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    Chronostratigraphy of silt-dominated Pleistocene periglacial slope deposits on Mt. Ślęża (SW, Poland): Palaeoenvironmental and pedogenic significance
    (New York, NY [u.a.] : Elsevier, 2020) Waroszewski, Jaroslaw; Sprafke, Tobias; Kabala, Cezary; Musztyfaga, Elżbieta; Kot, Aleksandra; Tsukamoto, Sumiko; Frechen, Manfred
    Slope deposits with aeolian silt admixture are a widespread parent material of soils in the temperate zone but may be neglected when rates of soil production are quantified. The concept of periglacial cover beds differentiates slope deposits with or without aeolian silt admixture; yet there is a remaining debate on processes and the timing of their formation. A previous study done by us at Mt. Ślęża, SW Poland, concluded that slope deposits with variable aeolian silt admixture, or its lack, have a significant influence on the pathway of soil formation. The present work builds upon this finding, by adding further granulometric and micromorphological data from three representative profiles along a toposequence, in order to refine our understanding of local slope deposits and soil formation. Additionally, seven numerical ages using luminescence dating provide a chronological framework for our reconstructions and allow linking the forming processes of these pedosedimentary records to regional palaeoenvironmental conditions. The oldest aeolian deposits are of Middle Pleistocene age (>280 ± 19 ka) with interlayered palaeosol (marine isotope stage [MIS] 9 or older). Late Pleistocene slope deposits encompass the maximum loess thickness and are dated to MIS 2. Luminescence ages from the upper layers indicate shallow reworking, which we tentatively correlate to the Younger Dryas (YD). Two profiles with thick loess mantles have strong clay illuviation features, presumably formed during the Holocene. However, weak clay illuviation in the third profile with a thin loess mantle (having an age of YD) over granite regolith seems to have occurred before the Holocene, as only fragmented clay coatings (probably MIS 2 pedogenesis) could be found. © 2020 The Authors
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    Copper-iron bimetal ion-exchanged sapo-34 for NH3-scr of NOx
    (Basel : MDPI, 2020) Doan, Tuan; Dam, Phong; Nguyen, Khang; Vuong, Thanh Huyen; Le, Minh Thang; Pham, Thanh Huyen
    SAPO-34 was prepared with a mixture of three templates containing triethylamine, tetraethylammonium hydroxide, and morpholine, which leads to unique properties for support and production cost reduction. Meanwhile, Cu/SAPO-34, Fe/SAPO-34, and Cu-Fe/SAPO-34 were prepared through the ion-exchanged method in aqueous solution and used for selective catalytic reduction (SCR) of NOx with NH3. The physical structure and original crystal of SAPO-34 are maintained in the catalysts. Cu-Fe/SAPO-34 catalysts exhibit high NOx conversion in a broad temperature window, even in the presence of H2O. The physicochemical properties of synthesized samples were further characterized by various methods, including XRD, FE-SEM, EDS, N2 adsorption-desorption isotherms, UV-Vis-DRS spectroscopy, NH3-TPD, H2-TPR, and EPR. The best catalyst, 3Cu-1Fe/SAPO-34 exhibited high NOx conversion (> 90%) in a wide temperature window of 250–600 °C, even in the presence of H2O. In comparison with mono-metallic samples, the 3Cu-1Fe/SAPO-34 catalyst had more isolated Cu2+ ions and additional oligomeric Fe3+ active sites, which mainly contributed to the higher capacity of NH3 and NOx adsorption by the enhancement of the number of acid sites as well as its greater reducibility. Therefore, this synergistic effect between iron and copper in the 3Cu-1Fe/SAPO-34 catalyst prompted higher catalytic performance in more extensive temperature as well as hydrothermal stability after iron incorporation. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
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    The Cyclostratigraphy Intercomparison Project (CIP): consistency, merits and pitfalls
    (Amsterdam [u.a.] : Elsevier, 2019) Sinnesael, Matthias; De Vleeschouwer, David; Zeeden, Christian; Batenburg, Sietske J.; Da Silva, Anne-Christine; de Winter, Niels J.; Dinarès-Turell, Jaume; Drury, Anna Joy; Gambacorta, Gabriele; Hilgen, Frederik J.; Hinnov, Linda A.; Hudson, Alexander J.L.; Kemp, David B.; Lantink, