nm] < dfacet, an ensemble of non-interacting single crystal surfaces is approached. Already for moderate size of the facet diameters, the capacitance is remarkably well approximated by the classical approach of adding the single crystal capacities of the contributing facets weighted by their respective surface fraction. As a consequence, the potential of zero charge is not necessarily attained at a local minimum of capacitance, but might be located at a local capacitance maximum instead. Moreover, the results show that surface roughness can be accurately taken into account by multiplication of the ideally flat polycrystalline surface capacitance with a single factor. In particular, we find that the influence of the actual geometry of the facet pattern in negligible and our theory opens the way to a stochastic description of complex real polycrystal surfaces. © 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.
- ItemA discussion of the cell voltage during discharge of an intercalation electrode for various C-rates based on non-equilibrium thermodynamics and numerical simulations(Bristol : IOP Publishing, 2020) Landstorfer, ManuelIn this work we discuss the modeling procedure and validation of a non-porous intercalation half-cell during galvanostatic discharge. The modeling is based on continuum thermodynamics with non-equilibrium processes in the active intercalation particle, the electrolyte, and the common interface where the intercalation reaction Li+ + e- ↔ Li occurs. The model is in detail investigated and discussed in terms of scalings of the non-equilibrium parameters, i.e. the diffusion coefficients DA and DE of the active phase and the electrolyte, conductivity sA and sE of both phases, and the exchange current density e0L, with numerical solutions of the underlying PDE system. The current density i as well as all non-equilibrium parameters are scaled s with respect to the 1-C current density iC A of the intercalation electrode. We compute then numerically the cell voltage E as function of the capacity Q and the C-rate Ch. Within a hierarchy of approximations we provide computations of E(Q) for various scalings of the diffusion coefficients, the conductivities and the exchange current density. For the later we provide finally a discussion for possible concentration dependencies. © The Author(s) 2019. Published by ECS.
- ItemS-wave seismic imaging of near-surface sediments using tailored processing strategies(Amsterdam [u.a.] : Elsevier Science, 2020) Burschil, Thomas; Buness, HermannReflection seismic imaging using horizontally-polarized S-waves (SH) can increase resolution and it could be cost-efficient compared to the common use of P-waves. However, since S-wave application often delivers varying data quality, appropriate processing schemes are required for particular imaging and interpretation purposes. In this paper, we present four tailored processing strategies that are applied to SH-wave data acquired in an overdeepened Quaternary basin in the Alpine foreland, the Tannwald Basin. The applied processing schemes consist of (1) processing using a short automatic gain control window that enhances structural details and highlights small-scale structures, (2) offset restriction indicating that relative small offsets are sufficient for adequate imaging, which offers reduced field operation costs, (3) coherency-enhancement that reveals large-scale structures for interpretation, and (4) adapted amplitude scaling that enables structural comparison of P-wave and S-wave seismic sections. With respect to P-wave data measured on the same profile, we demonstrate the benefits of the S-wave seismic reflection method. P-waves offer robust imaging results, but S-waves double the resolution, better depict shallow reflections, and may image reflectors in areas where the P-wave struggles. At least for the Tannwald Basin, S-wave imaging is also more cost-efficient than P-wave imaging. © 2020 The Authors
- ItemNon-invasive prospection techniques and direct push sensing as high-resolution validation tools in wetland geoarchaeology – Artificial water supply at a Carolingian canal in South Germany?(Amsterdam [u.a.] : Elsevier Science, 2020) Rabiger-Völlmer, Johannes; Schmidt, Johannes; Linzen, Sven; Schneider, Michael; Werban, Ulrike; Dietrich, Peter; Wilken, Dennis; Wunderlich, Tina; Fediuk, Annika; Berg, Stefanie; Werther, Lukas; Zielhofer, ChristophThe prospection of (geo-)archaeological sites yield important knowledge about the concept and the utilisation of pre-historical and historical infrastructure. The satisfactory conduction of classical prospection methods like archaeological excavations or geoarchaeological vibra-coring might be challenging in the case of large sites or difficult underground conditions. This is particularly problematic in wetlands featuring a high groundwater table and high compaction rates of organic layers. In this study, we provide an alternative and non- to minimal-invasive exploration approach to discover hydro-engineering structures for artificial water supply in the surrounding of a Carolingian summit canal in South Germany. The Early Medieval Fossa Carolina was intended 792/793 CE to bridge the Central European watershed between Rhine-Main and Danube catchments. As the canal was constructed as a summit canal, an artificial water supply at the highest levels seemed very likely or even obligatory. In order to explore these obligatory hydro-engineering features, we