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- ItemCarbon materials for stable Li metal anodes: Challenges, solutions, and outlook(Hoboken, NJ : Wiley, 2021) Lu, Q.; Jie, Y.; Meng, X.; Omar, A.; Mikhailova, D.; Cao, R.; Jiao, S.; Lu, Y.; Xu, Y.Lithium (Li) metal is regarded as the ultimate anode for next-generation Li-ion batteries due to its highest specific capacity and lowest electrochemical potential. However, the Li metal anode has limitations, including virtually infinite volume change, nonuniform Li deposition, and an unstable electrode–electrolyte interface, which lead to rapid capacity degradation and poor cycling stability, significantly hindering its practical application. To address these issues, intensive efforts have been devoted toward accommodating and guiding Li deposition as well as stabilizing the interface using various carbon materials, which have demonstrated excellent effectiveness, benefiting from their vast variety and excellent tunability of the structure–property relationship. This review is intended as a guide through the fundamental challenges of Li metal anodes to the corresponding solutions utilizing carbon materials. The specific functionalities and mechanisms of carbon materials for stabilizing Li metal anodes in these solutions are discussed in detail. Apart from the stabilization of the Li metal anode in liquid electrolytes, attention has also been paid to the review of anode-free Li metal batteries and solid-state batteries enabled by strategies based on carbon materials. Furthermore, we have reviewed the unresolved challenges and presented our outlook on the implementation of carbon materials for stabilizing Li metal anodes in practical applications.
- ItemArchitecture engineering of carbonaceous anodes for high‐rate potassium‐ion batteries(Hoboken, NJ : Wiley, 2021) Wu, Tianlai; Zhang, Weicai; Yang, Jiaying; Lu, Qiongqiong; Peng, Jing; Zheng, Mingtao; Xu, Fei; Liu, Yingliang; Liang, YeruThe limited lithium resource in earth's crust has stimulated the pursuit of alternative energy storage technologies to lithium‐ion battery. Potassium‐ion batteries (KIBs) are regarded as a kind of promising candidate for large‐scale energy storage owing to the high abundance and low cost of potassium resources. Nevertheless, further development and wide application of KIBs are still challenged by several obstacles, one of which is their fast capacity deterioration at high rates. A considerable amount of effort has recently been devoted to address this problem by developing advanced carbonaceous anode materials with diverse structures and morphologies. This review presents and highlights how the architecture engineering of carbonaceous anode materials gives rise to high‐rate performances for KIBs, and also the beneficial conceptions are consciously extracted from the recent progress. Particularly, basic insights into the recent engineering strategies, structural innovation, and the related advances of carbonaceous anodes for high‐rate KIBs are under specific concerns. Based on the achievements attained so far, a perspective on the foregoing, and proposed possible directions, and avenues for designing high‐rate anodes, are presented finally.
- ItemFlexible MXene films for batteries and beyond(Hoboken, NJ : Wiley, 2022) Huang, Yang; Lu, Qiongqiong; Wu, Dianlun; Jiang, Yue; Liu, Zhenjie; Chen, Bin; Zhu, Minshen; Schmidt, Oliver G.MXenes add dozens of metallic conductors to the family of two-dimensional (2D) materials. A top-down synthesis approach removing A-layer atoms (e.g., Al, Si, and Ga) in MAX phases to produce 2D flakes attaches various surface terminations to MXenes. With these terminations, MXenes show tunable properties, promising a range of applications from energy storage devices to electronics, including sensors, transistors, and antennas. MXenes are also excellent building blocks to create flexible films used for flexible and wearable devices. This article summarizes the synthesis of MXene flakes and highlights aspects that need attention for flexible devices. Rather than listing the development of energy storage devices in detail, we focus on the main challenges of and solutions for constructing high-performance devices. Moreover, we show the applications of MXene films in electronics to call on designs to construct a complete system based on MXene with good flexibility, which consists of a power source, sensors, transistors, and wireless communications.
