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End date: 2019 × Start date: 2010 × Type: Text × Subject: Anisotropy × WGL Institute: IFWD ×

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Now showing 1 - 4 of 4
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    Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc2N@C80-Ih with M running through the whole 4f row
    (Cambridge : RSC, 2015) Zhang, Y.; Krylov, D.; Rosenkranz, M.; Schiemenz, S.; Popov, A. A.
    Paramagnetic and variable temperature 13C and 45Sc nuclear magnetic resonance studies are performed for nitride clusterfullerenes MSc2N@C80 with icosahedral Ih(7) carbon cage, where M runs through all lanthanides forming nitride clusters. The influence of the endohedral lanthanide ions on the NMR spectral pattern is carefully followed, and dramatic differences are found in peak positions and line widths. Thus, 13C lines broaden from 0.01–0.02 ppm in diamagnetic MSc2N@C80 molecules (M = La, Y, Lu) to several ppm in TbSc2N@C80 and DySc2N@C80. Direction of the paramagnetic shift depends on the shape of the 4f electron density in corresponding lanthanide ions. In TmSc2N@C80 and ErSc2N@C80 with prolate 4f-density of lanthanide ions, 13C signals are shifted down-field, whereas 45Sc peaks are shifted up-field versus diamagnetic values. In all other MSc2N@C80 molecules lanthanide ions have oblate-shaped 4f electron density, and the lanthanide-induced shift is negative for 13C and positive for 45Sc peaks. Analysis of the pseudocontact and contact contributions to chemical shifts revealed that the pseudocontact term dominates both in 13C and 45Sc NMR spectra, although contact shifts for 13C signals are also considerable. Point charge computations of the ligand field splitting are performed to explain experimental results, and showed reasonable agreement with experimental pseudocontact shifts. Nitrogen atom bearing large negative charge and located close to the lanthanide ion results in large magnetic anisotropy of lanthanide ions in nitride clusterfullerenes with quasi-uniaxial ligand field.
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    Magnetic flux-trapping of anisotropic-grown Y-Ba-Cu-O bulk superconductors during and after pulsed-field magnetizing processes
    (Milton Park : Taylor & Francis, 2014) Oka, T.; Yamada, Y.; Horiuchi, T.; Ogawa, J.; Fukui, S.; Sato, T.; Yokoyama, K.; Langer, M.
    The magnetic flux penetration into the melt-textured Y-Ba-Cu-O high temperature superconducting bulk magnets were precisely evaluated during and after the pulsed field magnetization processes operated at 30 K. The bulk magnets were carefully fabricated by the cold seeding method with use of a single and a pair of seed crystals composed of the Nd-Ba-Cu-O thin films. These seed crystals were put on the top surfaces of the precursors to let the large grains grow during the heat treatments. We observed the flux penetrations which occurred in the lower applied-field regions at around 3.1 T for the samples bearing the twin seeds than those of the single-seeded crystals at around 3.8 T. This means that the magnetic fluxes are capable of invading into the twin-seeded samples more easily than the single-seeds. It suggests that the anisotropic grain growths of parallel and normal to the rows of seed crystals affects the variations of Jc values with different distributions of the pinning centers, results in the preferential paths for the invading magnetic fluxes.
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    Magnetically induced anisotropy of flux penetration into strong-pinning superconductor/ferromagnet bilayers
    (Bristol : Institute of Physics Publishing, 2019) Simmendinger, J.; Hanisch, J.; Bihler, M.; Ionescu, A.M.; Weigand, M.; Sieger, M.; Hühne, R.; Rijckaert, H.; Van Driessche, I.; Schütz, G.; Albrecht, J.
    We studied the impact of soft ferromagnetic permalloy (Py) on the shielding currents in a strong-pinning superconductor - YBa2Cu3O7-δ with Ba2Y(Nb/Ta)O6 nano-precipitates - by means of scanning transmission x-ray microscopy. Typically and in particular when in the thin film limit, superconductor/ferromagnet (SC/FM) bilayers exhibit isotropic properties of the flux line ensemble at all temperatures. However, in elements with small aspect ratio a significant anisotropy in flux penetration is observed. We explain this effect by local in-plane fields arising from anisotropic magnetic stray fields originated by the ferromagnet. This leads to direction-dependent motion of magnetic vortices inside the SC/FM bilayer. Our results demonstrate that small variations of the magnetic properties can have huge impact on the superconductor.
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    Coupling of chiralities in spin and physical spaces: The Möbius ring as a case study
    (College Park : American Physical Society, 2015) Pylypovskyi, Oleksandr V.; Kravchuk, Volodymyr P.; Sheka, Denis D.; Makarov, Denys; Schmidt, Oliver G.; Gaididei, Yuri
    We show that the interaction of the magnetic subsystem of a curved magnet with the magnet curvature results in the coupling of a topologically nontrivial magnetization pattern and topology of the object. The mechanism of this coupling is explored and illustrated by an example of a ferromagnetic Möbius ring, where a topologically induced domain wall appears as a ground state in the case of strong easy-normal anisotropy. For the Möbius geometry, the curvilinear form of the exchange interaction produces an additional effective Dzyaloshinskii-like term which leads to the coupling of the magnetochirality of the domain wall and chirality of the Möbius ring. Two types of domain walls are found, transversal and longitudinal, which are oriented across and along the Möbius ring, respectively. In both cases, the effect of magnetochirality symmetry breaking is established. The dependence of the ground state of the Möbius ring on its geometrical parameters and on the value of the easy-normal anisotropy is explored numerically.