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- ItemSynthesis and Characterization of Oxide Chloride Sr2VO3Cl, a Layered S = 1 Compound(Washington, DC : ACS Publications, 2023) Sannes, Johnny A.; Kizhake Malayil, Ranjith K.; Corredor, Laura T.; Wolter, Anja U. B.; Grafe, Hans-Joachim; Valldor, MartinThe mixed-anion compound with composition Sr2VO3Cl has been synthesized for the first time, using the conventional high-temperature solid-state synthesis technique in a closed silica ampule under inert conditions. This compound belongs to the known Sr2TmO3Cl (Tm = Sc, Mn, Fe, Co, Ni) family, but with Tm = V. All homologues within this family can be described with the tetragonal space group P4/nmm (No. 129); from a Rietveld refinement of powder X-ray diffraction data on the Tm = V homologue, the unit cell parameters were determined to a = 3.95974(8) and c = 14.0660(4) Å, and the atomic parameters in the crystal structure could be estimated. The synthesized powder is black, implying that the compound is a semiconductor. The magnetic investigations suggest that Sr2VO3Cl is a paramagnet at high temperatures, exhibiting a μeff = 2.0 μB V-1 and antiferromagnetic (AFM) interactions between the magnetic vanadium spins (θCW = −50 K), in line with the V-O-V advantageous super-exchange paths in the V-O layers. Specific heat capacity studies indicate two small anomalies around 5 and 35 K, which however are not associated with long-range magnetic ordering. 35Cl ss-NMR investigations suggest a slow spin freezing below 4.2 K resulting in a glassy-like spin ground state.
- ItemStrain Engineered Electrically Pumped SiGeSn Microring Lasers on Si(Washington, DC : ACS, 2022) Marzban, Bahareh; Seidel, Lukas; Liu, Teren; Wu, Kui; Kiyek, Vivien; Zoellner, Marvin Hartwig; Ikonic, Zoran; Schulze, Joerg; Grützmacher, Detlev; Capellini, Giovanni; Oehme, Michael; Witzens, Jeremy; Buca, DanSiGeSn holds great promise for enabling fully group-IV integrated photonics operating at wavelengths extending in the mid-infrared range. Here, we demonstrate an electrically pumped GeSn microring laser based on SiGeSn/GeSn heterostructures. The ring shape allows for enhanced strain relaxation, leading to enhanced optical properties, and better guiding of the carriers into the optically active region. We have engineered a partial undercut of the ring to further promote strain relaxation while maintaining adequate heat sinking. Lasing is measured up to 90 K, with a 75 K T0. Scaling of the threshold current density as the inverse of the outer circumference is linked to optical losses at the etched surface, limiting device performance. Modeling is consistent with experiments across the range of explored inner and outer radii. These results will guide additional device optimization, aiming at improving electrical injection and using stressors to increase the bandgap directness of the active material.
- ItemHandreichung Urheberrecht und Datenschutz(Genève : CERN, 2023) Blumtritt, Ute; Euler, Ellen; Fadeevy, Yuliya; Pohle, Jörg; Rack, Fabian; Wrzesinski, MarcelDie vorliegende Handreichung adressiert wissenschaftsgeleitete Zeitschriften sowie herausgebende Einrichtungen. Sie sollen in die Lage versetzt werden, erste urheberrechtliche wie datenschutzrechtliche Fragen zu beantworten und dabei Qualitätsstandards einzuhalten. Dieser Text ersetzt keine Rechtsberatung, sondern bietet grundsätzliche Informationen, gibt Empfehlungen zum Weiterlesen für klassische Fragestellungen und verweist auf gelungene Beispiele im weiteren Feld des wissenschaftsgeleiteten Publizierens.
- ItemMineral dust in Central Asia: Combining lidar and other measurements during the Central Asian dust experiment (CADEX)(Les Ulis : EDP Sciences, 2018) Althausen, Dietrich; Hofer, Julian; Abdullaev, Sabur; Makhmudov, Abduvosit; Baars, Holger; Engelmann, Ronny; Wadinga Fomba, Khanneh; Müller, Konrad; Schettler, Georg; Klüser, Lars; Kandler, Konrad; Nicolae, D.; Makoto, A.; Vassilis, A.; Balis, D.; Behrendt, A.; Comeron, A.; Gibert, F.; Landulfo, E.; McCormick, M.P.; Senff, C.; Veselovskii, I.; Wandinger, U.Mineral dust needs to be characterized comprehensively since it contributes to the climate change in Tajikistan / Central Asia. Lidar results from the measurements of mineral dust during CADEX are compared with results of sun photometer measurements, satellite-based measurements, and chemical analysis of ground samples. Although the dust is often advected from far-range sources, it impacts on the local conditions considerably.