- ItemSynthesis and characterization of poly(1,2,3-triazole)s with inherent high sulfur content for optical applications(Hoboken, NJ : Wiley, 2023) Mazumder, Kajari; Komber, Hartmut; Bittrich, Eva; Voit, Brigitte; Banerjee, SusantaThe synthesis of solution-processable sulfur-containing polytriazoles for optoelectronic applications is a relatively less explored domain in polymer research. The synthesis of novel bifunctional (DA) and trifunctional (TA) azido-monomers with inherent high sulfur content and of organo-soluble high refractive index poly(1,2,3-triazole)s using the azido-monomers via Cu(I) assisted click polymerization reactions are reported in this work. The azido-monomers were synthesized by the conversion of previously reported amine-functionalized compounds to azides using azidotrimethylsilane in a polar aprotic solvent. Dialkyne monomers were also synthesized and reacted with the azides to prepare a series of five linear and two hyperbranched poly(1,2,3-triazole)s. Fourier transform infrared spectroscopy, nuclear magnetic resonance spectroscopy, differential scanning calorimetry and thermogravimetric analysis were used to characterize the synthesized polymers. It was also demonstrated that the use of the trifunctional azide in optimized conditions resulted in increased solubility of an otherwise insoluble linear poly(1,2,3-triazole). The optical characterization of the polymers was carried out on thin polymer films with thickness in the nanometer range, which were successfully prepared by spin-coating on silicon wafers. It was found that the increase in the sulfur and aromatic content in the polymer backbone successfully increased the refractive index of the polymers up to 1.743 at 589 nm.
- ItemInvestigating Mesozoic Climate Trends and Sensitivities With a Large Ensemble of Climate Model Simulations(Hoboken, NJ : Wiley, 2021) Landwehrs, Jan; Feulner, Georg; Petri, Stefan; Sames, Benjamin; Wagreich, MichaelThe Mesozoic era (∼252 to 66 million years ago) was a key interval in Earth's evolution toward its modern state, witnessing the breakup of the supercontinent Pangaea and significant biotic innovations like the early evolution of mammals. Plate tectonic dynamics drove a fundamental climatic transition from the early Mesozoic supercontinent toward the Late Cretaceous fragmented continental configuration. Here, key aspects of Mesozoic long-term environmental changes are assessed in a climate model ensemble framework. We analyze so far the most extended ensemble of equilibrium climate states simulated for evolving Mesozoic boundary conditions covering the period from 255 to 60 Ma in 5 Myr timesteps. Global mean temperatures are generally found to be elevated above the present and exhibit a baseline warming trend driven by rising sea levels and increasing solar luminosity. Warm (Triassic and mid-Cretaceous) and cool (Jurassic and end-Cretaceous) anomalies result from pCO2 changes indicated by different reconstructions. Seasonal and zonal temperature contrasts as well as continental aridity show an overall decrease from the Late Triassic-Early Jurassic to the Late Cretaceous. Meridional temperature gradients are reduced at higher global temperatures and less land area in the high latitudes. With systematic sensitivity experiments, the influence of paleogeography, sea level, vegetation patterns, pCO2, solar luminosity, and orbital configuration on these trends is investigated. For example, long-term seasonality trends are driven by paleogeography, but orbital cycles could have had similar-scale effects on shorter timescales. Global mean temperatures, continental humidity, and meridional temperature gradients are, however, also strongly affected by pCO2.
