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Thin film models for an active gel

2017, Kitavtsev, Georgy, Münch, Andreas, Wagner, Barbara

In this study we present a free-boundary problem for an active liquid crystal based on the Beris-Edwards theory that uses a tensorial order parameter and includes active contributions to the stress tensor to analyse the rich defect structure observed in applications such as the Adenosinetriphosphate (ATP) driven motion of a thin film of an actin filament network. The small aspect ratio of the film geometry allows for an asymptotic approximation of the free-boundary problem in the limit of weak elasticity of the network and strong active terms. The new thin film model captures the defect dynamics in the bulk as well as wall defects and thus presents a significant extension of previous models based on the Leslie-Erickson-Parodi theory. Analytic expressions are derived that reveal the interplay of anchoring conditions, film thickness and active terms and their control of transitions of flow structure.

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New insights on the interfacial tension of electrochemical interfaces and the Lippmann equation

2015, Dreyer, Wolfgang, Guhlke, Clemens, Landstorfer, Manuel, Neumann, Johannes, Müller, Rüdiger

The Lippmann equation is considered as universal relationship between interfacial tension, double layer charge, and cell potential. Based on the framework of continuum thermo-electrodynamics we provide some crucial new insights to this relation. In a previous work we have derived a general thermodynamic consistent model for electrochemical interfaces, which showed a remarkable agreement to single crystal experimental data. Here we apply the model to a curved liquid metal electrode. If the electrode radius is large compared to the Debye length, we apply asymptotic analysis methods and obtain the Lippmann equation. We give precise definitions of the involved quantities and show that the interfacial tension of the Lippmann equation is composed of the surface tension of our general model, and contributions arising from the adjacent space charge layers. This finding is confirmed by a comparison of our model to experimental data of several mercury-electrolyte interfaces. We obtain qualitative and quantitative agreement in the 2V potential range for various salt concentrations. We also discuss the validity of our asymptotic model when the electrode radius is comparable to the Debye length.

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Surface induced phase separation of a swelling hydrogel

2018, Hennessy, Matthew G., Münch, Andreas, Wagner, Barbara

We present a formulation of the free boundary problem for a hydrogel that accounts for the interfacial free energy and finite strain due to the large deformation of the polymer network during solvent transport across the free boundary. For the geometry of an initially dry layer fixed at a rigid substrate, our model predicts a phase transition when a critical value of the solvent concentration has been reached near the free boundary. A one-dimensional case study shows that depending on the flux rate at the free boundary an initial saturation front is followed by spinodal decomposition of the hydrogel and the formation of an interfacial front that moves through the layer. Moreover, increasing the shear modulus of the elastic network delays or even suppresses phase separation.

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Overcoming the shortcomings of the Nernst-Planck model

2012, Dreyer, Wolfgang, Guhlke, Clemens, Müller, Rüdiger

This is a study on electrolytes that takes a thermodynamically consistent coupling between mechanics and diffusion into account. It removes some inherent deficiencies of the popular Nernst-Planck model. A boundary problem for equilibrium processes is used to illustrate the new features of our model.

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A diffuse interface model for quasi-incrompressible flows : sharp interface limits and numerics

2012, Aki, Gonca, Daube, Johannes, Dreyer, Wolfgang, Giesselmann, Jan, Kränkel, Mirko, Kraus, Christiane

In this contribution, we investigate a diffuse interface model for quasi–incompressible flows. We determine corresponding sharp interface limits of two different scalings. The sharp interface limit is deduced by matched asymptotic expansions of the fields in powers of the interface. In particular, we study solutions of the derived system of inner equations and discuss the results within the general setting of jump conditions for sharp interface models. Furthermore, we treat, as a subproblem, the convective Cahn–Hilliard equation numerically by a Local Discontinuous Galerkin scheme.

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Asymptotic analysis for Korteweg models

2010, Dreyer, Wolfgang, Giesselmann, Jan, Kraus, Christiane, Rohde, Christiane

This paper deals with a sharp interface limit of the isothermal Navier-Stokes-Korteweg system. The sharp interface limit is performed by matched asymptotic expansions of the fields in powers of the interface width. These expansions are considered in the interfacial region (inner expansions) and in the bulk (outer expansion) and are matched order by order. Particularly we consider the first orders of the corresponding inner equations obtained by a change of coordinates in an interfacial layer. For a specific scaling we establish solvability criteria for these inner equations and recover the results within the general setting of jump conditions for sharp interface models.

