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- ItemLifetime vs. rate capability: Understanding the role of FEC and VC in high-energy Li-ion batteries with nano-silicon anodes(Amsterdam : Elsevier, 2016) Jaumann, Tony; Balach, Juan; Langklotz, Ulrike; Sauchuk, Viktar; Fritsch, Marco; Michaelis, Alexander; Teltevskij, Valerij; Mikhailova, Daria; Oswald, Steffen; Klose, Markus; Stephani, Guenter; Hauser, Ralf; Eckert, Jürgen; Giebeler, LarsFluoroethylene carbonate (FEC) and vinylene carbonate (VC) are the most frequently used electrolyte components to enhance the lifetime of anode materials in Li-ion batteries, but for silicon it is still ambiguous when FEC or VC is more beneficial. Herein, a nanostructured silicon/carbon anode derived from low-cost HSiCl3 is tailored by the rational choice of the electrolyte component, to obtain an anode material outperforming current complex silicon structures. We demonstrate highly reversible areal capacities of up to 5 mA h/cm2 at 4.4 mg/cm2 mass loading, a specific capacity of 1280 mA h/gElectrode, a capacity retention of 81% after 500 deep-discharge cycles versus lithium metal and successful full-cell tests with high-voltage cathodes meeting the requirements for real application. Electrochemical impedance spectroscopy and post-mortem investigation provide new insights in tailoring the interfacial properties of silicon-based anodes for high performance anode materials based on an alloying mechanism with large volume changes. The role of fluorine in the FEC-derived interfacial layer is discussed in comparison with the VC-derived layer and possible degradation mechanisms are proposed. We believe that this study gives a valuable understanding and provides new strategies on the facile use of additives for highly reversible silicon anodes in Li-ion batteries.
- ItemFossil-fueled development (SSP5): An energy and resource intensive scenario for the 21st century(Amsterdam : Elsevier, 2016) Kriegler, Elmar; Bauer, Nico; Popp, Alexander; Humpenöder, Florian; Leimbach, Marian; Strefler, Jessica; Baumstark, Lavinia; Bodirsky, Benjamin Leon; Hilaire, Jérôme; Klein, David; Mouratiadou, Ioanna; Weindl, Isabelle; Bertram, Christoph; Dietrich, Jan-Philipp; Luderer, Gunnar; Pehl, Michaja; Pietzcker, Robert; Piontek, Franziska; Lotze-Campen, Hermann; Biewald, Anne; Bonsch, Markus; Giannousakis, Anastasis; Kreidenweis, Ulrich; Müller, Christoph; Rolinski, Susanne; Schultes, Anselm; Schwanitz, Jana; Stevanovic, Miodrag; Calvin, Katherine; Emmerling, Johannes; Fujimori, Shinichiro; Edenhofer, OttmarThis paper presents a set of energy and resource intensive scenarios based on the concept of Shared Socio-Economic Pathways (SSPs). The scenario family is characterized by rapid and fossil-fueled development with high socio-economic challenges to mitigation and low socio-economic challenges to adaptation (SSP5). A special focus is placed on the SSP5 marker scenario developed by the REMIND-MAgPIE integrated assessment modeling framework. The SSP5 baseline scenarios exhibit very high levels of fossil fuel use, up to a doubling of global food demand, and up to a tripling of energy demand and greenhouse gas emissions over the course of the century, marking the upper end of the scenario literature in several dimensions. These scenarios are currently the only SSP scenarios that result in a radiative forcing pathway as high as the highest Representative Concentration Pathway (RCP8.5). This paper further investigates the direct impact of mitigation policies on the SSP5 energy, land and emissions dynamics confirming high socio-economic challenges to mitigation in SSP5. Nonetheless, mitigation policies reaching climate forcing levels as low as in the lowest Representative Concentration Pathway (RCP2.6) are accessible in SSP5. The SSP5 scenarios presented in this paper aim to provide useful reference points for future climate change, climate impact, adaption and mitigation analysis, and broader questions of sustainable development.
