1976 results
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Now showing 1 - 10 of 1976
- Item(μ5-Cyclo-penta-dien-yl)bis-(triphenyl-phosphane)cobalt(I) -toluene-n-hexane (1/0.20/0.25)(Chester : International Union of Crystallography, 2008) Hapke, M.; Spannenberg, A.The title compound, [Co(C5H5)(C18H15P)2]·0.2C7H8·0.25C6H14, was synthesized by the reaction of cobaltocene, Cp2Co, with elemental lithium in tetra-hydro-furan in the presence of two equivalents of PPh3. The mol-ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol-ecules in the asymmetric unit besides the disordered solvent molecules.
- ItemRedetermination of terbium scandate, revealing a defect-type perovskite derivative(Chester : International Union of Crystallography, 2008) Veličkov, B.; Kahlenberg, V.; Bertram, R.; Uecker, R.The crystal structure of terbium(III) scandate(III), with ideal formula TbScO3, has been reported previously on the basis of powder diffraction data [Liferovich & Mitchell (2004). J. Solid State Chem. 177, 2188-2197]. The current data were obtained from single crystals grown by the Czochralski method and show an improvement in the precision of the geometric parameters. Moreover, inductively coupled plasma optical emission spectrometry studies resulted in a nonstoichiometric composition of the title compound. Site-occupancy refinements based on diffraction data support the idea of a Tb deficiency on the A site (inducing O defects on the O2 position). The crystallochemical formula of the investigated sample thus may be written as A(0.04Tb0.96) BScO2.94. In the title compound, Tb occupies the eightfold- coordinated sites (site symmetry m) and Sc the centres of corner-sharing [ScO6] octa-hedra (site symmetry ). The mean bond lengths and site distortions fit well into the data of the remaining lanthanoid scandates in the series from DyScO3 to NdScO3. A linear structural evolution with the size of the lanthanoid from DyScO3 to NdScO3 can be predicted.
- ItemDIVA: An iterative method for building modular integrated models(München : European Geopyhsical Union, 2005) Hinkel, J.Integrated modelling of global environmental change impacts faces the challenge that knowledge from the domains of Natural and Social Science must be integrated. This is complicated by often incompatible terminology and the fact that the interactions between subsystems are usually not fully understood at the start of the project. While a modular modelling approach is necessary to address these challenges, it is not sufficient. The remaining question is how the modelled system shall be cut down into modules. While no generic answer can be given to this question, communication tools can be provided to support the process of modularisation and integration. Along those lines of thought a method for building modular integrated models was developed within the EU project DINAS-COAST and applied to construct a first model, which assesses the vulnerability of the world’s coasts to climate change and sea-level-rise. The method focuses on the development of a common language and offers domain experts an intuitive interface to code their knowledge in form of modules. However, instead of rigorously defining interfaces between the subsystems at the project’s beginning, an iterative model development process is defined and tools to facilitate communication and collaboration are provided. This flexible approach has the advantage that increased understanding about subsystem interactions, gained during the project’s lifetime, can immediately be reflected in the model.
- ItemSporadic Ca and Ca+ layers at mid-latitudes: Simultaneous observations and implications for their formation(München : European Geopyhsical Union, 2001) Gerding, M.; Alpers, M.; Höffner, J.; von Zahn, U.We report on the observations of 188 sporadic layers of either Ca atoms and/or Ca ions that we have observed during 112 nights of lidar soundings of Ca, and 58 nights of Ca+ soundings, at Kühlungsborn, Germany (54° N, 12° E). The Ca+ soundings have been performed simultaneously and in a common volume with the Ca soundings by two separate lidars. Correlations between sporadic neutral and ionized metal layers are demonstrated through four case studies. A systematic study of the variations of occurrence of sporadic Ca and Ca+ layers reveals that neutral and ionized Ca layers are not as closely correlated as expected earlier: (a) The altitude distribution shows the simultaneous occurrence of both sporadic Ca and Ca+ layers to be most likely only in the narrow altitude range between 90 and 95 km. Above that region, in the lower thermosphere, the sporadic ion layers are much more frequent than atom layers. Below 90 km only very few sporadic layers have been observed; (b) The seasonal variation of sporadic Ca layers exhibits a minimum of occurrence in summer, while sporadic Ca+ layers do not show a significant seasonal variation (only the dense Ca+ layers appear to have a maximum in summer). At mid-latitudes sporadic Ca layers are more frequent than sporadic layers of other atmospheric metals like Na or K. For the explanation of our observations new formation mechanisms are discussed.
