2008, Hapke, M., Spannenberg, A.

The title compound, [Co(C5H5)(C18H15P)2]·0.2C7H8·0.25C6H14, was synthesized by the reaction of cobaltocene, Cp2Co, with elemental lithium in tetra-hydro-furan in the presence of two equivalents of PPh3. The mol-ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol-ecules in the asymmetric unit besides the disordered solvent molecules.

2008, Polom, U., Arsyad, I., Kümpel, H.-J.

As part of the project "Management of Georisk" (MANGEONAD) of the Federal Institute for Geosciences and Natural Resources (BGR), Hanover, high resolution shallow shear-wave reflection seismics was applied in the Indonesian province Nanggroe Aceh Darussalam, North Sumatra in cooperation with the Government of Indonesia, local counterparts, and the Leibniz Institute for Applied Geosciences, Hanover. The investigations were expected to support classification of earthquake site effects for the reconstruction of buildings and infrastructure as well as for groundwater exploration. The study focus sed on the city of Banda Aceh and the surroundings of Aceh Besar. The shear-wave seismic surveys were done parallel to standard geoengineering investigations like cone penetrometer tests to support subsequent site specific statistical calibration. They were also partly supplemented by shallow p-wave seismics for the identification of (a) elastic subsurface parameters and (b) zones with abundance of groundwater. Evaluation of seismic site effects based on shallow reflection seismics has in fact been found to be a highly useful method in Aceh province. In particular, use of a vibratory seismic source was essential for successful application of shear-wave seismics in the city of Banda Aceh and in areas with compacted ground like on farm tracks in the surroundings, presenting mostly agricultural land use areas. We thus were able to explore the mechanical stiffness of the subsurface down to 100 m depth, occasionally even deeper, with remarkably high resolution. The results were transferred into geotechnical site classification in terms of the International Building Code (IBC, 2003). The seismic images give also insights into the history of the basin sedimentation processes of the Krueng Aceh River delta, which is relevant for the exploration of new areas for construction of safe foundations of buildings and for identification of fresh water aquifers in the tsunami flooded region.

2008, Gerding, M., Höffner, J., Lautenbach, J., Rauthe, M., Lübken, F.-J.

Temperature soundings are performed by lidar at the mid-latitude station of Kühlungsborn (Germany, 54° N, 12° E). The profiles cover the complete range from the lower troposphere (~1 km) to the lower thermosphere (~105 km) by simultaneous and co-located operation of a Rayleigh-Mie-Raman lidar and a potassium resonance lidar. Observations have been done during 266 nights between June 2002 and July 2007, each of 3–15 h length. This large and unique data set provides comprehensive information on the altitudinal and seasonal variation of temperatures from the troposphere to the lower thermosphere. The remaining day-to-day-variability is strongly reduced by harmonic fits at constant altitude levels and a representative data set is achieved. This data set reveals a two-level mesopause structure with an altitude of about 86–87 km (~144 K) in summer and ~102 km (~170 K) during the rest of the year. The average stratopause altitude is ~48 km throughout the whole year, with temperatures varying between 258 and 276 K. From the fit parameters amplitudes and phases of annual, semi-annual, and quarter-annual variations are derived. The amplitude of the annual component is largest with amplitudes of up to 30 K in 85 km, while the quarter-annual variation is smallest and less than 3 K at all altitudes. The lidar data set is compared with ECMWF temperatures below about 70 km altitude and reference data from the NRLMSISE-00 model above. Apart from the temperature soundings the aerosol backscatter ratio is measured between 20 and 35 km. The seasonal variation of these values is presented here for the first time.

2008, Archer, D., Brovkin, V.

The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere/ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial/interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere. © 2008 The Author(s).

2008, Veličkov, B., Kahlenberg, V., Bertram, R., Uecker, R.

The crystal structure of terbium(III) scandate(III), with ideal formula TbScO3, has been reported previously on the basis of powder diffraction data [Liferovich & Mitchell (2004). J. Solid State Chem. 177, 2188-2197]. The current data were obtained from single crystals grown by the Czochralski method and show an improvement in the precision of the geometric parameters. Moreover, inductively coupled plasma optical emission spectrometry studies resulted in a nonstoichiometric composition of the title compound. Site-occupancy refinements based on diffraction data support the idea of a Tb deficiency on the A site (inducing O defects on the O2 position). The crystallochemical formula of the investigated sample thus may be written as A(0.04Tb0.96) BScO2.94. In the title compound, Tb occupies the eightfold- coordinated sites (site symmetry m) and Sc the centres of corner-sharing [ScO6] octa-hedra (site symmetry ). The mean bond lengths and site distortions fit well into the data of the remaining lanthanoid scandates in the series from DyScO3 to NdScO3. A linear structural evolution with the size of the lanthanoid from DyScO3 to NdScO3 can be predicted.

