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End date: 2019 × Start date: 2010 × DDC: 050 × Type: Text × Subject: Chemical Synthesis × WGL Institute: LIKAT ×

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    The Exploration of Aroyltrimethylgermane as Potent Synthetic Origins and Their Preparation
    (Amsterdam [u.a.] : Elsevier, 2019) Yuan, Yang; Zhang, Youcan; Chen, Bo; Wu, Xiao-Feng
    The synthetic utilities of acylgermanes are surprisingly rarely explored compared with their analogues. In this communication, the survey of aroyltrimethylgermane as potent synthetic origins has been studied. A variety of novel chemical transformations have been realized, including using the acylgermane group as a directing group in Rh-catalyzed aromatic C-H alkenylation reaction and Ir-catalyzed aromatic C-H amidation reactions. Additionally, a general approach for acylgermanes preparation has been established as well. The catalytic system proceeds effectively in the presence of Pd(OAc)2/BINOL-based monophosphite (L11) and allows for the straightforward access to a wide range of functionalized acylgermanes in high yields. © 2019 The Author(s)Catalysis; Organic Synthesis; Organic Reaction; Chemical Synthesis © 2019 The Author(s)