- ItemMelt Electrowriting of Graded Porous Scaffolds to Mimic the Matrix Structure of the Human Trabecular Meshwork(Washington, DC : ACS Publ., 2022) Włodarczyk-Biegun, Małgorzata K.; Villiou, Maria; Koch, Marcus; Muth, Christina; Wang, Peixi; Ott, Jenna; del Campo, AranzazuThe permeability of the human trabecular meshwork (HTM) regulates eye pressure via a porosity gradient across its thickness modulated by stacked layers of matrix fibrils and cells. Changes in HTM porosity are associated with increases in intraocular pressure and the progress of diseases such as glaucoma. Engineered HTMs could help to understand the structure-function relation in natural tissues and lead to new regenerative solutions. Here, melt electrowriting (MEW) is explored as a biofabrication technique to produce fibrillar, porous scaffolds that mimic the multilayer, gradient structure of native HTM. Poly(caprolactone) constructs with a height of 125-500 μm and fiber diameters of 10-12 μm are printed. Scaffolds with a tensile modulus between 5.6 and 13 MPa and a static compression modulus in the range of 6-360 kPa are obtained by varying the scaffold design, that is, the density and orientation of the fibers and number of stacked layers. Primary HTM cells attach to the scaffolds, proliferate, and form a confluent layer within 8-14 days, depending on the scaffold design. High cell viability and cell morphology close to that in the native tissue are observed. The present work demonstrates the utility of MEW for reconstructing complex morphological features of natural tissues.
- ItemComparative Verification of the Digital Library of Mathematical Functions and Computer Algebra Systems(Berlin ; Heidelberg : Springer, 2022) Greiner-Petter, André; Cohl, Howard S.; Youssef, Abdou; Schubotz, Moritz; Trost, Avi; Dey, Rajen; Aizawa, Akiko; Gipp, Bela; Fisman, Dana; Rosu, GrigoreDigital mathematical libraries assemble the knowledge of years of mathematical research. Numerous disciplines (e.g., physics, engineering, pure and applied mathematics) rely heavily on compendia gathered findings. Likewise, modern research applications rely more and more on computational solutions, which are often calculated and verified by computer algebra systems. Hence, the correctness, accuracy, and reliability of both digital mathematical libraries and computer algebra systems is a crucial attribute for modern research. In this paper, we present a novel approach to verify a digital mathematical library and two computer algebra systems with one another by converting mathematical expressions from one system to the other. We use our previously developed conversion tool (referred to as ) to translate formulae from the NIST Digital Library of Mathematical Functions to the computer algebra systems Maple and Mathematica. The contributions of our presented work are as follows: (1) we present the most comprehensive verification of computer algebra systems and digital mathematical libraries with one another; (2) we significantly enhance the performance of the underlying translator in terms of coverage and accuracy; and (3) we provide open access to translations for Maple and Mathematica of the formulae in the NIST Digital Library of Mathematical Functions.
- ItemHandreichung Technik und Infastrukturen(Genève : CERN, 2023) Eichler, Frederik; Eppelin, Anita; Kampkaspar, Dario; Schrader, Antonia C.; Söllner, Konstanze; Vierkant, Paul; Withanage, Dulip; Wrzesinski, MarcelIn der vorliegenden Handreichung stellen wir unterschiedliche technische Ressourcen vor, die redaktionelle Arbeiten unterstützen können. Dabei empfiehlt es sich, Software und Systeme zu nutzen, die den Wandel hin zu einer offenen, niederschwelligen und nachhaltigen Wissenschaftskultur fördern. Hierzu zählt in erster Linie die Verwendung von Open-Source-Software. Unsere Empfehlungen haben dabei eine begrenzte Reichweite: Serviceanbieter, Software und Projekte sind zu einem späteren Zeitpunkt ggf. nicht mehr verfügbar. Auch sind gerade die Infrastruktureinrichtungen in das föderale Wissenschaftssystem integriert, was sie bestimmten Unwägbarkeiten aussetzt.
