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- ItemEfficient Current Injection Into Single Quantum Dots Through Oxide-Confined p-n-Diodes(New York, NY : IEEE, 2016) Kantner, Markus; Bandelow, Uwe; Koprucki, Thomas; Schulze, Jan-Hindrik; Strittmatter, Andre; Wunsche, Hans-JurgenCurrent injection into single quantum dots embedded in vertical p-n-diodes featuring oxide apertures is analyzed in the low-injection regime suitable for single-photon emitters. The experimental and theoretical evidence is found for a rapid lateral spreading of the carriers after passing the oxide aperture in the conventional p-i-n-design. By an alternative design employing p-doping up to the oxide aperture, the current spreading can be suppressed resulting in an enhanced current confinement and increased injection efficiencies, both, in the continuous wave and under pulsed excitation.
- ItemElectrothermal Tristability Causes Sudden Burn-In Phenomena in Organic LEDs(Weinheim : Wiley-VCH, 2021) Kirch, Anton; Fischer, Axel; Liero, Matthias; Fuhrmann, Jürgen; Glitzky, Annegret; Reineke, SebastianOrganic light-emitting diodes (OLEDs) have been established as a mature display pixel technology. While introducing the same technology in a large-area form factor to general lighting and signage applications, some key questions remain unanswered. Under high-brightness conditions, OLED panels were reported to exhibit nonlinear electrothermal behavior causing lateral brightness inhomogeneities and even regions of switched-back luminance. Also, the physical understanding of sudden device failure and burn-ins is still rudimentary. A safe and stable operation of lighting tiles, therefore, requires an in-depth understanding of these physical phenomena. Here, it is shown that the electrothermal treatment of thin-film devices allows grasping the underlying physics. Configurations of OLEDs with different lateral dimensions are studied as a role model and it is reported that devices exceeding a certain panel size develop three stable, self heating-induced operating branches. Switching between them causes the sudden formation of dark spots in devices without any preexisting inhomogeneities. A current-stabilized operation mode is commonly used in the lighting industry, as it ensures degradation-induced voltage adjustments. Here, it is demonstrated that a tristable operation always leads to destructive switching, independent of applying constant currents or voltages. With this new understanding of the effects at high operation brightness, it will be possible to adjust driving schemes accordingly, design more resilient system integrations, and develop additional failure mitigation strategies. © 2021 The Authors. Advanced Functional Materials published by Wiley-VCH GmbH
- ItemBoundary conditions for electrochemical interfaces(Bristol : IOP Publishing, 2017) Landstorfer, ManuelConsistent boundary conditions for electrochemical interfaces, which cover double layer charging, pseudo-capacitive effects and transfer reactions, are of high demand in electrochemistry and adjacent disciplines. Mathematical modeling and optimization of electrochemical systems is a strongly emerging approach to reduce cost and increase efficiency of super-capacitors, batteries, fuel cells, and electro-catalysis. However, many mathematical models which are used to describe such systems lack a real predictive value. Origin of this shortcoming is the usage of oversimplified boundary conditions. In this work we derive the boundary conditions for some general electrode-electrolyte interface based on non-equilibrium thermodynamics for volumes and surfaces. The resulting equations are widely applicable and cover also tangential transport. The general framework is then applied to a specific material model which allows the deduction of a current-voltage relation and thus a comparison to experimental data. Some simplified 1D examples show the range of applicability of the new approach.
