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- ItemFulleretic well-defined scaffolds: Donor–fullerene alignment through metal coordination and its effect on photophysics(Hoboken, NJ : Wiley, 2016) Williams, Derek E.; Dolgopolova, Ekaterina A.; Godfrey, Danielle C.; Ermolaeva, Evgeniya D.; Pellechia, Perry J.; Greytak, Andrew B.; Smith, Mark D.; Avdoshenko, Stanislav M.; Popov, Alexey A.; Shustova, Natalia B.Herein, we report the first example of a crystalline metal–donor–fullerene framework, in which control of the donor–fullerene mutual orientation was achieved through chemical bond formation, in particular, by metal coordination. The 13C cross‐polarization magic‐angle spinning NMR spectroscopy, X‐ray diffraction, and time‐resolved fluorescence spectroscopy were performed for comprehensive structural analysis and energy‐transfer (ET) studies of the fulleretic donor–acceptor scaffold. Furthermore, in combination with photoluminescence measurements, the theoretical calculations of the spectral overlap function, Förster radius, excitation energies, and band structure were employed to elucidate the photophysical and ET processes in the prepared fulleretic material. We envision that the well‐defined fulleretic donor–acceptor materials could contribute not only to the basic science of fullerene chemistry but would also be used towards effective development of organic photovoltaics and molecular electronics.
- ItemStimuli‐responsive microjets with reconfigurable shape(Hoboken, NJ : Wiley, 2014) Magdanz, Veronika; Stoychev, Georgi; Ionov, Leonid; Sanchez, Samuel; Schmidt, Oliver.G.Flexible thermoresponsive polymeric microjets are formed by the self‐folding of polymeric layers containing a thin Pt film used as catalyst for self‐propulsion in solutions containing hydrogen peroxide. The flexible microjets can reversibly fold and unfold in an accurate manner by applying changes in temperature to the solution in which they are immersed. This effect allows microjets to rapidly start and stop multiple times by controlling the radius of curvature of the microjet. This work opens many possibilities in the field of artificial nanodevices, for fundamental studies on self‐propulsion at the microscale, and also for biorelated applications.
- ItemHigh-performance Li-O2 batteries with trilayered Pd/MnOx/Pd nanomembranes(Hoboken, NJ : Wiley, 2015) Lu, Xueyi; Deng, Junwen; Si, Wenping; Sun, Xiaolei; Liu, Xianghong; Liu, Bo; Liu, Lifeng; Oswald, Steffen; Baunack, Stefan; Grafe, Hans Joachim; Yan, Chenglin; Schmidt, Oliver G.Trilayered Pd/MnOx/Pd nanomembranes are fabricated as the cathode catalysts for Li‐O2 batteries. The combination of Pd and MnOx facilitates the transport of electrons, lithium ions, and oxygen‐containing intermediates, thus effectively decomposing the discharge product Li2O2 and significantly lowering the charge overpotential and enhancing the power efficiency. This is promising for future environmentally friendly applications.
- ItemControllable sliding transfer of wafer‐size graphene(Hoboken, NJ : Wiley, 2016) Lu, Wenjing; Zeng, Mengqi; Li, Xuesong; Wang, Jiao; Tan, Lifang; Shao, Miaomiao; Han, Jiangli; Wang, Sheng; Yue, Shuanglin; Zhang, Tao; Hu, Xuebo; Mendes, Rafael G.; Rümmeli, Mark H.; Peng, Lianmao; Liu, Zhongfan; Fu, LeiThe innovative design of sliding transfer based on a liquid substrate can succinctly transfer high‐quality, wafer‐size, and contamination‐free graphene within a few seconds. Moreover, it can be extended to transfer other 2D materials. The efficient sliding transfer approach can obtain high‐quality and large‐area graphene for fundamental research and industrial applications.
- ItemDirect transfer of magnetic sensor devices to elastomeric supports for stretchable electronics(Hoboken, NJ : Wiley, 2015) Melzer, Michael; Karnaushenko, Daniil; Lin, Gungun; Baunack, Stefan; Makarov, Denys; Schmidt, Oliver G.A novel fabrication method for stretchable magnetoresistive sensors is introduced, which allows the transfer of a complex microsensor systems prepared on common rigid donor substrates to prestretched elastomeric membranes in a single step. This direct transfer printing method boosts the fabrication potential of stretchable magnetoelectronics in terms of miniaturization and level of complexity, and provides strain‐invariant sensors up to 30% tensile deformation.