- ItemNanoscale Mapping of the 3D Strain Tensor in a Germanium Quantum Well Hosting a Functional Spin Qubit Device(Washington, DC : Soc., 2023) Corley-Wiciak, Cedric; Richter, Carsten; Zoellner, Marvin H.; Zaitsev, Ignatii; Manganelli, Costanza L.; Zatterin, Edoardo; Schülli, Tobias U.; Corley-Wiciak, Agnieszka A.; Katzer, Jens; Reichmann, Felix; Klesse, Wolfgang M.; Hendrickx, Nico W.; Sammak, Amir; Veldhorst, Menno; Scappucci, Giordano; Virgilio, Michele; Capellini, GiovanniA strained Ge quantum well, grown on a SiGe/Si virtual substrate and hosting two electrostatically defined hole spin qubits, is nondestructively investigated by synchrotron-based scanning X-ray diffraction microscopy to determine all its Bravais lattice parameters. This allows rendering the three-dimensional spatial dependence of the six strain tensor components with a lateral resolution of approximately 50 nm. Two different spatial scales governing the strain field fluctuations in proximity of the qubits are observed at <100 nm and >1 μm, respectively. The short-ranged fluctuations have a typical bandwidth of 2 × 10-4 and can be quantitatively linked to the compressive stressing action of the metal electrodes defining the qubits. By finite element mechanical simulations, it is estimated that this strain fluctuation is increased up to 6 × 10-4 at cryogenic temperature. The longer-ranged fluctuations are of the 10-3 order and are associated with misfit dislocations in the plastically relaxed virtual substrate. From this, energy variations of the light and heavy-hole energy maxima of the order of several 100 μeV and 1 meV are calculated for electrodes and dislocations, respectively. These insights over material-related inhomogeneities may feed into further modeling for optimization and design of large-scale quantum processors manufactured using the mainstream Si-based microelectronics technology.
- ItemSeeded Growth Synthesis of Gold Nanotriangles: Size Control, SAXS Analysis, and SERS Performance(Washington, DC : Soc., 2018) Kuttner, Christian; Mayer, Martin; Dulle, Martin; Moscoso, Ana; López-Romero, Juan Manuel; Förster, Stephan; Fery, Andreas; Pérez-Juste, Jorge; Contreras-Cáceres, RafaelWe studied the controlled growth of triangular prismatic Au nanoparticles with different beveled sides for surface-enhanced Raman spectroscopy (SERS) applications. First, in a seedless synthesis using 3-butenoic acid (3BA) and benzyldimethylammonium chloride (BDAC), gold nanotriangles (AuNTs) were synthesized in a mixture with gold nanooctahedra (AuNOCs) and separated by depletion-induced flocculation. Here, the influence of temperature, pH, and reducing agent on the reaction kinetics was initially investigated by UV–vis and correlated to the size and yield of AuNT seeds. In a second step, the AuNT size was increased by seed-mediated overgrowth with Au. We show for the first time that preformed 3BA-synthesized AuNT seeds can be overgrown up to a final edge length of 175 nm and a thickness of 80 nm while maintaining their triangular shape and tip sharpness. The NT morphology, including edge length, thickness, and tip rounding, was precisely characterized in dispersion by small-angle X-ray scattering and in dry state by transmission electron microscopy and field-emission scanning electron microscopy. For sensor purposes, we studied the size-dependent SERS performance of AuNTs yielding analytical enhancement factors between 0.9 × 104 and 5.6 × 104 and nanomolar limit of detection (10–8–10–9 M) for 4-mercaptobenzoic acid and BDAC. These results confirm that the 3BA approach allows the fabrication of AuNTs in a whole range of sizes maintaining the NT morphology. This enables tailoring of localized surface plasmon resonances between 590 and 740 nm, even in the near-infrared window of a biological tissue, for use as colloidal SERS sensing agents or for optoelectronic applications.
- ItemDie Rolle der ORCID iD in der Wissenschaftskommunikation: Der Beitrag des ORCID-Deutschland-Konsortiums und das ORCID-DE-Projekt(Berlin : de Gruyter Saur, 2019) Dreyer, Britta; Hagemann-Wilholt, Stephanie; Vierkant, Paul; Strecker, Dorothea; Glagla-Dietz, Stephanie; Summann, Friedrich; Pampel, Heinz; Burger, MarleenORCID’s services such as the unambiguous linking of researchers and their research output form the basis of modern scholarly communication. The ORCID Germany Consortium offers a reduced ORCID premium membership fee and supports its members during ORCID integration. Services include a dialogue platform that provides German-language information and additional support services. Another major success factor is an all-encompassing communication strategy: members of the ORCID implementation can resort to established organizational communication channels. Together and with the support of the ORCID DE project they contribute significantly to the successful distribution of ORCID in Germany.