2008, Birmili, W., Schepanski, K., Ansmann, A., Spindler, G., Tegen, I., Wehner, B., Nowak, A., Reimer, E., Mattis, I., Müller, K., Brüggemann, E., Gnauk, T., Herrmann, H., Wiedensohler, A., Althausen, D., Schladitz, A., Tuch, T., Löschau, G.

On 24 March 2007, an extraordinary dust plume was observed in the Central European troposphere. Satellite observations revealed its origins in a dust storm in Southern Ukraine, where large amounts of soil were resuspended from dried-out farmlands at wind gusts up to 30 m s−1. Along the pathway of the plume, maximum particulate matter (PM10) mass concentrations between 200 and 1400 μg m−3 occurred in Slovakia, the Czech Republic, Poland, and Germany. Over Germany, the dust plume was characterised by a volume extinction coefficient up to 400 Mm−1 and a particle optical depth of 0.71 at wavelength 0.532 μm. In-situ size distribution measurements as well as the wavelength dependence of light extinction from lidar and Sun photometer measurements confirmed the presence of a coarse particle mode with diameters around 2–3 μm. Chemical particle analyses suggested a fraction of 75% crustal material in daily average PM10 and up to 85% in the coarser fraction PM10–2.5. Based on the particle characteristics as well as a lack of increased CO and CO2 levels, a significant impact of biomass burning was ruled out. The reasons for the high particle concentrations in the dust plume were twofold: First, dust was transported very rapidly into Central Europe in a boundary layer jet under dry conditions. Second, the dust plume was confined to a relatively stable boundary layer of 1.4–1.8 km height, and could therefore neither expand nor dilute efficiently. Our findings illustrate the capacity of combined in situ and remote sensing measurements to characterise large-scale dust plumes with a variety of aerosol parameters. Although such plumes from Southern Eurasia seem to occur rather infrequently in Central Europe, its unexpected features highlights the need to improve the description of dust emission, transport and transformation processes needs, particularly when facing the possible effects of further anthropogenic desertification and climate change.

2008, Vetter, M., Churkina, G., Jung, M., Reichstein, M., Zaehle, S., Bondeau, A., Chen, Y., Ciais, P., Feser, F., Freibauer, A., Geyer, R., Jones, C., Papale, D., Tenhunen, J., Tomelleri, E., Trusilova, K., Viovy, N., Heimann, M.

Globally, the year 2003 is associated with one of the largest atmospheric CO2 rises on record. In the same year, Europe experienced an anomalously strong flux of CO2 from the land to the atmosphere associated with an exceptionally dry and hot summer in Western and Central Europe. In this study we analyze the magnitude of this carbon flux anomaly and key driving ecosystem processes using simulations of seven terrestrial ecosystem models of different complexity and types (process-oriented and diagnostic). We address the following questions: (1) how large were deviations in the net European carbon flux in 2003 relative to a short-term baseline (1998–2002) and to longer-term variations in annual fluxes (1980 to 2005), (2) which European regions exhibited the largest changes in carbon fluxes during the growing season 2003, and (3) which ecosystem processes controlled the carbon balance anomaly . In most models the prominence of 2003 anomaly in carbon fluxes declined with lengthening of the reference period from one year to 16 years. The 2003 anomaly for annual net carbon fluxes ranged between 0.35 and –0.63 Pg C for a reference period of one year and between 0.17 and –0.37 Pg C for a reference period of 16 years for the whole Europe. In Western and Central Europe, the anomaly in simulated net ecosystem productivity (NEP) over the growing season in 2003 was outside the 1σ variance bound of the carbon flux anomalies for 1980–2005 in all models. The estimated anomaly in net carbon flux ranged between –42 and –158 Tg C for Western Europe and between 24 and –129 Tg C for Central Europe depending on the model used. All models responded to a dipole pattern of the climate anomaly in 2003. In Western and Central Europe NEP was reduced due to heat and drought. In contrast, lower than normal temperatures and higher air humidity decreased NEP over Northeastern Europe. While models agree on the sign of changes in simulated NEP and gross primary productivity in 2003 over Western and Central Europe, models diverge in the estimates of anomalies in ecosystem respiration. Except for two process models which simulate respiration increase, most models simulated a decrease in ecosystem respiration in 2003. The diagnostic models showed a weaker decrease in ecosystem respiration than the process-oriented models. Based on the multi-model simulations we estimated the total carbon flux anomaly over the 2003 growing season in Europe to range between –0.02 and –0.27 Pg C relative to the net carbon flux in 1998–2002.

