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    Correlation of carbon nanotube dispersability in aqueous surfactant solutions and polymers
    (New York, NY [u.a.] : Pergamon Press, 2009) Krause, Beate; Petzold, Gudrun; Pegel, Sven; Pötschke, Petra
    In order to assess the dispersability of carbon nanotube materials, tubes produced under different synthesis conditions were dispersed in aqueous surfactant solutions and the sedimentation behaviour under centrifugation forces was investigated using a LUMiFuge stability analyzer. The electrical percolation threshold of the nanotubes after melt mixing in polyamide 6.6 was determined and the state of dispersion was studied. As a general tendency, the nanotubes having better aqueous dispersion stability showed lower electrical percolation threshold and better nanotube dispersion in the composites. This indicates that the investigation of the stability of aqueous dispersions is also able to give information about the nanotubes inherent dispersability in polymer melts, both strongly influenced by the entanglement and agglomerate structure of the tubes within the as-produced nanotube materials. The shape of the nanotubes in the aqueous dispersions was assessed using a SYSMEX flow particle image analyzer and found to correspond to the shape observed from cryofractured surfaces of the polymer composites. © 2008 Elsevier Ltd. All rights reserved.
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    Magnetic field effects of double-walled carbon nanotubes
    (São Carlos : Universidade Federal de São Carlos, 2006) Latgé, A.; Grimm, D.; Ferreira, M.S.
    A theoretical discussion of electronic and transport properties of a particular family of double-wall carbon nanotubes, named commensurate structures of the armchair type (n,n)@(2n,2n) is addressed. A single p-band tight binding hamiltonian is considered and the magnetic field is theoretically described by following the Peierls approximation into the hopping energies. Our emphasis is put on investigating the main effects of the geometrical aspects and relative positions of the tubes on the local density of states and on the conductance of the system. By considering intershell interactions between a set of neighboring atoms on the walls of the inner and outer tubes, we study the possibility of founding Aharonov-Bohm effects in the DWCNs when a magnetic field is applied along the axial direction.