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- ItemInfluence of microwave plasma treatment on the surface properties of carbon fibers and their adhesion in a polypropylene matrix(London [u.a.] : Institute of Physics, 2016) Scheffler, C.; Wölfel, E.; Förster, T.; Poitzsch, C.; Kotte, L.; Mäder, G.; Madsen, Bo; Biel, A.; Kusano, Y.; Lilholt, H.; Mikkelsen, L.P.; Mishnaevsky Jr., L.; Sørensen, B.F.A commercially available carbon fiber (CF) with an epoxy-based sizing (EP-sized CF) and an unsized CF have been plasma treated to study the effect on the fiber-matrix adhesion towards a polypropylene matrix. The EP-sized fiber was chosen because of its predictable low adhesion in a polypropylene (PP) matrix. The fibers have been modified using a microwave low-pressure O2/CO2/N2-gas plasma source (Cyrannus®) developed at IWS in a batch process. One aim of this study was the evaluation of parameters using high energies and short time periods in the plasma chamber to see the effect on mechanical performance of CF. These results will be the fundamental work for a planned continuous plasma modification line. The CF surface was characterized by determining the surface energies, single fiber tensile strength and XPS analysis. The adhesion behavior before and after plasma treatment was studied by single fiber pull-out test (SFPO) and scanning electron microscopy (SEM). It was shown that the CO2- and O2-plasma increases the number of functional groups on the fiber surface during short time plasma treatment of 30 s. Carboxylic groups on the unsized CF surface resulting from O2-plasma treatment lead to an enhanced fiber-matrix adhesion, whereas the fiber strength was merely reduced.
- ItemRaman imaging to study structural and chemical features of the dentin enamel junction(London [u.a.] : Institute of Physics, 2015) Alebrahim, M.A.; Krafft, C.; Popp, J.; El-Khateeb, Mohammad Y.The structure and chemical features of the human dentin enamel junction (DEJ) were characterized using Raman spectroscopic imaging. Slices were prepared from 10 German, and 10 Turkish teeth. Raman images were collected at 785 nm excitation and the average Raman spectra were calculated for analysis. Univariate and multivariate spectral analysis were applied for investigation. Raman images were obtained based on the intensity ratios of CH at 1450 cm-1 (matrix) to phosphate at 960 cm-1 (mineral), and carbonate to phosphate (1070/960) ratios. Different algorithms (HCA, K-means cluster and VCA) also used to study the DEJ. The obtained results showed that the width of DEJ is about 5 pm related to univariate method while it varies from 6 to 12 μm based on multivariate spectral technique. Both spectral analyses showed increasing in carbonate content inside the DEJ compared to the dentin, and the amide I (collagen) peak in dentin spectra is higher than DEJ spectra peak.
- ItemEffects of high energy electrons on the properties of polyethylene / multiwalled carbon nanotubes composites: Comparison of as-grown and oxygen-functionalised MWCNT(Melville, NY : AIP, 2014) Krause, Beate; Pötschke, Petra; Gohs, U.Polymer modification with high energy electrons (EB) is well established in different applications for many years. It is used for crosslinking, curing, degrading, grafting of polymeric materials and polymerisation of monomers. In contrast to this traditional method, electron induced reactive processing (EIReP) combines the polymer modification with high energy electrons and the melt mixing process. This novel reactive method was used to prepare polymer blends and composites. In this study, both methods were used for the preparation of polyethylene (PE)/ multiwalled carbon nanotubes (MWCNT) composites in the presence of a coupling agent. The influence of MWCNT and type of electron treatment on the gel content, the thermal conductivity, rheological, and electrical properties was investigated whereby as-grown and oxidised MWCNT were used. In the presence of a coupling agent and at an absorbed dose of 40 kGy, the gel content increased from 57 % for the pure PE to 74 % or 88 % by the addition of as-grown (Baytubes® C150P) or oxidised MWCNT, respectively. In comparison to the composites containing the as-grown MWCNTs, the use of the oxidised MWCNTs led to higher melt viscosity and higher storage modulus due to higher yield of filler polymer couplings. The melt viscosity increased due to the addition of MWCNT and crosslinking of PE. The thermal conductivity increased to about 150 % and showed no dependence on the kind of MWCNT and the type of electron treatment. In contrast, the lowest value of electrical volume resistivity was found for the non-irradiated samples and after state of the art electron treatment without any influence of the type of MWCNT. In the case of EIReP, the volume resistivity increased by 2 (as-grown MWCNT) or 3 decades (oxidised MWCNT) depending on the process parameters. © 2014 American Institute of Physics.