2008, Rost, S., Gerten, D., Heyder, U.

This study quantifies current and potential future changes in transpiration, evaporation, interception loss and river discharge in response to land use change, irrigation and climate change, by performing several distinct simulations within the consistent hydrology and biosphere modeling framework LPJmL (Lund-Potsdam-Jena managed Land). We distinguished two irrigation simulations: a water limited one in which irrigation was restricted by local renewable water resources (ILIM), and a potential one in which no such limitation was assumed but withdrawals from deep groundwater or remote rivers allowed (IPOT). We found that the effect of historical land use change as compared to potential natural vegetation was pronounced, including a reduction in interception loss and transpiration by 25.9% and 10.6%, respectively, whereas river discharge increased by 6.6% (climate conditions of 1991-2000). Furthermore, we estimated that about 1170km3yr-1 of irrigation water could be withdrawn from local renewable water resources (in ILIM), which resulted in a reduction of river discharge by 1.5%. However, up to 1660km3yr-1 of water withdrawals were required in addition under the assumption that optimal growth of irrigated crops was sustained (IPOT), which resulted in a slight net increase in global river discharge by 2.0% due to return flows. Under the HadCM3 A2 climate and emission scenario, climate change alone will decrease total evapotranspiration by 1.5% and river discharge by 0.9% in 2046-2055 compared to 1991-2000 average due to changes in precipitation patterns, a decrease in global precipitation amount, and the net effect of CO2 fertilization. A doubling of agricultural land in 2046-2055 compared to 1991-2000 average as proposed by the IMAGE land use change scenario will result in a decrease in total evapotranspiration by 2.5% and in an increase in river discharge by 3.9%. That is, the effects of land use change in the future will be comparable in magnitude to the effects of climate change in this particular scenario. On present irrigated areas future water withdrawal will increase especially in regions where climate changes towards warmer and dryer conditions will be pronounced.

2008, Ehrlich, A., Bierwirth, E., Wendisch, M., Gayet, J.-F., Mioche, G., Lampert, A., Heintzenberg, J.

Arctic boundary-layer clouds were investigated with remote sensing and in situ instruments during the Arctic Study of Tropospheric Aerosol, Clouds and Radiation (ASTAR) campaign in March and April 2007. The clouds formed in a cold air outbreak over the open Greenland Sea. Beside the predominant mixed-phase clouds pure liquid water and ice clouds were observed. Utilizing measurements of solar radiation reflected by the clouds three methods to retrieve the thermodynamic phase of the cloud are introduced and compared. Two ice indices IS and IP were obtained by analyzing the spectral pattern of the cloud top reflectance in the near infrared (1500–1800 nm wavelength) spectral range which is characterized by ice and water absorption. While IS analyzes the spectral slope of the reflectance in this wavelength range, IS utilizes a principle component analysis (PCA) of the spectral reflectance. A third ice index IA is based on the different side scattering of spherical liquid water particles and nonspherical ice crystals which was recorded in simultaneous measurements of spectral cloud albedo and reflectance. Radiative transfer simulations show that IS, IP and IA range between 5 to 80, 0 to 8 and 1 to 1.25 respectively with lowest values indicating pure liquid water clouds and highest values pure ice clouds. The spectral slope ice index IS and the PCA ice index IP are found to be strongly sensitive to the effective diameter of the ice crystals present in the cloud. Therefore, the identification of mixed-phase clouds requires a priori knowledge of the ice crystal dimension. The reflectance-albedo ice index IA is mainly dominated by the uppermost cloud layer (τ<1.5). Therefore, typical boundary-layer mixed-phase clouds with a liquid cloud top layer will be identified as pure liquid water clouds. All three methods were applied to measurements above a cloud field observed during ASTAR 2007. The comparison with independent in situ microphysical measurements shows the ability of the three approaches to identify the ice phase in Arctic boundary-layer clouds.

2008, Döll, P., Berkhoff, K., Bormann, H., Fohrer, N., Gerten, D., Hagemann, S., Krol, M.

Large-scale hydrological modelling has become increasingly wide-spread during the last decade. An annual workshop series on large-scale hydrological modelling has provided, since 1997, a forum to the German-speaking community for discussing recent developments and achievements in this research area. In this paper we present the findings from the 2007 workshop which focused on advances and visions in large-scale hydrological modelling. We identify the state of the art, difficulties and research perspectives with respect to the themes "sensitivity of model results", "integrated modelling" and "coupling of processes in hydrosphere, atmosphere and biosphere". Some achievements in large-scale hydrological modelling during the last ten years are presented together with a selection of remaining challenges for the future.