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- ItemFigures in Scientific Open Access Publications(New York, NY : Springer, 2018) Sohmen, Lucia; Charbonnier, Jean; Blümel, Ina; Wartena, Christian; Heller, Lambert; Méndez, E.; Crestani, F.; Ribeiro, C.; David, G.; Lopes, J.This paper summarizes the results of a comprehensive statistical analysis on a corpus of open access articles and contained figures. It gives an insight into quantitative relationships between illustrations or types of illustrations, caption lengths, subjects, publishers, author affiliations, article citations and others.
- ItemMethods to characterize the dispersability of carbon nanotubes and their length distribution(Weinheim : Wiley-VCH Verl., 2012) Krause, Beate; Mende, Mandy; Petzold, Gudrun; Boldt, Regine; Pötschke, PetraTwo main properties of carbon nanotube (CNT) materials are discussed in this contribution. First, a method to characterize the dispersability of CNT materials in aqueous surfactant solutions in presented, which also allows conclusions towards the dispersability in other media, like polymer melts. On the other hand it is shown, how the length of CNTs before and after processing, e.g., after melt mixing with thermoplastics, can be quantified. Both methods are illustrated with examples and the practical relevance is shown. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
- ItemAudio Ontologies for Intangible Cultural Heritage(Bramhall, Stockport ; EasyChair Ltd., 2022-04-12) Tan, Mary Ann; Posthumus, Etienne; Sack, HaraldCultural heritage portals often contain intangible objects digitized as audio files. This paper presents and discusses the adaptation of existing audio ontologies intended for non-cultural heritage applications. The resulting alignment of the German Digital Library-Europeana Data Model (DDB-EDM) with Music Ontology (MO) and Audio Commons Ontology (ACO) is presented.
- ItemElectrical, mechanical, and glass transition behavior of polycarbonate-based nanocomposites with different multi-walled carbon nanotubes(Oxford : Elsevier Science, 2011) Castillo, Frank Yepez; Socher, Robert; Krause, Beate; Headrick, Robert; Grady, Brian P.; Prada-Silvy, Ricardo; Pötschke, PetraFive commercially available multi-walled carbon nanotubes (MWNTs), with different characteristics, were melt mixed with polycarbonate (PC) in a twin-screw micro compounder to obtain nanocomposites containing 0.25-3.0 wt.% MWNT. The electrical properties of the composites were assessed using bulk electrical conductivity measurements, the mechanical properties of the composites were evaluated using tensile tests and dynamic mechanical analysis (DMA), and the thermal properties of the composites were investigated using differential scanning calorimetry (DSC). Electrical percolation thresholds (pcs) were observed between 0.28 wt.% and 0.60 wt.%, which are comparable with other well-dispersed melt mixed materials. Based on measurements of diameter and length distributions of unprocessed tubes it was found that nanotubes with high aspect ratios exhibited lower pcs, although one sample did show higher pc than expected (based on aspect ratio) which was attributed to poorer dispersion achieved during mixing. The stress-strain behavior of the composites is only slightly altered with CNT addition; however, the strain at break is decreased even at low loadings. DMA tests suggest the formation of a combined polymer-CNT continuous network evidenced by measurable storage moduli at temperatures above the glass transition temperature (T g), consistent with a mild reinforcement effect. The composites showed lower glass transition temperatures than that of pure PC. Lowering of the height of the tanδ peak from DMA and reductions in the heat capacity change at the glass transition from DSC indicate that MWNTs reduced the amount of polymer material that participates in the glass transition of the composites, consistent with immobilization of polymer at the nanotube interface. © 2011 Elsevier Ltd. All rights reserved.