- ItemThe atmospheric background situation in northern Scandinavia during January/February 2003 in the context of the MaCWAVE campaign(München : European Geopyhsical Union, 2006) Blum, U.; Baumgarten, G.; Schöch, A.; Kirkwood, S.; Naujokat, B.; Fricke, K.H.The atmosphere background wind field controls the propagation of gravity waves from the troposphere through the stratosphere into the mesosphere. During January 2003 the MaCWAVE campaign took place at Esrange, with the purpose of observing vertically ascending waves induced by orography. Temperature data from the U. Bonn lidar at Esrange (68° N/21° E) and the ALOMAR RMR lidar (69° N/16° E), wind data from Esrange MST radar ESRAD, as well as wind data from the ECMWF T106 model, are used to analyse the atmospheric background situation and its effect on mountain wave propagation during January/February 2003. Critical levels lead to dissipation of vertically ascending waves, thus mountain waves are not observable above those levels. In the first half of January a minor as well as a major stratospheric warming dominated the meteorological background situation. These warmings led to a wind reversal, thus to critical level filtering and consequently prevented gravity waves from propagating to high altitudes. While the troposphere was not transparent for stationary gravity waves most of the time, there was a period of eight days following the major warming with a transparent stratosphere, with conditions allowing gravity waves generated in the lower troposphere to penetrate the stratosphere up to the stratopause and sometimes even into the lower mesosphere. In the middle of February a minor stratospheric warming occurred, which again led to critical levels such that gravity waves were not able to ascend above the middle stratosphere. Due to the unfavourable troposphere and lower stratosphere conditions for gravity wave excitation and propagation, the source of the observed waves in the middle atmosphere is probably different from orography.
- ItemObservation of an unusual mid-stratospheric aerosol layer in the Arctic: Possible sources and implications for polar vortex dynamics(München : European Geopyhsical Union, 2003) Gerding, M.; Baumgarten, G.; Blum, U.; Thayer, J.P.; Fricke, K.-H.; Neuber, R.; Fiedler, J.By the beginning of winter 2000/2001, a mysterious stratospheric aerosol layer had been detected by four different Arctic lidar stations. The aerosol layer was observed first on 16 November 2000, at an altitude of about 38 km near Søndre Strømfjord, Greenland (67° N, 51° W) and on 19 November 2000, near Andenes, Norway (69° N, 16° E). Subsequently, in early December 2000, the aerosol layer was observed near Kiruna, Sweden (68° N, 21° E) and Ny-Ålesund, Spitsbergen (79° N, 12° E). No mid-latitude lidar station observed the presence of aerosols in this altitude region. The layer persisted throughout the winter 2000/2001, at least up to 12 February 2001. In November 2000, the backscatter ratio at a wavelength of 532 nm was up to 1.1, with a FWHM of about 2.5 km. By early February 2001, the layer had sedimented from an altitude of 38 km to about 26 km. Measurements at several wavelengths by the ALOMAR and Koldewey lidars indicate the particle size was between 30 and 50 nm. Depolarisation measurements reveal that the particles in the layer are aspherical, hence solid. In the mid-stratosphere, the ambient atmospheric temperature was too high to support in situ formation or existence of cloud particles consisting of ice or an acid-water solution. Furthermore, in the year 2000 there was no volcanic eruption, which could have injected aerosols into the upper stratosphere. Therefore, other origins of the aerosol, such as meteoroid debris, condensed rocket fuel, or aerosols produced under the influence of charged solar particles, will be discussed in the paper. Trajectory calculations illustrate the path of the aerosol cloud within the polar vortex and are used to link the observations at the different lidar sites. From the descent rate of the layer and particle sedimentation rates, the mean down-ward motion of air within the polar vortex was estimated to be about 124 m/d between 35 and 30 km, with higher values at the edge of the vortex.
- ItemOn the longitudinal structure of the transient day-to-day variation of the semidiurnal tide in the mid-latitude lower thermosphere - I. Winter season(München : European Geopyhsical Union, 2001) Merzlyakov, E.G.; Portnyagin, Yu.I.; Jacobi, C.; Mitchell, N.J.; Muller, H.G.; Manson, A.H.; Fachrutdinova, A.N.; Singer, W.; Hoffmann, P.The longitudinal structure of the day-to-day variations of semidiurnal tide amplitudes is analysed based on coordinated mesosphere/lower thermosphere wind measurements at several stations during three winter campaigns. Possible excitation sources of these variations are discussed. Special attention is given to a nonlinear interaction between the semidiurnal tide and the day-to-day mean wind variations. Data processing includes the S-transform analysis which takes into account transient behaviour of secondary waves. It is shown that strong tidal modulations appear during a stratospheric warming and may be caused by aperiodic mean wind variations during this event.