- ItemMode competition in broad-ridge-waveguide lasers(Bristol : IOP Publ., 2020) Koester, J.-P.; Putz, A.; Wenzel, H.; Wünsche, H.-J.; Radziunas, M.; Stephan, H.; Wilkens, M.; Zeghuzi, A.; Knigge, A.The lateral brightness achievable with high-power GaAs-based laser diodes having long and broad waveguides is commonly regarded to be limited by the onset of higher-order lateral modes. For the study of the lateral-mode competition two complementary simulation tools are applied, representing different classes of approximations. The first tool bases on a completely incoherent superposition of mode intensities and disregards longitudinal effects like spatial hole burning, whereas the second tool relies on a simplified carrier transport and current flow. Both tools yield agreeing power-current characteristics that fit the data measured for 5-23 µm wide ridges. Also, a similarly good qualitative conformance of the near and far fields is found. However, the threshold of individual modes, the partition of power between them at a given current, and details of the near and far fields show differences. These differences are the consequence of a high sensitivity of the mode competition to details of the models and of the device structure. Nevertheless, it can be concluded concordantly that the brightness rises with increasing ridge width irrespective of the onset of more and more lateral modes. The lateral brightness W mm-1at 10 MW cm-2 power density on the front facet of the investigated laser with widest ridge (23 µm) is comparable with best values known from much wider broad-area lasers. In addition, we show that one of the simulation tools is able to predict beam steering and coherent beam coupling without introducing any phenomenological coupling coefficient or asymmetries. © 2020 The Author(s). Published by IOP Publishing Ltd.
- ItemA discussion of the cell voltage during discharge of an intercalation electrode for various C-rates based on non-equilibrium thermodynamics and numerical simulations(Bristol : IOP Publishing, 2020) Landstorfer, ManuelIn this work we discuss the modeling procedure and validation of a non-porous intercalation half-cell during galvanostatic discharge. The modeling is based on continuum thermodynamics with non-equilibrium processes in the active intercalation particle, the electrolyte, and the common interface where the intercalation reaction Li+ + e- ↔ Li occurs. The model is in detail investigated and discussed in terms of scalings of the non-equilibrium parameters, i.e. the diffusion coefficients DA and DE of the active phase and the electrolyte, conductivity sA and sE of both phases, and the exchange current density e0L, with numerical solutions of the underlying PDE system. The current density i as well as all non-equilibrium parameters are scaled s with respect to the 1-C current density iC A of the intercalation electrode. We compute then numerically the cell voltage E as function of the capacity Q and the C-rate Ch. Within a hierarchy of approximations we provide computations of E(Q) for various scalings of the diffusion coefficients, the conductivities and the exchange current density. For the later we provide finally a discussion for possible concentration dependencies. © The Author(s) 2019. Published by ECS.
- ItemModeling Polycrystalline Electrode-electrolyte Interfaces: The Differential Capacitance(Bristol : IOP Publishing, 2020) Müller, Rüdiger; Fuhrmann, Jürgen; Landstorfer, ManuelWe present and analyze a model for polycrystalline electrode surfaces based on an improved continuum model that takes finite ion size and solvation into account. The numerical simulation of finite size facet patterns allows to study two limiting cases: While for facet size diameter dfacet →0 we get the typical capacitance of a spatially homogeneous but possible amorphous or liquid surface, in the limit 1[nm] < dfacet, an ensemble of non-interacting single crystal surfaces is approached. Already for moderate size of the facet diameters, the capacitance is remarkably well approximated by the classical approach of adding the single crystal capacities of the contributing facets weighted by their respective surface fraction. As a consequence, the potential of zero charge is not necessarily attained at a local minimum of capacitance, but might be located at a local capacitance maximum instead. Moreover, the results show that surface roughness can be accurately taken into account by multiplication of the ideally flat polycrystalline surface capacitance with a single factor. In particular, we find that the influence of the actual geometry of the facet pattern in negligible and our theory opens the way to a stochastic description of complex real polycrystal surfaces. © 2020 The Author(s). Published on behalf of The Electrochemical Society by IOP Publishing Limited.
- ItemNumerical simulation of TEM images for In(Ga)As/GaAs quantum dots with various shapes(Dordrecht [u.a.] : Springer Science + Business Media B.V, 2020) Maltsi, Anieza; Niermann, Tore; Streckenbach, Timo; Tabelow, Karsten; Koprucki, ThomasWe present a mathematical model and a tool chain for the numerical simulation of TEM images of semiconductor quantum dots (QDs). This includes elasticity theory to obtain the strain profile coupled with the Darwin–Howie–Whelan equations, describing the propagation of the electron wave through the sample. We perform a simulation study on indium gallium arsenide QDs with different shapes and compare the resulting TEM images to experimental ones. This tool chain can be applied to generate a database of simulated TEM images, which is a key element of a novel concept for model-based geometry reconstruction of semiconductor QDs, involving machine learning techniques.