use a wide range of on-site and off-site tools in a spatial hierarchical way. Our approach includes the large-scale SQUID magnetic survey and the sighting of historical maps. Furthermore, we integrate high-resolution direct push colour logs, and subsequent vibra-coring for small-scale stratigraphical verification and sedimentological analyses. The SQUID magnetic survey and related depth models discover two pronounced linear anomalies that might represent potential artificial water inlets in the North-Eastern and Northern Sections of the canal. I) In the North-Eastern Section, direct push colour logs, vibra-coring and 14C dating provide no evidence for a Carolingian hydro-engineering feature but reveal a natural lenticular structure of Early Holocene age. II) The linear magnetic anomaly in the Northern Section can be excluded with high probability as a hydro-engineering structure as well. Here, direct push colour logs, vibra-coring, 14C dating and the comparison with a historic map reveal evidence for a historic gravel road. Thus, we have nicely verified the magnetic information but have no prove for an artificial Carolingian water inlet from the Swabian Rezat River that contradicts with assumptions of former studies. © 2020 The Authors
- ItemNon-remote reference noise cancellation - using reference data in the presence of surface-NMR signals(Amsterdam [u.a.] : Elsevier Science, 2020) Müller-Petke, MikeSurface-NMR measurements commonly suffer from low signal-to-noise ratios. In recent years, with the introduction of multi-channel surface-NMR instruments, the technique of remote-reference noise cancellation (RNC) was developed and significantly improved the applicability of surface-NMR. The current formulation of RNC requires a reference loop to be placed a remote distance from the transmitter loop such that no NMR signal is recorded. Reference loops placed at non-remote distances have been envisaged to provide both improved noise cancellation performance and field efficiency; however, the concept has not been previously applied because the theoretical framework was missing. In this paper, the theoretical framework is presented. It is demonstrated that reference loops placed at non-remote distances provide superior noise cancellation performance. Considerations for placing the reference loop relative to the transmitter loop are provided, and the theoretical framework is evaluated based on a semi-synthetic example using real field noise and synthetic surface-NMR data. © 2020
- ItemEvaluation of spectral induced polarization field measurements in time and frequency domain(Amsterdam [u.a.] : Elsevier Science, 2020) Martin, Tina; Günther, Thomas; Orozco, Adrian Flores; Dahlin, TorleifSpectral induced polarization (SIP) measurements have been demonstrated to correlate with important parameters in hydrogeological and environmental investigations. Although SIP measurements were often collected in the frequency domain (FDIP), recent developments have demonstrated the capabilities to solve for the frequency-dependence of the complex conductivity through measurements collected in the time domain (TDIP). Therefore, the aim of our field investigations is a comparison of the measured frequency-dependence at a broad frequency range resolved through FDIP and TDIP. In contrast to previous studies, we conducted measurements with different instruments and measuring technologies for both FDIP and TDIP. This allows for investigating the robustness of different measurements and assessing various sources of errors, for the assessment of the advantages and drawbacks from different measuring techniques. Our results demonstrate that data collected through different instruments are consistent. Apparent resistivity measurements as well as the inversion results revealed quantitatively the same values for all instruments. The measurements of the IP effect are also comparable, particularly FDIP readings in the low frequencies (< 10 Hz) revealed to be quantitatively the same for different instruments. TDIP measurements are consistent for data collected with both devices. As expected, the spatial distribution of the values is also consistent for low frequency data (in FDIP) and late times measurements in TDIP (> 0.1 s). However, data quality for higher frequencies in FDIP (i.e., early times in TDIP) show larger variations, which reflects the differences between the instruments to deal with the electromagnetic contamination of the IP data. Concluded in general, the different instruments and measuring techniques can provide consistent responses for varying signal-to-noise ratio and measuring configurations. © 2020 The Authors