- ItemWearable magnetic field sensors for flexible electronics(Hoboken, NJ : Wiley, 2014) Melzer, Michael; Mönch, Jens Ingolf; Makarov, Denys; Zabila, Yevhen; Bermúdez, Gilbert Santiago Cañón; Karnaushenko, Daniil; Baunack, Stefan; Bahr, Falk; Yan, Chenglin; Kaltenbrunner, Martin; Schmidt, Oliver G.Highly flexible bismuth Hall sensors on polymeric foils are fabricated, and the key optimization steps that are required to boost their sensitivity to the bulk value are identified. The sensor can be bent around the wrist or positioned on the finger to realize an interactive pointing device for wearable electronics. Furthermore, this technology is of great interest for the rapidly developing market of eMobility, for optimization of eMotors and magnetic bearings.
- ItemBiomimetic microelectronics for regenerative neuronal cuff implants(Hoboken, NJ : Wiley, 2015) Karnaushenko, Daniil; Münzenrieder, Niko; Karnaushenko, Dmitriy D.; Koch, Britta; Meyer, Anne K.; Baunack, Stefan; Petti, Luisa; Tröster, Gerhard; Makarov, Denys; Schmidt, Oliver G.Smart biomimetics, a unique class of devices combining the mechanical adaptivity of soft actuators with the imperceptibility of microelectronics, is introduced. Due to their inherent ability to self‐assemble, biomimetic microelectronics can firmly yet gently attach to an inorganic or biological tissue enabling enclosure of, for example, nervous fibers, or guide the growth of neuronal cells during regeneration.
- ItemChemotactic behavior of catalytic motors in microfluidic channels(Hoboken, NJ : Wiley, 2013) Baraban, Larysa; Harazim, Stefan M.; Sanchez, Samuel; Schmidt, Oliver.G.Chemotaxis in practice: Two different artificial catalytic micromotors (tubular and spherical, see scheme) show chemotactic behavior in microfluidic channels demonstrating that catalytic micromotors can sense the gradient of chemical fuel in their environment and be directed towards desired locations.
- ItemMononuclear clusterfullerene single‐molecule magnet containing strained fused‐pentagons stabilized by a nearly linear metal cyanide cluster(Hoboken, NJ : Wiley, 2017) Liu, Fupin; Wang, Song; Gao, Cong-Li; Deng, Qingming; Zhu, Xianjun; Kostanyan, Aram; Westerstrçm, Rasmus; Jin, Fei; Xie, Su‐Yuan; Popov, Alexey A.; Greber, Thomas; Yang, ShangfengFused‐pentagons results in an increase of local steric strain according to the isolated pentagon rule (IPR), and for all reported non‐IPR clusterfullerenes multiple (two or three) metals are required to stabilize the strained fused‐pentagons, making it difficult to access the single‐atom properties. Herein, we report the syntheses and isolations of novel non‐IPR mononuclear clusterfullerenes MNC@C76 (M=Tb, Y), in which one pair of strained fused‐pentagon is stabilized by a mononuclear cluster. The molecular structures of MNC@C76 (M=Tb, Y) were determined unambiguously by single‐crystal X‐ray diffraction, featuring a non‐IPR C2v(19138)‐C76 cage entrapping a nearly linear MNC cluster, which is remarkably different from the triangular MNC cluster within the reported analogous clusterfullerenes based on IPR‐obeying C82 cages. The TbNC@C76 molecule is found to be a field‐induced single‐molecule magnet (SMM).
- ItemMethane as a selectivity booster in the arc-discharge synthesis of endohedral fullerenes: Selective synthesis of the single-molecule magnet Dy2TiC@C80and Its Congener Dy2TiC2@C80(Hoboken, NJ : Wiley, 2015) Junghans, Katrin; Schlesier, Christin; Kostanyan, Aram; Samoylova, Nataliya A.; Deng, Qingming; Rosenkranz, Marco; Schiemenz, Sandra; Westerström, Rasmus; Greber, Thomas; Büchner, Bernd; Greber, Thomas; Popov, Alexey A.The use of methane as a reactive gas dramatically increases the selectivity of the arc‐discharge synthesis of M‐Ti‐carbide clusterfullerenes (M=Y, Nd, Gd, Dy, Er, Lu). Optimization of the process parameters allows the synthesis of Dy2TiC@C80‐I and its facile isolation in a single chromatographic step. A new type of cluster with an endohedral acetylide unit, M2TiC2@C80, is discovered along with the second isomer of M2TiC@C80. Dy2TiC@C80‐(I,II) and Dy2TiC2@C80‐I are shown to be single‐molecule magnets (SMM), but the presence of the second carbon atom in the cluster Dy2TiC2@C80 leads to substantially poorer SMM properties.