- ItemEnergy, land-use and greenhouse gas emissions trajectories under a green growth paradigm(Amsterdam : Elsevier, 2016) van Vuuren, Detlef P.; Stehfest, Elke; Gernaat, David E.H.J.; Doelman, Jonathan C.; van den Berg, Maarten; Harmsen, Mathijs; de Boer, Harmen Sytze; Bouwman, Lex F.; Daioglou, Vassilis; Edelenbosch, Oreane Y.; Girod, Bastien; Kram, Tom; Lassaletta, Luis; Lucas, Paul L.; van Meijl, Hans; Müller, Christoph; van Ruijven, Bas J.; van der Sluis, Sietske; Tabeau, AndrzejThis paper describes the possible developments in global energy use and production, land use, emissions and climate changes following the SSP1 storyline, a development consistent with the green growth (or sustainable development) paradigm (a more inclusive development respecting environmental boundaries). The results are based on the implementation using the IMAGE 3.0 integrated assessment model and are compared with a) other IMAGE implementations of the SSPs (SSP2 and SSP3) and b) the SSP1 implementation of other integrated assessment models. The results show that a combination of resource efficiency, preferences for sustainable production methods and investment in human development could lead to a strong transition towards a more renewable energy supply, less land use and lower anthropogenic greenhouse gas emissions in 2100 than in 2010, even in the absence of explicit climate policies. At the same time, climate policy would still be needed to reduce emissions further, in order to reduce the projected increase of global mean temperature from 3 °C (SSP1 reference scenario) to 2 or 1.5 °C (in line with current policy targets). The SSP1 storyline could be a basis for further discussions on how climate policy can be combined with achieving other societal goals.
- ItemThe Shared Socioeconomic Pathways and their energy, land use, and greenhouse gas emissions implications: An overview(Amsterdam : Elsevier, 2016) Riahi, Keywan; van Vuuren, Detlef P.; Kriegler, Elmar; Edmonds, Jae; O’Neill, Brian C.; Fujimori, Shinichiro; Bauer, Nico; Calvin, Katherine; Dellink, Rob; Fricko, Oliver; Lutz, Wolfgang; Popp, Alexander; Crespo Cuaresma, Jesus; KC, Samir; Leimbach, Marian; Jiang, Leiwen; Kram, Tom; Rao, Shilpa; Emmerling, Johannes; Ebi, Kristie; Hasegawa, Tomoko; Havlik, Petr; Humpenöder, Florian; Aleluia Da Silva, Lara; Smith, Steve; Stehfest, Elke; Bosetti, Valentina; Eom, Jiyong; Gernaat, David; Masui, Toshihiko; Rogelj, Joeri; Strefler, Jessica; Drouet, Laurent; Krey, Volker; Luderer, Gunnar; Harmsen, Mathijs; Takahashi, Kiyoshi; Baumstark, Lavinia; Doelman, Jonathan C.; Kainuma, Mikiko; Klimont, Zbigniew; Marangoni, Giacomo; Lotze-Campen, Hermann; Obersteiner, Michael; Tabeau, Andrzej; Tavoni, MassimoThis paper presents the overview of the Shared Socioeconomic Pathways (SSPs) and their energy, land use, and emissions implications. The SSPs are part of a new scenario framework, established by the climate change research community in order to facilitate the integrated analysis of future climate impacts, vulnerabilities, adaptation, and mitigation. The pathways were developed over the last years as a joint community effort and describe plausible major global developments that together would lead in the future to different challenges for mitigation and adaptation to climate change. The SSPs are based on five narratives describing alternative socio-economic developments, including sustainable development, regional rivalry, inequality, fossil-fueled development, and middle-of-the-road development. The long-term demographic and economic projections of the SSPs depict a wide uncertainty range consistent with