- ItemVibrations of a laboratory-scale gas-stirred ladle with two eccentric nozzles and multiple sensors([Singapore] : Springer Singapore, 2019) Alia, Najib; Pylvänäinen, Mika; Visuri, Ville-Valtteri; John, Volker; Ollila, SeppoDuring ladle stirring, a gas is injected into the steel bath to generate a mixing of the liquid steel. The optimal process control requires a reliable measurement of the stirring intensity, for which the induced ladle wall vibrations have proved to be a potential indicator. An experimental cold water ladle with two eccentric nozzles and eight mono-axial accelerometers was thus investigated to measure the vibrations. The effect of the sensors’ positions with respect to the gas plugs on the vibration intensity was analyzed, and experimental data on several points of the ladle were collected for future numerical simulations. It is shown that the vibration root-mean-square values depend not only on process parameters, such as gas flow rate, water, and oil heights, but also on the radial and axial positions of the sensors. The vibration intensity is clearly higher, close to the gas plumes, than in the opposite side. If one of the nozzles is clogged, the vibration intensity close to the clogged nozzle drops drastically (−36 to −59%), while the vibrations close to the normal operating nozzle are hardly affected. Based on these results, guidelines are provided for an optimized vibration-based stirring.
- ItemDecomposition of a Cooling Plant for Energy Efficiency Optimization Using OptTopo(Basel : MDPI, 2022) Thiele, Gregor; Johanni, Theresa; Sommer, David; Krüger, JörgThe operation of industrial supply technology is a broad field for optimization. Industrial cooling plants are often (a) composed of several components, (b) linked using network technology, (c) physically interconnected, and (d) complex regarding the effect of set-points and operating points in every entity. This leads to the possibility of overall optimization. An example containing a cooling tower, water circulations, and chillers entails a non-linear optimization problem with five dimensions. The decomposition of such a system allows the modeling of separate subsystems which can be structured according to the physical topology. An established method for energy performance indicators (EnPI) helps to formulate an optimization problem in a coherent way. The novel optimization algorithm OptTopo strives for efficient set-points by traversing a graph representation of the overall system. The advantages are (a) the ability to combine models of several types (e.g., neural networks and polynomials) and (b) an constant runtime independent from the number of operation points requested because new optimization needs just to be performed in case of plant model changes. An experimental implementation of the algorithm is validated using a simscape simulation. For a batch of five requests, OptTopo needs 61 (Formula presented.) while the solvers Cobyla, SDPEN, and COUENNE need 0.3 min, 1.4 min, and 3.1 min, respectively. OptTopo achieves an efficiency improvement similar to that of established solvers. This paper demonstrates the general feasibility of the concept and fortifies further improvements to reduce computing time.
- ItemDetecting striations via the lateral photovoltage scanning method without screening effect(Dordrecht [u.a.] : Springer Science + Business Media B.V, 2021) Kayser, S.; Farrell, P.; Rotundo, N.The lateral photovoltage scanning method (LPS) detects doping inhomogeneities in semiconductors such as Si, Ge and SixGe1−x in a cheap, fast and nondestructive manner. LPS relies on the bulk photovoltaic effect and thus can detect any physical quantity affecting the band profiles of the sample. LPS finite volume simulation using commercial software suffer from long simulation times and convergence instabilities. We present here an open-source finite volume simulation for a 2D Si sample using the ddfermi simulator. For low injection conditions we show that the LPS voltage is proportional to the doping gradient. For higher injection conditions, we directly show how the LPS voltage and the doping gradient differ and link the physical effect of lower local resolution to the screening effect. Previously, the loss of local resolution was assumed to be only connected to the enlargement of the excess charge carrier distribution.