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End date: 2020 × Start date: 2016 × DDC: 690 × Publisher: Cambridge : RSC Publ. ×

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    The mutual dependence of negative emission technologies and energy systems
    (Cambridge : RSC Publ., 2019) Creutzig, Felix; Breyer, Christian; Hilaire, Jérôme; Minx, Jan; Peters, Glen P.; Socolow, Robert
    While a rapid decommissioning of fossil fuel technologies deserves priority, most climate stabilization scenarios suggest that negative emission technologies (NETs) are required to keep global warming well below 2 °C. Yet, current discussions on NETs are lacking a distinct energy perspective. Prominent NETs, such as bioenergy with carbon capture and storage (BECCS) and direct air carbon capture and storage (DACCS), will integrate differently into the future energy system, requiring a concerted research effort to determine adequate means of deployment. In this perspective, we discuss the importance of energy per carbon metrics, factors of future cost development, and the dynamic response of NETs in intermittent energy systems. The energy implications of NETs deployed at scale are massive, and NETs may conceivably impact future energy systems substantially. DACCS outperform BECCS in terms of primary energy required per ton of carbon sequestered. For different assumptions, DACCS displays a sequestration efficiency of 75–100%, whereas BECCS displays a sequestration efficiency of 50–90% or less if indirect land use change is included. Carbon dioxide removal costs of DACCS are considerably higher than BECCS, but if DACCS modularity and granularity helps to foster technological learning to <100$ per tCO2, DACCS may remove CO2 at gigaton scale. DACCS also requires two magnitudes less land than BECCS. Designing NET systems that match intermittent renewable energies will be key for stringent climate change mitigation. Our results contribute to an emerging understanding of NETs that is notably different to that derived from scenario modelling.
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    Mg3(Bi,Sb)2 single crystals towards high thermoelectric performance
    (Cambridge : RSC Publ., 2020) Pan, Yu; Yao, Mengyu; Hong, Xiaochen; Zhu, Yifan; Fan, Fengren; Imasato, Kazuki; He, Yangkun; Hess, Christian; Fink, Jörg; Yang, Jiong; Büchner, Bernd; Fu, Chenguang; Snyder, G. Jeffrey; Felser, Claudia
    The rapid growth of the thermoelectric cooler market makes the development of novel room temperature thermoelectric materials of great importance. Ternary n-type Mg3(Bi,Sb)2 alloys are promising alternatives to the state-of-the-art Bi2(Te,Se)3 alloys but grain boundary resistance is the most important limitation. n-type Mg3(Bi,Sb)2 single crystals with negligible grain boundaries are expected to have particularly high zT but have rarely been realized due to the demanding Mg-rich growth conditions required. Here, we report, for the first time, the thermoelectric properties of n-type Mg3(Bi,Sb)2 alloyed single crystals grown by a one-step Mg-flux method using sealed tantalum tubes. High weighted mobility ∼140 cm2 V−1 s−1 and a high zT of 0.82 at 315 K are achieved in Y-doped Mg3Bi1.25Sb0.75 single crystals. Through both experimental angle-resolved photoemission spectroscopy and theoretical calculations, we denote the origin of the high thermoelectric performance from a point of view of band widening effect and electronegativity, as well as the necessity to form high Bi/Sb ratio ternary Mg3(Bi,Sb)2 alloys. The present work paves the way for further development of Mg3(Bi,Sb)2 for near room temperature thermoelectric applications.
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    Unveiling the phonon scattering mechanisms in half-Heusler thermoelectric compounds
    (Cambridge : RSC Publ., 2020) He, Ran; Zhu, Taishan; Wang, Yumei; Wolff, Ulrike; Jaud, Jean-Christophe; Sotnikov, Andrei; Potapov, Pavel; Wolf, Daniel; Ying, Pingjun; Wood, Max; Liu, Zhenhui; Feng, Le; Perez Rodriguez, Nicolas; Snyder, G. Jeffrey; Grossman, Jeffrey C.; Nielsch, Kornelius; Schierning, Gabi
    Half-Heusler (HH) compounds are among the most promising thermoelectric (TE) materials for large-scale applications due to their superior properties such as high power factor, excellent mechanical and thermal reliability, and non-toxicity. Their only drawback is the remaining-high lattice thermal conductivity. Various mechanisms were reported with claimed effectiveness to enhance the phonon scattering of HH compounds including grain-boundary scattering, phase separation, and electron–phonon interaction. In this work, however, we show that point-defect scattering has been the dominant mechanism for phonon scattering other than the intrinsic phonon–phonon interaction for ZrCoSb and possibly many other HH compounds. Induced by the charge-compensation effect, the formation of Co/4d Frenkel point defects is responsible for the drastic reduction of lattice thermal conductivity in ZrCoSb1−xSnx. Our work systematically depicts the phonon scattering profile of HH compounds and illuminates subsequent material optimizations.