the scenario literature. A multi-model approach was used for the elaboration of the energy, land-use and the emissions trajectories of SSP-based scenarios. The baseline scenarios lead to global energy consumption of 400–1200 EJ in 2100, and feature vastly different land-use dynamics, ranging from a possible reduction in cropland area up to a massive expansion by more than 700 million hectares by 2100. The associated annual CO2 emissions of the baseline scenarios range from about 25 GtCO2 to more than 120 GtCO2 per year by 2100. With respect to mitigation, we find that associated costs strongly depend on three factors: (1) the policy assumptions, (2) the socio-economic narrative, and (3) the stringency of the target. The carbon price for reaching the target of 2.6 W/m2 that is consistent with a temperature change limit of 2 °C, differs in our analysis thus by about a factor of three across the SSP marker scenarios. Moreover, many models could not reach this target from the SSPs with high mitigation challenges. While the SSPs were designed to represent different mitigation and adaptation challenges, the resulting narratives and quantifications span a wide range of different futures broadly representative of the current literature. This allows their subsequent use and development in new assessments and research projects. Critical next steps for the community scenario process will, among others, involve regional and sectoral extensions, further elaboration of the adaptation and impacts dimension, as well as employing the SSP scenarios with the new generation of earth system models as part of the 6th climate model intercomparison project (CMIP6).
- ItemFuture air pollution in the Shared Socio-economic Pathways(Amsterdam : Elsevier, 2016) Rao, Shilpa; Klimont, Zbigniew; Smith, Steven J.; Van Dingenen, Rita; Dentener, Frank; Bouwman, Lex; Riahi, Keywan; Amann, Markus; Bodirsky, Benjamin Leon; van Vuuren, Detlef P.; Aleluia Reis, Lara; Calvin, Katherine; Drouet, Laurent; Fricko, Oliver; Fujimori, Shinichiro; Gernaat, David; Havlik, Petr; Harmsen, Mathijs; Hasegawa, Tomoko; Heyes, Chris; Hilaire, Jérôme; Luderer, Gunnar; Masui, Toshihiko; Stehfest, Elke; Strefler, Jessica; van der Sluis, Sietske; Tavoni, MassimoEmissions of air pollutants such as sulfur and nitrogen oxides and particulates have significant health impacts as well as effects on natural and anthropogenic ecosystems. These same emissions also can change atmospheric chemistry and the planetary energy balance, thereby impacting global and regional climate. Long-term scenarios for air pollutant emissions are needed as inputs to global climate and chemistry models, and for analysis linking air pollutant impacts across sectors. In this paper we present methodology and results for air pollutant emissions in Shared Socioeconomic Pathways (SSP) scenarios. We first present a set of three air pollution narratives that describe high, central, and low pollution control ambitions over the 21st century. These narratives are then translated into quantitative guidance for use in integrated assessment models. The resulting pollutant emission trajectories under the SSP scenarios cover a wider range than the scenarios used in previous international climate model comparisons. In the SSP3 and SSP4 scenarios, where economic, institutional and technological limitations slow air quality improvements, global pollutant emissions over the 21st century can be comparable to current levels. Pollutant emissions in the SSP1 scenarios fall to low levels due to the assumption of technological advances and successful global action to control emissions.