- ItemComparison of novel semi-airborne electromagnetic data with multi-scale geophysical, petrophysical and geological data from Schleiz, Germany(Amsterdam [u.a.] : Elsevier Science, 2020) Steuer, Annika; Smirnova, Maria; Becken, Michael; Schiffler, Markus; Günther, Thomas; Rochlitz, Raphael; Yogeshwar, Pritam; Mörbe, Wiebke; Siemon, Bernhard; Costabel, Stephan; Preugschat, Benedikt; Ibs-von Seht, Malte; Zampa, Luigi Sante; Müller, FranzIn the framework of the Deep Electromagnetic Sounding for Mineral EXploration (DESMEX) project, we carried out multiple geophysical surveys from regional to local scales in a former mining area in the state of Thuringia, Germany. We prove the applicability of newly developed semi-airborne electromagnetic (EM) systems for mineral exploration by cross-validating inversion results with those of established airborne and ground-based investigation techniques. In addition, supporting petrophysical and geological information to our geophysical measurements allowed the synthesis of all datasets over multiple scales. An initial regional-scale reconnaissance survey was performed with BGR's standard helicopter-borne geophysical system deployed with frequency-domain electromagnetic (HEM), magnetic and radiometric sensors. In addition to geological considerations, the HEM results served as base-line information for the selection of an optimal location for the intermediate-scale semi-airborne EM experiments. The semi-airborne surveys utilized long grounded transmitters and two independent airborne receiver instruments: induction coil magnetometers and SQUID sensors. Due to the limited investigation depth of the HEM method, local-scale electrical resistivity tomography (ERT) and long-offset transient electromagnetic (LOTEM) measurements were carried out on a reference profile, enabling the validation of inversion results at greater depths. The comparison of all inversion results provided a consistent overall resistivity distribution. It further confirmed that both semi-airborne receiver instruments achieve the bandwidth and sensitivity required for the investigation of the resistivity structure down to 1 km depth and therewith the detection of deeply seated earth resources. A 3D geological model, lithological and geophysical borehole logs as well as petrophysical investigations were integrated to interpret of the geophysical results. Distinct highly-conductive anomalies with resistivities of less than 10 Om were identified as alum shales over all scales. Apart from that, the petrophysical investigations exhibited that correlating geophysical and geological information using only one single parameter, such as the electrical resistivity, is hardly possible. Therefore, we developed a first approach based on clustering methods and self-organizing maps (SOMs) that allowed us to assign geological units at the surface to a given combination of geophysical and petrophysical parameters, obtained on different scales. © 2020 The Authors
- ItemClassification of slag material by spectral induced polarization laboratory and field measurements(Amsterdam [u.a.] : Elsevier Science, 2021) Martin, Tina; Günther, Thomas; Weller, Andreas; Kuhn, KerstinHistorical slag dumps are of increasing interest due to economic, environmental or archaeological reasons. Geophysical investigations can help accessing the potential reuse of slag material to recover metallic raw material or for the estimation of the hazard potential of the buried slag material due to dissolution occurrence. In our study, we have investigated various slag material in the laboratory with the spectral induced polarization (SIP) method, obtained from different historical slag dumps, located in the Harz Mountains, Germany. We also present SIP results from field measurements at a historical slag dump where most of the slag samples reveal high amounts of iron, zinc, silica, and barium. Our results reveal a discrimination between three different slag grades (low, medium, high) by using the imaginary conductivity σ″ at a medium frequency (1–10 Hz) in both laboratory and field. Furthermore, additional information is obtained by a classification based on the spectral polarization behaviour and considering the field frequency range (0.1 Hz – 100 Hz). Five different types of spectra (ascending, descending, constant, maximum and minimum type) can be discriminated and recognized in the laboratory and in distinct areas of the slag dump. Even though a direct comparison between the laboratory and field results still needs to be proven, the buried slag material can be differentiated from the surrounding material by the polarization magnitude.
- ItemApplication of adiabatic pulses for magnetic Resonance Sounding – Pulse shapes and resolution(Amsterdam [u.a.] : Elsevier Science, 2020) Dlugosch, Raphael; Müller-Petke, MikeMagnetic Resonance Sounding (MRS) can image the spatial distribution of hydrologically relevant parameters in in the subsurface. However, the application of MRS is often limited by its low signal-to-noise ratio. The use of adiabatic excitation pulses show promising features to overcome this limitation. In this work, we study practical considerations when applying adiabatic pulses for MRS, i.e. calculation of the sensitivity kernel for varying pulse shapes and vertical resolution. The pulse shape is crucial for the performance of adiabatic pulses. We investigate the shapes of adiabatic pulses recorded during a MRS and observe small systematic deviations from the theoretical predicted pulse shape and variations between different pulse strengths. We show that the overall impact on the obtained sounding curve and inversion result was small. This enables to limit the time consuming modelling of the spin dynamic to one representative pulse shape, which significantly speeds up the calculation of the sensitivity kernel, necessary for the interpretation of MRS. Additionally, we show that on-resonance excitation generally outperforms adiabatic excitation concerning vertical resolution and depth of investigation (both up to a factor of two). This is true for a wide range of noise conditions. For a very shallow depth interval compared to the loop size, however, adiabatic excitation features improved imaging capabilities. © 2020 The Authors