- ItemEvaluation of Expert Reports to Quantify the Exploration Risk for Geothermal Projects in Germany(Amsterdam [u.a.] : Elsevier, 2015) Ganz, Britta; Ask, Maria; Hangx, Suzanne; Bruckman, Viktor; Kühn, MichaelThe development of deep geothermal energy sources in Germany still faces many uncertainties and high upfront investment costs. Methodical approaches to assess the exploration risk are thus of major importance for geothermal project development. Since 2002, expert reports to quantify the exploration risk for geothermal projects in Germany were carried out. These reports served as a basis for insurance contracts covering the exploration risk. Using data from wells drilled in the meantime, the reports were evaluated and the stated probabilities compared with values actually reached.
- ItemOccurrence of polar mesosphere summer echoes at very high latitudes(München : European Geopyhsical Union, 2009) Zecha, M.; Röttger, J.Observations of polar mesosphere summer echoes (PMSE) have been carried out during the summer periodes 1999–2001 and 2003–2004 at the very high latitude of 78° N using the SOUSY Svalbard Radar (53.5 MHz) at Longyearbyen. Although the measurements could not be done continuously in these seasons, PMSE have been detected over more than 6600 h of 9300 h of observation time overall. Using this data base, particular PMSE occurrence characteristics have been determined. PMSE at Svalbard appear from the middle of May to the end of August with an almost permanent total occurrence in June and July. Diurnal variations are observable in the height-depend occurrence rates and in PMSE thickness, they show a maximum around 09:00–10:00 UTC and a minimum around 21:00–22:00 UTC. PMSE occur nearly exclusively between a height of 80 km and 92 km with a maximum near 85 km. However, PMSE appear not simultaneously over the entire height range, the mean vertical PMSE extension is around 4–6 km in June and July. Furthermore, typically PMSE are separated into several layers, and only 30% of all PMSE are single layers. The probability of multiple layers is greater in June and July than at the beginning and the end of the PMSE season and shows a marked 5-day-variation. The same variation is noticeable in the seasonal dependence of the PMSE occurrence and the PMSE thickness. We finally discuss potential geophysical processes to explain our observational results.
- ItemSurface, interphase and tensile properties of unsized, sized and heat treated basalt fibres(London [u.a.] : Institute of Physics, 2016) Förster, T.; Sommer, G.S.; Mäder, E.; Scheffler, C.Recycling of fibre reinforced polymers is in the focus of several investigations. Chemical and thermal treatments of composites are the common ways to separate the reinforcing fibres from the polymer matrices. However, most sizings on glass and basalt fibre are not designed to resist high temperatures. Hence, a heat treatment might also lead to a sizing removal, a decrease of mechanical performance and deterioration in fibre-matrix adhesion. Different basalt fibres were investigated using surface analysis methods as well as single fibre tensile tests and single fibre pull-out tests in order to reveal the possible causes of these issues. Heat treatment in air reduced the fibre tensile strength in the same level like heat treatment in nitrogen atmosphere, but it influenced the wetting capability. Re-sizing by a coupling agent slightly increased the adhesion strength and reflected a decreased post-debonding friction.
- ItemDevelopment of a polymer composite with high electrical conductivity and improved impact strength for the application as bipolar plate(Melville, NY : AIP, 2016) Hopmann, C.; Windeck, C.; Cohnen, A.; Onken, J.; Krause, Beate; Pötschke, Petra; Hickmann, T.Bipolar plates constitute the most important structural component in fuel cell stacks. Highly filled thermoplastic composites with high electrical conductivity obtain an increasing importance in the design of bipolar plates as alternative to conventional metallic systems. Thermoplastics (e.g. PP) have suitable properties such as a good processability, chemical resistance, light weight and low production costs. As thermoplastics have low electrical conductivities, conductive fillers have to be included in the matrix. A high content of such fillers (e.g. graphite) in excess of 80 wt.-% is necessary to achieve the desired electrical properties. However, materials with such high filler contents embrittle readily. The workability in injection and compression molding is difficult and the mechanical stability is insufficient in case of strain deformation. As consequence, material failure and an inacceptable amount of damaged goods can be observed during the processing. As no suitable thermoplastic system is available for better mechanical properties, the induction and dispersion of a rubber phase in the thermoplastic matrix can be used to increase the impact strength of the conductive composite. In this research work a ternary composite, based on PP as matrix, EPDM as impact modifier and synthetic graphite as conductive filler, was developed. The material was produced using a 26 mm co-rotating, intermeshing twin-screw extruder. The amounts of PP, EPDM and graphite were varied systematically and a process window was defined that enables improved impact strength and high electrical conductivity of the new material. The results indicate that impact strength can be enhanced by about 99 % with an EPDM content of 30 wt.-% in the PP matrix. The electrical conductivity decreases in a small range with increasing content of EPDM, but the conductivity is still excellent for producing bipolar plates.
