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- ItemDynamics of droplet formation at T-shaped nozzles with elastic feed lines(Heidelberg : Springer, 2010) Malsch, D.; Gleichmann, N.; Kielpinski, M.; Mayer, G.; Henkel, T.; Mueller, D.; Van Steijn, V.; Kleijn, C.R.; Kreutzer, M.T.We describe the formation of water in oil droplets, which are commonly used in lab-on-a-chip systems for sample generation and dosing, at microfluidic T-shaped nozzles from elastic feed lines. A narrow nozzle forms a barrier for a liquid-liquid interface, such that pressure can build up behind the nozzle up to a critical pressure. Above this critical pressure, the liquid bursts into the main channel. Build-up of pressure is possible when the fluid before the nozzle is compressible or when the channel that leads to the nozzle is elastic. We explore the value of the critical pressure and the time required to achieve it. We describe the fluid flow of the sudden burst, globally in terms of flow rate into the channel and spatially resolved in terms of flow fields measured using micro-PIV. A total of three different stages-the lag phase, a spill out phase, and a linear growth phase-can be clearly discriminated during droplet formation. The lag time linearly scales with the curvature of the interface inside the nozzle and is inversly proportional to the flow rate of the dispersed phase. A complete overview of the evolution of the growth of droplets and the internal flow structure is provided in the digital supplement. © The Author(s) 2009.
- ItemPyrimidinone: Versatile Trojan horse in DNA photodamage?(Heidelberg : Springer, 2015) Micheel, Mathias; Torres Ziegenbein, Christian; Gilch, Peter; Ryseck, Gerald(6-4) Photolesions between adjacent pyrimidine DNA bases are prone to secondary photochemistry. It has been shown that singlet excited (6-4) moieties form Dewar valence isomers as well as triplet excitations. We here report on the triplet state of a minimal model for the (6-4) photolesion, 1-methyl-2(1H)-pyrimidinone. Emphasis is laid on its ability to abstract hydrogen atoms from alcohols and carbohydrates. Steady-state and time-resolved experiments consistently yield bimolecular rate constants of ∼104 M−1 s−1 for the hydrogen abstraction. The process also occurs intramolecularly as experiments on zebularine (1-(β-D-ribofuranosyl)-2(1H)-pyrimidinone) show.
- ItemMicro-structured fiber interferometer as sensitive temperature sensor(Heidelberg : Springer, 2013) Favero, F.C.; Becker, M.; Spittel, R.; Rothhardt, M.; Kobelke, J.; Bartelt, H.We report on a fast and sensitive temperature sensor using a micro-structured or photonic crystal fiber interferometer with a high germanium doped fiber core. The wavelength sensitivity for temperature variation was as high as δλ/δT= 78 pm/ C up to 500 C, which was 6 times more sensitive than the fiber Bragg grating temperature sensitivity of δλ/δT= 13 pm/ C at 1550 nm. The sensor device was investigated concerning the sensitivity characteristics and response time.
- ItemNanoscopic tip sensors fabricated by gas phase etching of optical glass fibers(Heidelberg : Springer, 2012) Bierlich, J.; Kobelke, J.; Brand, D.; Kirsch, K.; Dellith, J.; Bartelt, H.Silica-based fiber tips are used in a variety of spectroscopic, micro- or nano-scopic optical sensor applications and photonic micro-devices. The miniaturization of optical sensor systems and the technical implementation using optical fibers can provide new sensor designs with improved properties and functionality for new applications. The selective-etching of specifically doped silica fibers is a promising method in order to form complex photonic micro structures at the end or within fibers such as tips and cavities in various shapes useful for the all-fiber sensor and imaging applications. In the present study, we investigated the preparation of geometrically predefined, nanoscaled fiber tips by taking advantage of the dopant concentration profiles of highly doped step-index fibers. For this purpose, a gas phase etching process using hydrofluoric acid (HF) vapor was applied. The shaping of the fiber tips was based on very different etching rates as a result of the doping characteristics of specific optical fibers. Technological studies on the influence of the etching gas atmosphere on the temporal tip shaping and the final geometry were performed using undoped and doped silica fibers. The influence of the doping characteristics was investigated in phosphorus-, germanium-, fluorine- and boron-doped glass fibers. Narrow exposed as well as protected internal fiber tips in various shapes and tip radiuses down to less than 15 nm were achieved and characterized geometrically and topologically. For investigations into surface plasmon resonance effects, the fiber tips were coated with nanometer-sized silver layers by means of vapour deposition and finally subjected to an annealing treatment.
