Search Results
Crystal structure of (2S,4S,7S)-7,7-dichloro-4-(1-chloro-1-methylethyl)-1- (2,2,2-trichloroethyl)bicyclo[4.1.0]heptane, C12H16Cl 6
C12H16Cl6, orthorhombic, P2 12121 (no. 19), a = 6.0742(3) Å, b = 9.7189(6) Å, c = 26.700(1) Å, V = 1576.2 Å3, Z = 4, Rgt(F) = 0.019, wRref(F2) = 0.045, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
Air-water experiments in a vertical DN200-pipe : technical report ; project title: TOPFLOW-Experiments, development and validation of CFD models for steam-water flows with phase transfer ; reactor safety research-project no.: 150 1329
[no abstract available]
CLIME/RADIMP : Schlussbericht zum Forschungsvorhaben CLIME: Klimaänderungen in der Mesosphäre, climate changes in the mesosphere ; RADIMP: Non-LTE Studie des Strahlungseinflusses der unteren Atmosphäre auf die Mesosphäre/untere Thermosphäre, Non-LTE study of the radiative impact of the lower atmosphere on the mesosphere/lower thermosphere
[no abstract available]
Simulations of 3D/4D precipitation processes in a turbulent flow field
Precipitation processes are modeled by population balance systems. A very expensive part of the simulation of population balance systems is the solution of the equation for the particle size distribution (PSD) since this equation is defined in a higher dimensional domain than the other equations in the system. This paper studies different approaches for the solution of this equation: two finite difference upwind schemes and a linear finite element flux--corrected transport method. It is shown that the different schemes lead to qualitatively different solutions for an output of interest.
Significance of redox reactions in glass refining processes
The role of the redox reactions due to refining agents in the glass refining processes was examined. Α new approximate model for shrinkage (or growth) of gas bubbles in glassmelts in which redox reactions caused by refining agents were taken into account was developed. The proposed model is a modification of the quasi-stationary model by which the redox reactions due to refining agents can not be considered. It was found that the shrinkage (or growth) of gas bubbles in melts with refining agents is quite faster than that in those without refining agents. Numerical results for single-component and multicomponent gas bubbles indicate that the mechanism of the bubble shrinkage (or growth) in the refining process is significantly controlled by the oxidation of refining agents, which decreases (or increases) the oxygen concentration in the glassmelt and as a result causes the rapid oxygen transfer across the bubble/glassmelt Interface and hence the fast shrinkage (or growth) of the gas bubble. The applicability of the proposed model was examined using the computational results and experimental measurements in the literature. It was also found that the proposed model provides better predictions compared with the quasi-stationary model.
Mechanisms of bonding effected by nanoparticles in zirconia coatings applied by spraying of suspensions
Zirconia coatings consisting of a mixture of coarse and fine grained zirconia powders prepared by spraying of suspensions and subsequent thermal treatment at limited temperatures (up to 500°C) are poor in adherence and in intrinsic mechanical strength. We have shown elsewhere that mechanical properties of these coatings can be improved clearly by adding a small amount of nanoscaled zirconia. Here, the structural and the chemical development of this coating material and of the nanoparticles is examined to gain information about the underlying bonding mechanisms. The applied temperature is relatively low in comparison to the usual onset temperature of accelerated sintering. Nevertheless, the results show that diffusion controlled material transport mechanisms play their role in bonding. The condensation of surface OH groups may participate in bonding, too. These first results confirm the potential of nanoparticles to act as inorganic binder. Additional research effort to clarify the underlying mechanisms in detail is of interest. For the practical side, it can be concluded that the resulting effect of mechanical consolidation of ceramic structures at relatively low temperatures enables new ceramic applications, for example a new type of ceramic coatings on metallic substrates.
Stratifying modular representations of finite groups
We classify localising subcategories of the stable module category of a finite group that are closed under tensor product with simple (or, equivalently all) modules. One application is a proof of the telescope conjecture in this context. Others include new proofs of the tensor product theorem and of the classification of thick subcategories of the finitely generated modules which avoid the use of cyclic shifted subgroups. Along the way we establish similar classifications for differential graded modules over graded polynomial rings, and over graded exterior algebras.