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Spin coating of an evaporating polymer solution

2010, Münch, Andreas, Please, Colin P., Wagner, Barbara

We consider a mathematical model of spin coating of a single polymer blended in a solvent. The model describes the one-dimensional development of the thin layer of the mixture as the layer thins due to flow created by a balance of viscous forces and centrifugal forces and due to evaporation of the solvent. In the model both the diffusivity of the solvent in the polymer and the viscosity of the mixture are very rapidly varying functions of the solvent volume fraction. Guided by numerical solutions an asymptotic analysis reveals a number of different possible behaviours of the thinning layer dependent on the nondimensional parameters describing the system. The main practical interest is in controlling the appearance and development of a ``skin'' on the polymer where the solvent concentration reduces rapidly on the outer surface leaving the bulk of the layer still with high concentrations of solvent. The critical parameters controlling this behaviour are found to be eps the ratio of the diffusion to advection time scales, delta the ratio of the evaporation to advection time scales and exp(-gamma), the ratio of the diffusivity of the initial mixture and the pure polymer. In particular, our analysis shows that for very small evaporation with delta ll exp(-3/(4gamma)) eps^3/4 skin formation can be prevented

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Hybrid mode-locking in edge-emitting semiconductor lasers: Simulations, analysis and experiments

2012, Arkhipov, Rostislav, Pimenov, Alexander, Radziunas, Mindaugas, Vladimirov, Andrei G., Arsenjevi´c, Dejan, Rachinskii, Dmitrii, Schmeckebier, Holger, Bimberg, Dieter

Hybrid mode-locking in a two section edge-emitting semiconductor laser is studied numerically and analytically using a set of three delay differential equations. In this set the external RF signal applied to the saturable absorber section is modeled by modulation of the carrier relaxation rate in this section. Estimation of the locking range where the pulse repetition frequency is synchronized with the frequency of the external modulation is performed numerically and the effect of the modulation shape and amplitude on this range is investigated. Asymptotic analysis of the dependence of the locking range width on the laser parameters is carried out in the limit of small signal modulation. Our numerical simulations indicate that hybrid mode-locking can be also achieved in the cases when the frequency of the external modulation is approximately twice larger and twice smaller than the pulse repetition frequency of the free running passively mode-locked laser fP . Finally, we provide an experimental demonstration of hybrid mode-locking in a 20 GHz quantum-dot laser with the modulation frequency of the reverse bias applied to the absorber section close to fP / 2.

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Delayed feedback control of self-mobile cavity solitons

2013, Pimenov, Alexander, Vladimirov, Andrei G., Gurevich, Svetlana V., Panajotov, Krassimir, Huyet, Guillaume, Tlidi, Mustapha

Control of the motion of cavity solitons is one the central problems in nonlinear optical pattern formation. We report on the impact of the phase of the time-delayed optical feedback and carrier lifetime on the self-mobility of localized structures of light in broad area semiconductor cavities. We show both analytically and numerically that the feedback phase strongly affects the drift instability threshold as well as the velocity of cavity soliton motion above this threshold. In addition we demonstrate that non-instantaneous carrier response in the semiconductor medium is responsible for the increase in critical feedback rate corresponding to the drift instability.

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Asymptotic analysis of a tumor growth model with fractional operators

2019, Colli, Pierluigi, Gilardi, Gianni, Sprekels, Jürgen

In this paper, we study a system of three evolutionary operator equations involving fractional powers of selfadjoint, monotone, unbounded, linear operators having compact resolvents. This system constitutes a generalized and relaxed version of a phase field system of Cahn--Hilliard type modelling tumor growth that has originally been proposed in Hawkins-Daarud et al. (Int. J. Numer. Math. Biomed. Eng. 28 (2012), 3--24). The original phase field system and certain relaxed versions thereof have been studied in recent papers co-authored by the present authors and E. Rocca. The model consists of a Cahn--Hilliard equation for the tumor cell fraction φ, coupled to a reaction-diffusion equation for a function S representing the nutrient-rich extracellular water volume fraction. Effects due to fluid motion are neglected. Motivated by the possibility that the diffusional regimes governing the evolution of the different constituents of the model may be of different (e.g., fractional) type, the present authors studied in a recent note a generalization of the systems investigated in the abovementioned works. Under rather general assumptions, well-posedness and regularity results have been shown. In particular, by writing the equation governing the evolution of the chemical potential in the form of a general variational inequality, also singular or nonsmooth contributions of logarithmic or of double obstacle type to the energy density could be admitted. In this note, we perform an asymptotic analysis of the governing system as two (small) relaxation parameters approach zero separately and simultaneously. Corresponding well-posedness and regularity results are established for the respective cases; in particular, we give a detailed discussion which assumptions on the admissible nonlinearities have to be postulated in each of the occurring cases.