- ItemAn updated micromechanical model based on morphological characterization of carbon nanotube nanocomposites(Oxford [u.a.] : Elsevier, 2017) Talò, Michela; Krause, Beate; Pionteck, Jürgen; Lanzara, Giulia; Lacarbonara, WalterBy leveraging on extensive morphological analysis of carbon nanotube nanocomposites, an update of the Eshelby-Mori-Tanaka method is proposed for a more accurate estimation of the nanocomposites effective elastic response. The experimental results are employed to overcome the main modeling limitations inherent in most common micromechanical theories, such as the perfect dispersion of the nanofiller and the uniformity of the nanofiller's aspect ratio within the nanocomposite. The actual variability of the CNTs aspect ratio and the CNTs degree of dispersion are experimentally measured and introduced in the proposed model by averaging the Eshelby tensor over the actual CNT lengths distribution and by accounting for the effective CNT volume fraction. The effects of the nanofiller morphology on the mechanical response of three different thermoplastic nanocomposites with low- and high-aspect ratio CNTs are explored, and monotonic tensile tests are performed to validate the predictions of the proposed model. A good agreement is found between the predicted nanocomposites elastic moduli and the experimental data.
- ItemThe effect of branched carbon nanotubes as reinforcing nano-filler in polymer nanocomposites(London : Elsevier, 2022) Thompson, S.M.; Talò, M.; Krause, Beate; Janke, A.; Lanzerotti, M.; Capps, J.; Lanzara, G.; Lacarbonara, W.This work discusses the mechanical and dissipative properties of nanocomposite materials made of a high-performance thermoplastic polymer (polybutylene terephthalate, PBT) integrated with branched carbon nanotubes (bCNTs) as nanofiller. The storage and loss moduli as well as the loss factor/damping ratio of the nanocomposites are experimentally characterized for increasing bCNT weight fractions (wt% bCNT) upon variations of the input cyclic strain amplitude and of the input frequency, respectively. The trends obtained for the nanocomposites mechanical properties indicate improvements both in storage and loss modulus by increasing the bCNT weight fraction from 0.5% to 2%. The striking differences between the damping capacities exhibited by CNT/polymer and bCNT/polymer nanocomposites are discussed to shed light onto the different underlined mechanics of the nanocomposites. Due to the stick–slip relative sliding motion of the polymer chains with respect to the straight CNTs, CNT/PBT nanocomposites are known to exhibit a peak in the damping vs. strain amplitude curves, past which, the damping capacity shows a monotonically increasing trend due to the conjectured sliding of the polymer crystals. On the other hand, we show for the first time that bCNT/PBT nanocomposites do not exhibit a peak in the damping capacity but rather a plateau after an initial drop at low strains. This behavior is attributed to the much reduced mobility of the branched CNTs and the lack of formation of crystalline structures around the bCNTs.
- ItemConcept for Setting up an LTA Working Group in the NFDI Section "Common Infrastructures"(Zenodo, 2022-04-12) Bach, Felix; Degkwitz, Andreas; Horstmann, Wolfram; Leinen, Peter; Puchta, Michael; Stäcker, ThomasNFDI consortia have a variety of disparate and distributed information infrastructures, many of which are as yet only loosely or poorly connected. A major goal is to create a Research Data Commons (RDC) . The RDC concept1 includes, for example, shared cloud services, an application layer with access to high-performance computing (HPC), collaborative workspaces, terminology services, and a common authentication and authorization infrastructure (AAI). The necessary interoperability of services requires, in particular, agreement on protocols and standards, the specification of workflows and interfaces, and the definition of long-term sustainable responsibilities for overarching services and deliverables. Infrastructure components are often well-tested in NFDI on a domain-specific basis, but are quite heterogeneous and diverse between domains. LTA for digital resources has been a recurring problem for well over 30 years and has not been conclusively solved to date, getting urgency with the exponential growth of research data, whether it involves demands from funders - the DFG requires 10 years of retention - or digital artifacts that must be preserved indefinitely as digital cultural heritage. Against this background, the integration of the LTA into the RDC of the NFDI is an urgent desideratum in order to be able to guarantee the permanent usability of research data. A distinction must be2 made between the archiving of the digital objects as bitstreams (this can be numeric or textual data or complex objects such as models), which represents a first step towards long-term usability, and the archiving of the semantic and software-technical context of the digital original objects, which entails far more effort. Beyond the technical embedding of the LTA in the system environment of a multi-cloud-based infrastructure, a number of technically differentiated requirements of the NFDI's subject consortia are part of the development of a basic service for the LTA and for the re-use of research data.3 The need for funding for the development of a basic LTA service for the NFDI consortia results primarily from the additional costs associated with the technical and organizational development of a cross-NFDI, decentralized network structure for LTA and the sustainable subsequent use of research data. It is imperative that the technical actors are able to act within the network as a technology-oriented community, and that they can provide their own services as part of the support for also within a federated infrastructure. The working group "Long Term Archiving" (LTA) is to develop the requirements of the technical consortia for LTA and, on this basis, strategic approaches for the implementation of a basic service LTA. The working group consists of members of various NFDI consortia covering the humanities, natural science and engineering disciplines and experts from a variety of pertinent infrastructures with strong overall connections to the nestor long-term archiving competence network. The close linkage of NFDI consortia with experienced4 partners in the field of LTA ensures that a) the relevant technical state-of-the-art is present in the group and b) the knowledge of data producers about contexts of origin and data users interact directly. This composition enables the team to take an overarching view that spans the requirements of the disciplines and consortia, also takes into account interdisciplinary needs, and at the same time brings in the existing know-how in the infrastructure sector.