- ItemEvidence for the In‐Situ Generation of Plasma Depletion Structures Over the Transition Region of Geomagnetic Low‐Mid Latitude(Hoboken, NJ : Wiley, 2021) Sivakandan, M.; Mondal, S.; Sarkhel, S.; Chakrabarty, D.; Sunil Krishna, M.V.; Upadhayaya, A.K.; Shinbori, A.; Sori, T.; Kannaujiya, S.; Champati Ray, P.K.On a geomagnetic quiet night of October 29, 2018, we captured an observational evidence of the onset of dark band structures within the field-of-view of an all-sky airglow imager operating at 630.0 nm over a geomagnetic low-mid latitude transition region, Hanle, Leh Ladakh. Simultaneous ionosonde observations over New Delhi shows the occurrence of spread-F in the ionograms. Additionally, virtual and peak height indicate vertical upliftment in the F layer altitude and reduction in the ionospheric peak frequency were also observed when the dark band pass through the ionosonde location. All these results confirmed that the observed depletions are indeed associated with ionospheric F region plasma irregularities. The rate of total electron content index (ROTI) indicates the absence of plasma bubble activities over the equatorial/low latitude region which confirms that the observed event is a mid-latitude plasma depletion. Our calculations reveal that the growth time of the plasma depletion is ∼2 h if one considers only the Perkins instability mechanism. This is not consistent with the present observations as the plasma depletion developed within ∼25 min. By invoking possible Es layer instabilities and associated E-F region coupling, we show that the growth rate increases roughly by an order of magnitude. This strongly suggests that the Cosgrove and Tsunoda mechanism may be simultaneously operational in this case. Furthermore, it is also suggested that reduced F region flux-tube integrated conductivity in the southern part of onset region created conducive background conditions for the growth of the plasma depletion on this night.
- ItemMulti‐Point Measurements of the Plasma Properties Inside an Aurora From the SPIDER Sounding Rocket(Hoboken, NJ : Wiley, 2021) Giono, Gabriel; Ivchenko, Nickolay; Sergienko, Tima; Brändström, UrbanThe Small Payloads for Investigation of Disturbances in Electrojet by Rockets (SPIDER) sounding rocket was launched on February 2nd, 2016 (21:09 UT), deploying 10 free falling units (FFUs) inside a westward traveling auroral surge. Each FFUs deployed spherical electric field and Langmuir probes on wire-booms, providing in situ multi-point recordings of the electric field and plasma properties. The analytical retrieval of the plasma parameters, namely the electron density, electron temperature and plasma potential, from the Langmuir probe measurements was non-trivial due to sheath effects and detailed explanation are discussed in this article. An empirical assumption on the sheath thickness was required, which was confirmed by simulating the plasma environment around the FFU using the Spacecraft Plasma Interaction Software (SPIS). In addition, the retrieved electron density and temperature are also in agreement with the simultaneous incoherent scatter radar measurements from the EISCAT facility. These two independent confirmations provided a good level of confidence in the plasma parameters obtained from the FFUs, and events observed during the flight are discussed in more details. Hints of drift-wave instabilities and increased currents inside a region of enhanced density were observed by the FFUs.
- ItemHemispheric and Seasonal Contrast in Cloud Thermodynamic Phase From A‐Train Spaceborne Instruments(Hoboken, NJ : Wiley, 2021) Villanueva, Diego; Senf, Fabian; Tegen, InaAerosol-cloud interactions are an important source of uncertainty in current climate models. To understand and quantify the influence of ice-nucleating particles in cloud glaciation, it is crucial to have a reliable estimation of the hemispheric and seasonal contrast in cloud top phase, which is believed to result from the higher dust aerosol loading in boreal spring. For this reason, we locate and quantify these contrasts by combining three different A-Train cloud-phase products for the period 2007–2010. These products rely on a spaceborne lidar, a lidar-radar synergy, and a radiometer-polarimeter synergy. We show that the cloud-phase from the product combination is more reliable and that the estimation of the hemispheric and seasonal contrast has a lower error compared to the individual products. To quantify the contrast in cloud-phase, we use the hemispheric difference in ice cloud frequency normalized by the liquid cloud frequency in the southern hemisphere between −42 °C and 0 °C. In the midlatitudes, from −15 to −30 °C, the hemispheric contrasts increase with decreasing temperature. At −30 °C, the hemispheric contrast varies from 29% to 39% for the individual cloud-phase products and from 52% to 73% for the product combination. Similarly, in the northern hemisphere, we assess the seasonal contrast between spring and fall normalized by the liquid cloud frequency during fall. At −30 °C, the seasonal contrast ranges from 21% to 39% for the individual cloud-phase products and from 54% to 75% for the product combination.
