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- ItemCrystal structure of (2S,4S,7S)-7,7-dichloro-4-(1-chloro-1-methylethyl)-1- (2,2,2-trichloroethyl)bicyclo[4.1.0]heptane, C12H16Cl 6(Berlin : de Gruyter, 2009) Boualy, B.; el Firdoussi, L.; Ali, M.A.; Karim, A.; Spannenberg, A.C12H16Cl6, orthorhombic, P2 12121 (no. 19), a = 6.0742(3) Å, b = 9.7189(6) Å, c = 26.700(1) Å, V = 1576.2 Å3, Z = 4, Rgt(F) = 0.019, wRref(F2) = 0.045, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
- ItemDifferentialgeometrie im Grossen (hybrid meeting)(Zürich : EMS Publ. House, 2021) Hamenstädt, Ursula; Lang, Urs; Weinkove, BenThe field of classical differential geometry has expanded enormously over the last several decades, helped by the development of tools from neighboring fields such as partial differential equations, complex analysis and geometric topology. In the spirit of the previous meetings in the series, this meeting will bring together researchers from apparently separate subfields of differential geometry, but whose work is linked by common themes. In particular, this meeting will emphasize intrinsic geometric questions motivated by the classification and rigidity of global geometric structures and the interaction of curvature with the underlying geometry and topology.
- ItemSharp phase transition for Cox percolation(Berlin : Weierstraß-Institut für Angewandte Analysis und Stochastik, 2022) Hirsch, Christian; Jahnel, Benedikt; Muirhead, StephenWe prove the sharpness of the percolation phase transition for a class of Cox percolation models, i.e., models of continuum percolation in a random environment. The key requirements are that the environment has a finite range of dependence and satisfies a local boundedness condition, however the FKG inequality need not hold. The proof combines the OSSS inequality with a coarse-graining construction.
- ItemArbeitsgemeinschaft mit aktuellem Thema: Polylogarithms(Zürich : EMS Publ. House, 2004) Kings, Guido; Wildeshaus, Jörg[no abstract available]
- ItemEffects of (complementary) polyelectrolytes characteristics on composite calcium carbonate microparticles properties(Bucureşti : [Verlag nicht ermittelbar], 2017) Mic, Cristian Barbu; Mihai, Marcela; Varganici, Cristian Dragos; Schwarz, Simona; Scutaru, Dan; Simionescu, Bogdan C.This study follows the possibility to tune the thermal stability of some CaCO3/polymer composites by crystal growth from supersaturated solutions controlled by polymer structure or by using nonstoichiometric polyelectrolyte complexes (NPECs). As the ratio between the organic and inorganic parts in the composites controls the Ca2+/polymer network crosslinking density, the CaCO3/polymer weight ratio was kept constant at 50/1, varying the initial concentration of the polyanions solutions (0.05 or 0.06 wt.%), the NPECs molar ratio , n+/n- (0.2 or 0.4), or the inorganic precursors concentration (0.25 or 0.3 M). Poly(2-acrylamido-2-methylpropanesulfonic acid-co-acrylic acid) (PSA) and chondroitin-4-sulfate (CSA) were used as polyanions. Some NPEC dispersions, prepared with the same polyanions and poly(allylamine hydrochloride) (PAH), were also used for calcium carbonate crystallization. The characteristics of the prepared composites were investigated by scanning electron microscopy (SEM), flow particle image analysis (FPIA), particles charge density (CD), zeta-potential (ZP). The thermal stability of the composite particles was investigated as compared to bare CaCO3 microparticles prepared at the same initial inorganic concentrations.
- ItemSimulation of the future sea level contribution of Greenland with a new glacial system model(Katlenburg-Lindau : Copernicus, 2018) Calov, Reinhard; Beyer, Sebastian; Greve, Ralf; Beckmann, Johanna; Willeit, Matteo; Kleiner, Thomas; Rückamp, Martin; Humbert, Angelika; Ganopolski, AndreyWe introduce the coupled model of the Greenland glacial system IGLOO 1.0, including the polythermal ice sheet model SICOPOLIS (version 3.3) with hybrid dynamics, the model of basal hydrology HYDRO and a parameterization of submarine melt for marine-terminated outlet glaciers. The aim of this glacial system model is to gain a better understanding of the processes important for the future contribution of the Greenland ice sheet to sea level rise under future climate change scenarios. The ice sheet is initialized via a relaxation towards observed surface elevation, imposing the palaeo-surface temperature over the last glacial cycle. As a present-day reference, we use the 1961-1990 standard climatology derived from simulations of the regional atmosphere model MAR with ERA reanalysis boundary conditions. For the palaeo-part of the spin-up, we add the temperature anomaly derived from the GRIP ice core to the years 1961-1990 average surface temperature field. For our projections, we apply surface temperature and surface mass balance anomalies derived from RCP 4.5 and RCP 8.5 scenarios created by MAR with boundary conditions from simulations with three CMIP5 models. The hybrid ice sheet model is fully coupled with the model of basal hydrology. With this model and the MAR scenarios, we perform simulations to estimate the contribution of the Greenland ice sheet to future sea level rise until the end of the 21st and 23rd centuries. Further on, the impact of elevation-surface mass balance feedback, introduced via the MAR data, on future sea level rise is inspected. In our projections, we found the Greenland ice sheet to contribute between 1.9 and 13.0 cm to global sea level rise until the year 2100 and between 3.5 and 76.4 cm until the year 2300, including our simulated additional sea level rise due to elevation-surface mass balance feedback. Translated into additional sea level rise, the strength of this feedback in the year 2100 varies from 0.4 to 1.7 cm, and in the year 2300 it ranges from 1.7 to 21.8 cm. Additionally, taking the Helheim and Store glaciers as examples, we investigate the role of ocean warming and surface runoff change for the melting of outlet glaciers. It shows that ocean temperature and subglacial discharge are about equally important for the melting of the examined outlet glaciers.