- ItemExtruded polycarbonate/Di-Allyl phthalate composites with ternary conductive filler system for bipolar plates of polymer electrolyte membrane fuel cells(Bristol : IOP Publ., 2019) Naji, Ahmed; Krause, Beate; Pötschke, Petra; Ameli, AmirHere, we report multifunctional polycarbonate (PC)-based conductive polymer composites (CPCs) with outstanding performance manufactured by a simple extrusion process and intended for use in bipolar plate (BPP) applications in polymer electrolyte membrane (PEM) fuel cells. CPCs were developed using a ternary conductive filler system containing carbon nanotube (CNT), carbon fiber (CF), and graphite (G) and by introducing di-allyl phthalate (DAP) as a plasticizer to PC matrix. The samples were fabricated using twin-screw extrusion followed by compression molding and the microstructure, electrical conductivity, thermal conductivity, and mechanical properties were investigated. The results showed a good dispersion of the fillers with some degree of interconnection between dissimilar fillers. The addition of DAP enhanced the electrical conductivity and tensile strength of the CPCs. Due to its plasticizing effect, DAP reduced the processing temperature by 75 °C and facilitated the extrusion of CPCs with filler loads as high as 63 wt% (3 wt% CNT, 30 wt% CF, 30 wt% G). Consequently, CPCs with the through-plane electrical, in-plane electrical and thermal conductivities and tensile strength of 4.2 S cm-1, 34.3 S cm-1, 2.9 W m-1 K-1, and 75.4 MPa, respectively, were achieved. This combination of properties indicates the potential of PC-based composites enriched with hybrid fillers and plasticizers as an alternative material for BPP application.
- ItemGraphite modified epoxy-based adhesive for joining of aluminium and PP/graphite composites(New York, NY [u.a.] : Taylor & Francis, 2020) Rzeczkowski, P.; Pötschke, Petra; Fischer, M.; Kühnert, I.; Krause, BeateA graphite-modified adhesive was developed in order to simultaneously enhance the thermal conductivity and the strength of an adhesive joint. The thermal conductivity through the joint was investigated by using highly filled PP/graphite composite substrates, which were joined with an epoxy adhesive of different layer thicknesses. Similar measurements were carried out with a constant adhesive layer thickness, whilst applying an epoxy adhesive modified with expanded graphite (EG) (6, 10, and 20 wt%). By reducing the adhesive layer thickness or modifying the adhesive with conductive fillers, a significant increase of the thermal conductivity through the joint was achieved. The examination of the mechanical properties of the modified adhesives was carried out by tensile tests (adhesive only), lap-shear tests, and fracture energy tests (mode 1) with aluminium substrates. Modification of the adhesive with EG led to an increase of the tensile lap-shear strength and the adhesive fracture energy (mode 1) of the joint. In addition, burst pressure tests were performed to determine the strength of the joint in a complex component. The strength of the joint increased with the graphite content in the PP substrate and in the epoxy adhesive.