- ItemSources, Occurrence and Characteristics of Fluorescent Biological Aerosol Particles Measured Over the Pristine Southern Ocean(Hoboken, NJ : Wiley, 2021) Moallemi, Alireza; Landwehr, Sebastian; Robinson, Charlotte; Simó, Rafel; Zamanillo, Marina; Chen, Gang; Baccarini, Andrea; Schnaiter, Martin; Henning, Silvia; Modini, Robin L.; Gysel-Beer, Martin; Schmale, JuliaIn this study, we investigate the occurrence of primary biological aerosol particles (PBAP) over all sectors of the Southern Ocean (SO) based on a 90-day data set collected during the Antarctic Circumnavigation Expedition (ACE) in austral summer 2016-2017. Super-micrometer PBAP (1-16 µm diameter) were measured by a wide band integrated bioaerosol sensor (WIBS-4). Low (3σ) and high (9σ) fluorescence thresholds are used to obtain statistics on fluorescent and hyper-fluorescent PBAP, respectively. Our focus is on data obtained over the pristine ocean, that is, more than 200 km away from land. The results indicate that (hyper-)fluorescent PBAP are correlated to atmospheric variables associated with sea spray aerosol (SSA) particles (wind speed, total super-micrometer aerosol number concentration, chloride and sodium concentrations). This suggests that a main source of PBAP over the SO is SSA. The median percentage contribution of fluorescent and hyper-fluorescent PBAP to super-micrometer SSA was 1.6% and 0.13%, respectively. We demonstrate that the fraction of (hyper-)fluorescent PBAP to total super-micrometer particles positively correlates with concentrations of bacteria and several taxa of pythoplankton measured in seawater, indicating that marine biota concentrations modulate the PBAP source flux. We investigate the fluorescent properties of (hyper-)fluorescent PBAP for several events that occurred near land masses. We find that the fluorescence signal characteristics of particles near land is much more variable than over the pristine ocean. We conclude that the source and concentration of fluorescent PBAP over the open ocean is similar across all sampled sectors of the SO.
- ItemUsing Principal Component Analysis of Satellite and Ground Magnetic Data to Model the Equatorial Electrojet and Derive Its Tidal Composition(Hoboken, NJ : Wiley, 2022) Soares, Gabriel; Yamazaki, Yosuke; Morschhauser, Achim; Matzka, Jürgen; Pinheiro, Katia J.; Stolle, Claudia; Alken, Patrick; Yoshikawa, Akimasa; Hozumi, Kornyanat; Kulkarni, Atul; Supnithi, PornchaiThe intensity of the equatorial electrojet (EEJ) shows temporal and spatial variability that is not yet fully understood nor accurately modeled. Atmospheric solar tides are among the main drivers of this variability but determining different tidal components and their respective time series is challenging. It requires good temporal and spatial coverage with observations, which, previously could only be achieved by accumulating data over many years. Here, we propose a new technique for modeling the EEJ based on principal component analysis (PCA) of a hybrid ground-satellite geomagnetic data set. The proposed PCA-based model (PCEEJ) represents the observed EEJ better than the climatological EEJM-2 model, especially when there is good local time separation among the satellites involved. The amplitudes of various solar tidal modes are determined from PCEEJ based tidal equation fitting. This allows to evaluate interannual and intraannual changes of solar tidal signatures in the EEJ. On average, the obtained time series of migrating and nonmigrating tides agree with the average climatology available from earlier work. A comparison of tidal signatures in the EEJ with tides derived from neutral atmosphere temperature observations show a remarkable correlation for nonmigrating tides such as DE3, DE2, DE4, and SW4. The results indicate that it is possible to obtain a meaningful EEJ spectrum related to solar tides for a relatively short time interval of 70 days.