- ItemFuture growth patterns of world regions – A GDP scenario approach(Amsterdam : Elsevier, 2015) Leimbach, Marian; Kriegler, Elmar; Roming, Niklas; Schwanitz, JanaGlobal GDP projections for the 21st century are needed for the exploration of long-term global environmental problems, in particular climate change. Greenhouse gas emissions as well as climate change mitigation and adaption capacities strongly depend on growth of per capita income. However, long-term economic projections are highly uncertain. This paper provides five new long-term economic scenarios as part of the newly developed shared socio-economic pathways (SSPs) which represent a set of widely diverging narratives. A method of GDP scenario building is presented that is based on assumptions about technological progress, and human and physical capital formation as major drivers of long-term GDP per capita growth. The impact of these drivers differs significantly between different shared socio-economic pathways and is traced back to the underlying narratives and the associated population and education scenarios. In a highly fragmented world, technological and knowledge spillovers are low. Hence, the growth impact of technological progress and human capital is comparatively low, and per capita income diverges between world regions. These factors play a much larger role in globalization scenarios, leading to higher economic growth and stronger convergence between world regions. At the global average, per capita GDP is projected to grow annually in a range between 1.0% (SSP3) and 2.8% (SSP5) from 2010 to 2100. While this covers a large portion of variety in future global economic growth projections, plausible lower and higher growth projections may still be conceivable. The GDP projections are put into the context of historic patterns of economic growth (stylized facts), and their sensitivity to key assumptions is explored.
- ItemChallenges for developing national climate services – Poland and Norway(Amsterdam : Elsevier, 2017) Kundzewicz, Zbigniew W.; Førland, Eirik J.; Piniewski, MikołajThis contribution discusses the challenges for developing national climate services in two countries with high fossil fuel production – Poland (coal) and Norway (oil and gas). Both countries, Poland and Norway, have highly developed weather services, but largely differ on climate services. Since empirical and dynamical downscaling of climate models started in Norway over 20 years ago and meteorological and hydrological institutions in Oslo and Bergen have been collaborating on tailoring and disseminating downscaled climate projections to the Norwegian society, climate services are now well developed in Norway. The Norwegian Centre for Climate Services (NCCS) was established in 2011. In contrast, climate services in Poland, in the international understanding, do not exist. Actually, Poland is not an exception, as compared to other Central and Eastern European countries, many of which neither have their national climate services, nor are really interested in European climate services disseminated via common EU initiatives. It is worth posing a question – can Poland learn from Norway as regards climate services? This contribution is based on results of the CHASE-PL (Climate change impact assessment for selected sectors in Poland) project, carried out in the framework of the Polish – Norwegian Research Programme. The information generated within the Polish-Norwegian CHASE-PL project that is being broadly disseminated in Poland can be considered as a substitute for information delivered in other countries by climate services.
- ItemSimulation of flood hazard and risk in the Danube basin with the Future Danube Model(Amsterdam : Elsevier, 2018) Hattermann, Fred F.; Wortmann, Michel; Liersch, Stefan; Toumi, Ralf; Sparks, Nathan; Genillard, Christopher; Schröter, Kai; Steinhausen, Max; Gyalai-Korpos, Miklós; Máté, Kinga; Hayes, Ben; del RocÃo Rivas López, MarÃa; Rácz, Tibor; Nielsen, Marie R.; Kaspersen, Per S.; Drews, MartinMajor river and flash flood events have accumulated in Central and Eastern Europe over the last decade reminding the public as well as the insurance sector that climate related risks are likely to become even more damaging and prevalent as climate patterns change. However, information about current and future hydro-climatic extremes is often not available. The Future Danube Model (FDM) is an end-user driven multi-hazard and risk model suite for the Danube region that has been developed to provide climate services related to perils such as heavy precipitation, heat waves, floods, and droughts under recent and scenario conditions. As a result, it provides spatially consistent information on extreme events and natural resources throughout the entire Danube catchment. It can be used to quantify climate risks, to support the implementation of the EU framework directives, for climate informed urban and land use planning, water resources management, and for climate proofing of large scale infrastructural planning including cost benefit analysis. The model suite consists of five individual and exchangeable modules: a weather and climate module, a hydrological module, a risk module, an adaptation module, and a web-based visualization module. They are linked in such a way that output from one module can either be used standalone or fed into subsequent modules. The utility of the tool has been tested by experts and stakeholders. The results show that more and more intense hydrological extremes are likely to occur under climate scenario conditions, e.g. higher order floods may occur more frequently.