- ItemDeep Geothermal Energy for Lower Saxony (North Germany) – Combined Investigations of Geothermal Reservoir Characteristics(Amsterdam [u.a.] : Elsevier, 2014) Hahne, Barbara; Thomas, Rüdiger; Bruckman, Viktor J.; Hangx, Suzanne; Ask, MariaFor the economic success of a geothermal project the hydraulic properties and temperature of the geothermal reservoir are crucial. New methodologies in seismics, geoelectrics and reservoir geology are tested within the frame of the collaborative research programme “Geothermal Energy and High-Performance Drilling” (gebo). Within nine geoscientific projects, tools were developed that help in the evaluation and interpretation of acquired data. Special emphasis is placed on the investigation of rock properties, on the development of early reservoir assessment even during drilling, and on the interaction between the drilling devices and the reservoir formation. The propagation of fractures and the transport of fluid and heat within the regional stress field are investigated using different approaches (field studies, seismic monitoring, multi-parameter modelling). Geologic structural models have been created for simulation of the local stress field and hydromechanical processes. Furthermore, a comprehensive dataset of hydrogeochemical environments was collected allowing characterisation and hydrogeochemical modelling of the reservoir.
- ItemModelling the Surface Heat Flow Distribution in the Area of Brandenburg (Northern Germany)(Amsterdam [u.a.] : Elsevier, 2013) Cacace, Mauro; Scheck-Wenderoth, Magdalena; Noack, Vera; Cherubini, Yvonne; Schellschmidt, Rüdiger; Kühn, Michael; Juhlin, Christopher; Held, Hermann; Bruckman, Viktor; Tambach, Tim; Kempka, ThomasA lithosphere scale geological model has been used to determine the surface heat flow component due to conductive heat transport for the area of Brandenburg. The modelling results have been constrained by a direct comparison with available heat flow measurements. The calculated heat flow captures the regional trend in the surface heat flow distribution which can be related to existing thermal conductivity variations between the different sedimentary units. An additional advective component due to topography induced regional flow and focused flow within major fault zones should be considered to explain the spatial variation observed in the surface heat flow.
- ItemCarrier Lifetime in Liquid-phase Crystallized Silicon on Glass(Amsterdam [u.a.] : Elsevier, 2016) Vetter, Michael; Gawlik, Annett; Plentz, Jonathan; Andrä, Gudrun; Ribeyron, Pierre-Jean; Cuevas, Andres; Weeber, Arthur; Ballif, Christophe; Glunz, Stefan; Poortmans, Jef; Brendel, Rolf; Aberle, Armin; Sinton, Ron; Verlinden, Pierre; Hahn, GisoLiquid-phase crystallized silicon on glass (LPCSG) presents a promising material to fabricate high quality silicon thin films, e.g. for solar cells and modules. Barrier layers and a doped amorphous silicon layer are deposited on the glass substrate followed by crystallization with a line focus laser beam. In this paper we introduce injection level dependent lifetime measurements generated by the quasi steady-state photoconductance decay method (QSSPC) to characterize LPCSG absorbers. This contactless method allows a determination of the LPCSG absorber quality already at an early stage of solar cell fabrication, and provides a monitoring of the absorber quality during the solar cell fabrication steps. We found minority carrier lifetimes higher than 200ns in our layers (e.g. n-type absorber with ND=2x1015cm-3) indicating a surface recombination velocity SBL<3000cm/s at the barrier layer/Si interface.