- ItemInferring causation from time series in Earth system sciences([London] : Nature Publishing Group UK, 2019) Runge, Jakob; Bathiany, Sebastian; Bollt, Erik; Camps-Valls, Gustau; Coumou, Dim; Deyle, Ethan; Glymour, Clark; Kretschmer, Marlene; Mahecha, Miguel D.; Muñoz-Marí, Jordi; van Nes, Egbert H.; Peters, Jonas; Quax, Rick; Reichstein, Markus; Scheffer, Marten; Schölkopf, Bernhard; Spirtes, Peter; Sugihara, George; Sun, Jie; Zhang, Kun; Zscheischler, JakobThe heart of the scientific enterprise is a rational effort to understand the causes behind the phenomena we observe. In large-scale complex dynamical systems such as the Earth system, real experiments are rarely feasible. However, a rapidly increasing amount of observational and simulated data opens up the use of novel data-driven causal methods beyond the commonly adopted correlation techniques. Here, we give an overview of causal inference frameworks and identify promising generic application cases common in Earth system sciences and beyond. We discuss challenges and initiate the benchmark platform causeme.net to close the gap between method users and developers. © 2019, The Author(s).
- ItemThermoelectric Properties of N-Type Poly (Ether Ether Ketone)/Carbon Nanofiber Melt-Processed Composites(Basel : MDPI, 2022) Paleo, Antonio Jose; Krause, Beate; Soares, Delfim; Melle-Franco, Manuel; Muñoz, Enrique; Pötschke, Petra; Rocha, Ana MariaThe thermoelectric properties, at temperatures from 30 °C to 100 °C, of melt-processed poly(ether ether ketone) (PEEK) composites prepared with 10 wt.% of carbon nanofibers (CNFs) are discussed in this work. At 30 °C, the PEEK/CNF composites show an electrical conductivity (σ) of ~27 S m−1 and a Seebeck coefficient (S) of −3.4 μV K−1, which means that their majority charge carriers are electrons. The origin of this negative Seebeck is deduced because of the impurities present in the as-received CNFs, which may cause sharply varying and localized states at approximately 0.086 eV above the Fermi energy level (EF) of CNFs. Moreover, the lower S, in absolute value, found in PEEK/CNF composites, when compared with the S of as-received CNFs (−5.3 μV K−1), is attributed to a slight electron withdrawing from the external layers of CNFs by the PEEK matrix. At temperatures from 30 °C to 100 °C, the σ (T) of PEEK/CNF composites, in contrast to the σ (T) of as-received CNFs, shows a negative temperature effect, understood through the 3D variable-range hopping (VRH) model, as a thermally activated hopping mechanism across a random network of potential wells. Moreover, their nonlinear S (T) follows the same behavior reported before for polypropylene composites melt-processed with similar CNFs at the same interval of temperatures.
- ItemLi+/H+ exchange of Li7La3Zr2O12 single and polycrystals investigated by quantitative LIBS depth profiling(Cambridge : Royal Society of Chemistry, 2022) Smetaczek, Stefan; Limbeck, Andreas; Zeller, Veronika; Ring, Joseph; Ganschow, Steffen; Rettenwander, Daniel; Fleig, JürgenLi7La3Zr2O12 (LLZO) garnets are highly attractive to be used as solid electrolyte in solid-state Li batteries. However, LLZO suffers from chemical interaction with air and humidity, causing Li+/H+ exchange with detrimental implication on its performance, processing and scalability. To better understand the kinetics of the detrimental Li+/H+ exchange and its dependence on microstructural features, accelerated Li+/H+ exchange experiments were performed on single crystalline and polycrystalline LLZO, exposed for 80 minutes to 80 °C hot water. The resulting chemical changes were quantified by analytical methods, i.e. inductively coupled plasma optical emission spectroscopy (ICP-OES) and laser induced breakdown spectroscopy (LIBS). From the time dependence of the Li+ enrichment in the water, measured by ICP-OES, a bulk interdiffusion coefficient of Li+/H+ could be determined (7 × 10−17 m2 s−1 at 80 °C). Depth dependent concentrations were obtained from the LIBS data for both ions after establishing a calibration method enabling not only Li+ but also H+ quantification in the solid electrolyte. Short interdiffusion lengths in the 1 μm range are found for the single crystalline Ga:LLZO, in accordance with the measured bulk diffusion coefficient. In polycrystalline Ta:LLZO, however, very long diffusion tails in the 20 μm range and ion exchange fractions up to about 70% are observed. Those are attributed to fast ion interdiffusion along grain boundaries. The severe compositional changes also strongly affect the electrical properties measured by impedance spectroscopy. This study highlights that microstructural effects may be decisive for the Li+/H+ ion exchange kinetics of LLZO.
- ItemThe Mathematical, Computational and Biological Study of Vision(Oberwolfach-Walke : Mathematisches Forschungsinstitut Oberwolfach, 2001) von der Malsburg, Christoph; Mumford, David[no abstract available]