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    Small-scale mixing processes enhancing troposphere-to-stratosphere transport by pyro-cumulonimbus storms
    (Göttingen : Copernicus GmbH, 2007) Luderer, G.; Trentmann, J.; Hungershöfer, K.; Herzog, M.; Fromm, M.; Andreae, M.O.
    Deep convection induced by large forest fires is an efficient mechanism for transport of aerosol particles and trace gases into the upper troposphere and lower stratosphere (UT/LS). For many pyro-cumulonimbus clouds (pyroCbs) as well as other cases of severe convection without fire forcing, radiometric observations of cloud tops in the thermal infrared (IR) reveal characteristic structures, featuring a region of relatively high brightness temperatures (warm center) surrounded by a U-shaped region of low brightness temperatures. We performed a numerical simulation of a specific case study of pyroCb using a non-hydrostatic cloud resolving model with a two-moment cloud microphysics parameterization and a prognostic turbulence scheme. The model is able to reproduce the thermal IR structure as observed from satellite radiometry. Our findings establish a close link between the observed temperature pattern and small-scale mixing processes atop and downwind of the overshooting dome of the pyroCb. Such small-scale mixing processes are strongly enhanced by the formation and breaking of a stationary gravity wave induced by the overshoot. They are found to increase the stratospheric penetration of the smoke by up to almost 30 K and thus are of major significance for irreversible transport of forest fire smoke into the lower stratosphere.
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    Sensitivity of polar stratospheric ozone loss to uncertainties in chemical reaction kinetics
    (Göttingen : Copernicus GmbH, 2009) Kawa, S.R.; Stolarski, R.S.; Newman, P.A.; Douglass, A.R.; Rex, M.; Hofmann, D.J.; Santee, M.L.; Frieler, K.
    The impact and significance of uncertainties in model calculations of stratospheric ozone loss resulting from known uncertainty in chemical kinetics parameters is evaluated in trajectory chemistry simulations for the Antarctic and Arctic polar vortices. The uncertainty in modeled ozone loss is derived from Monte Carlo scenario simulations varying the kinetic (reaction and photolysis rate) parameters within their estimated uncertainty bounds. Simulations of a typical winter/spring Antarctic vortex scenario and Match scenarios in the Arctic produce large uncertainty in ozone loss rates and integrated seasonal loss. The simulations clearly indicate that the dominant source of model uncertainty in polar ozone loss is uncertainty in the Cl2O 2 photolysis reaction, which arises from uncertainty in laboratory-measured molecular cross sections at atmospherically important wavelengths. This estimated uncertainty in JCl 2O2 from laboratory measurements seriously hinders our ability to model polar ozone loss within useful quantitative error limits. Atmospheric observations, however, suggest that the Cl2O2 photolysis uncertainty may be less than that derived from the lab data. Comparisons to Match, South Pole ozonesonde, and Aura Microwave Limb Sounder (MLS) data all show that the nominal recommended rate simulations agree with data within uncertainties when the Cl2O2 photolysis error is reduced by a factor of two, in line with previous in situ ClOx measurements. Comparisons to simulations using recent cross sections from Pope et al. (2007) are outside the constrained error bounds in each case. Other reactions producing significant sensitivity in polar ozone loss include BrO + ClO and its branching ratios. These uncertainties challenge our confidence in modeling polar ozone depletion and projecting future changes in response to changing halogen emissions and climate. Further laboratory, theoretical, and possibly atmospheric studies are needed.
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    Polynyas in a high-resolution dynamic-thermodynamic sea ice model and their parameterization using flux models
    (Abingdon : Taylor and Francis Ltd., 2001) Bjornsson, H.; Willmott, A.J.; Mysak, L.A.; Morales Maqueda, M.A.
    This paper presents an analysis of the solutions for a steady state latent heat polynya generated by an applied wind stress acting over a semi-enclosed channel using: (a) a dynamic-thermodynamic sea ice model, and (b) a steady state flux model. We examine what processes in the sea ice model are responsible for the maintenance of the polynya and how sensitive the results are to the choice of rheological parameters. We find that when the ice is driven onshore by an applied wind stress, a consolidated ice pack forms downwind of a zone of strong convergence in the ice velocities. The build-up of internal stresses within the consolidated ice pack becomes a crucial factor in the formation of this zone and results in a distinct polynya edge. Furthermore, within the ice pack the across-channel ice velocity varies with the across-channel distance. It is demonstrated that provided this velocity is well represented, the steady state polynya flux model solutions are in close agreement with those of the sea ice model. Experiments with the sea ice model also show that the polynya shape and area are insensitive to (a) the sea ice rheology; (b) the imposition of either free- slip or no-slip boundary conditions. These findings are used in the development of a simplified model of the consolidated ice pack dynamics, the output of which is then compared with the sea ice model results. Finally, we discuss the relevance of this study for the modelling of the North Water Polynya in northern Baffin Bay.