- ItemStudy of the tidal variations in mesospheric temperature at low and mid latitudes from WINDII and potassium lidar observations(Göttingen : Copernicus GmbH, 2004) Shepherd, M.; Fricke-Begemann, C.Zonal mean daytime temperatures from the Wind Imaging Interferometer (WINDII) on the Upper Atmosphere Research Satellite (UARS) and nightly temperatures from a potassium (K) lidar are employed in the study of the tidal variations in mesospheric temperature at low and mid latitudes in the Northern Hemisphere. The analysis is applied to observations at 89 km height for winter solstice, December to February (DJF), at 55° N, and for May and November at 28° N. The WINDII results are based on observations from 1991 to 1997. The K-lidar observations for DJF at Kühlungsborn (54° N) were from 1996-1999, while those for May and November at Tenerife 28° N were from 1999. To avoid possible effects from year-to-year variability in the temperatures observed, as well as differences due to instrument calibration and observation periods, the mean temperature field is removed from the respective data sets, assuming that only tidal and planetary scale perturbations remain in the temperature residuals. The latter are then binned in 0.5 h periods and the individual data sets are fitted in a least-mean square sense to 12-h and 8-h harmonics, to infer semidiurnal and terdiurnal tidal parameters. Both the K-lidar and WINDII independently observed a strong semidiurnal tide in November, with amplitudes of 13 K and 7.4 K, respectively. Good agreement was also found in the tidal parameters derived from the two data sets for DJF and May. It was recognized that insufficient local time coverage of the two separate data sets could lead to an overestimation of the semidiurnal tidal amplitude. A combined ground-based/satellite data set with full diurnal local time coverage was created which was fitted to 24 h+ 12 h+8 h harmonics and a novel method applied to account for possible differences between the daytime and nighttime means. The results still yielded a strong semidiurnal tide in November at 28° N with an amplitude of 8.8 K which is twice the SD amplitude in May and DJF. The diurnal tidal parameters were practically the same at 28° N and 55° N, in November and DJF, respectively, with an amplitude of 6.5 K and peaking at ∼9h. The diurnal and semidiurnal amplitudes in May were about the same, 4 K, and 4.6 K, while the terdiurnal tide had the same amplitudes and phases in May and November at 28° N. Good agreement is found with other experimental data while models tend to underestimate the amplitudes.
- ItemInertia gravity waves in the upper troposphere during the MaCWAVE winter campaign - Part II: Radar investigations and modelling studies(München : European Geopyhsical Union, 2006) Serafimovich, A.; Zülicke, Ch.; Hoffmann, P.; Peters, D.; Dalin, P.; Singer, W.We present an experimental and modelling study of a strong gravity wave event in the upper troposphere/lower stratosphere near the Scandinavian mountain ridge. Continuous VHF radar measurements during the MaCWAVE rocket and ground-based measurement campaign were performed at the Norwegian Andoya Rocket Range (ARR) near Andenes (69.3° N, 16° E) in January 2003. Detailed gravity wave investigations based on PSU/NCAR Fifth-Generation Mesoscale Model (MM5) data have been used for comparison with experimentally obtained results. The model data show the presence of a mountain wave and of an inertia gravity wave generated by a jet streak near the tropopause region. Temporal and spatial dependencies of jet induced inertia gravity waves with dominant observed periods of about 13 h and vertical wavelengths of ~4.5–5 km are investigated with wavelet transform applied on radar measurements and model data. The jet induced wave packet is observed to move upstream and downward in the upper troposphere. The model data agree with the experimentally obtained results fairly well. Possible reasons for the observed differences, e.g. in the time of maximum of the wave activity, are discussed. Finally, the vertical fluxes of horizontal momentum are estimated with different methods and provide similar amplitudes. We found indications that the derived positive vertical flux of the horizontal momentum corresponds to the obtained parameters of the jet-induced inertia gravity wave, but only at the periods and heights of the strongest wave activity.
- ItemAgents, Bayes, and Climatic Risks - a modular modelling approach(München : European Geopyhsical Union, 2005) Haas, A.; Jaeger, C.When insurance firms, energy companies, governments, NGOs, and other agents strive to manage climatic risks, it is by no way clear what the aggregate outcome should and will be. As a framework for investigating this subject, we present the LAGOM model family. It is based on modules depicting learning social agents. For managing climate risks, our agents use second order probabilities and update them by means of a Bayesian mechanism while differing in priors and risk aversion. The interactions between these modules and the aggregate outcomes of their actions are implemented using further modules. The software system is implemented as a series of parallel processes using the CIAMn approach. It is possible to couple modules irrespective of the language they are written in, the operating system under which they are run, and the physical location of the machine