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End date: 2024 × Start date: 2020 × DDC: 500 × DDC: 600 × Type: article × Subject: nonhuman ×

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    Bioactive glass–ceramics containing fluorapatite, xonotlite, cuspidine and wollastonite form apatite faster than their corresponding glasses
    ([London] : Macmillan Publishers Limited, 2024) Kirste, Gloria; Contreras Jaimes, Altair; de Pablos-Martín, Araceli; de Souza e Silva, Juliana Martins; Massera, Jonathan; Hill, Robert G.; Brauer, Delia S.
    Crystallisation of bioactive glasses has been claimed to negatively affect the ion release from bioactive glasses. Here, we compare ion release and mineralisation in Tris–HCl buffer solution for a series of glass–ceramics and their parent glasses in the system SiO2–CaO–P2O5–CaF2. Time-resolved X-ray diffraction analysis of glass–ceramic degradation, including quantification of crystal fractions by full pattern refinement, show that the glass–ceramics precipitated apatite faster than the corresponding glasses, in agreement with faster ion release from the glass–ceramics. Imaging by transmission electron microscopy and X-ray nano-computed tomography suggest that this accelerated degradation may be caused by the presence of nano-sized channels along the internal crystal/glassy matrix interfaces. In addition, the presence of crystalline fluorapatite in the glass–ceramics facilitated apatite nucleation and crystallisation during immersion. These results suggest that the popular view of bioactive glass crystallisation being a disadvantage for degradation, apatite formation and, subsequently, bioactivity may depend on the actual system study and, thus, has to be reconsidered.
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    Yield trends, variability and stagnation analysis of major crops in France over more than a century
    ([London] : Macmillan Publishers Limited, part of Springer Nature, 2018) Schauberger, Bernhard; Ben-Ari, Tamara; Makowski, David; Kato, Tomomichi; Kato, Hiromi; Ciais, Philippe
    France is a major crop producer, with a production share of approx. 20% within the European Union. Yet, a discussion has recently started whether French yields are stagnating. While for wheat previous results are unanimously pointing to recent stagnation, there is contradictory evidence for maize and few to no results for other crops. Here we analyse a data set with more than 120,000 yield observations from 1900 to 2016 for ten crops (barley, durum and soft wheat, maize, oats, potatoes, rapeseed, sugar beet, sunflower and wine) in the 96 mainland French départements (NUTS3 administrative division). We dissect the evolution of yield trends over time and space, analyse yield variation and evaluate whether growth of yields has stalled in recent years. Yields have, on average across crops, multiplied four-fold over the course of the 20th century. While absolute yield variability has increased, the variation relative to the mean has halved – mean yields have increased faster than their variability. But growth of yields has stagnated since the 1990’s for winter wheat, barley, oats, durum wheat, sunflower and wine on at least 25% of their areas. Reaching yield potentials is unlikely as a cause for stagnation. Maize, in contrast, shows no evidence for stagnation.