- ItemPolyester textile functionalization through incorporation of pH/thermo-responsive microgels. Part II: Polyester functionalization and characterization(Heidelberg : Springer, 2012) Glampedaki, P.; Calvimontes, A.; Dutschk, V.; Warmoeskerken, M.M.C.G.A new approach to functionalize the surface of polyester textiles is described in this study. Functionalization was achieved by incorporating pH/temperature-responsive polyelectrolyte microgels into the textile surface layer using UV irradiation. The aim of functionalization was to regulate polyester wettability according to ambient conditions by imparting stimuli-responsiveness from the microgel to the textile itself. Microgels consisted of pH/thermo-responsive microparticles of poly(N-isopropylacrylamide- co-acrylic acid) either alone or complexed with the pH-responsive natural polysaccharide chitosan. Scanning Electron Microscopy, X-ray Photoelectron Spectroscopy, ζ-potential measurements, and topographical analysis were used for surface characterization. Wettability of polyester textiles was assessed by dynamic wetting, water vapor transfer, and moisture regain measurements. One of the main findings showed that the polyester surface was rendered pH-responsive, both in acidic and alkaline pH region, owing to the microgel incorporation. With a marked relaxation in their structure and an increase in their microporosity, the functionalized textiles exhibited higher water vapor transfer rates both at 20 and 40 °C, and 65% relative humidity compared with the reference polyester. Also, at 40 °C, i.e., above the microgel Lower Critical Solution Temperature, the functionalized polyester textiles had lower moisture regains than the reference. Finally, the type of the incorporated microgel affected significantly the polyester total absorption times, with an up to 300% increase in one case and an up to 80% decrease in another case. These findings are promising for the development of functional textile materials with possible applications in biotechnology, technical, and protective clothing.
- Item5G transport network requirements for the next generation fronthaul interface(Heidelberg : Springer, 2017) Bartelt, J.; Vucic, N.; Camps-Mur, D.; Garcia-Villegas, E.; Demirkol, I.; Fehske, A.; Grieger, M.; Tzanakaki, A.; Gutiérrez, J.; Grass, E.; Lyberopoulos, G.; Fettweis, G.To meet the requirements of 5G mobile networks, several radio access technologies, such as millimeter wave communications and massive MIMO, are being proposed. In addition, cloud radio access network (C-RAN) architectures are considered instrumental to fully exploit the capabilities of future 5G RANs. However, RAN centralization imposes stringent requirements on the transport network, which today are addressed with purpose-specific and expensive fronthaul links. As the demands on future access networks rise, so will the challenges in the fronthaul and backhaul segments. It is hence of fundamental importance to consider the design of transport networks alongside the definition of future access technologies to avoid the transport becoming a bottleneck. Therefore, we analyze in this work the impact that future RAN technologies will have on the transport network and on the design of the next generation fronthaul interface. To understand the especially important impact of varying user traffic, we utilize measurements from a real-world 4G network and, taking target 5G performance figures into account, extrapolate its statistics to a 5G scenario. With this, we derive both per-cell and aggregated data rate requirements for 5G transport networks. In addition, we show that the effect of statistical multiplexing is an important factor to reduce transport network capacity requirements and costs. Based on our investigations, we provide guidelines for the development of the 5G transport network architecture.
- ItemStrain sensitivity enhancement in suspended core fiber tapers(Heidelberg : Springer, 2013) André, R.M.; Silva, S.O.; Becker, M.; Schuster, K.; Rothardt, M.; Bartelt, H.; Marques, M.B.; Frazão, O.Suspended core fiber tapers with different cross sections (with diameters from 70 μm to 120 μm) are produced by filament heating. Before obtaining the taper, the spectral behavior of the suspended core fiber is a multimode interference structure. When the taper is made, an intermodal interference between a few modes is observed. This effect is clearly visible for low taper core dimensions. Since the core and cladding do not collapse, two taper regions exist, one in the core and the other in the cladding. The cladding taper does not affect the light transmission, only the core is reduced to a microtaper. The spectral response of the microtaper based-suspended core fiber is similar to a beat of two interferometers. The strain is applied to the microtaper, and with the reduction in the transverse area, an increase in sensitivity is observed. When the taper is immersed in a liquid with a different index of refraction or subjected to temperature variations, no spectral change occurs.
- ItemCathode fall voltage of TIG arcs from a non-equilibrium arc model(Heidelberg : Springer, 2014) Uhrlandt, D.; Baeva, M.; Pipa, A.V.; Kozakov, R.; Gött, G.This work presents modelling results concerning a tungsten inert gas (TIG) welding arc. The model provides a consistent description of the free burning arc, the arc attachment and the electrodes. Thermal and chemical non-equilibrium is considered in the whole arc area, and a detailed model of the cathode space-charge sheath is included. The mechanisms in the cathode pre-sheath are treated in the framework of a non-equilibrium approach which is based on a two-fluid description of electrons and heavy particles and a simplified plasma chemistry of argon. A consistent determination of the electrode fall voltages and temperature distributions is achieved. The model is applied to arcs in pure argon at currents up to 250 A, whereby welding of a workpiece made of mild steel with a fixed burner is considered. Arc voltages in the range from 12 to 17 V are obtained at 50 at 250 A, respectively. The space-charge sheath voltage is found to be about 7 V and almost independent of the current. The corresponding temperatures of the cathode tip are in the range from 3,000 K to about 3,800 K. The results obtained are in a good agreement with measurements.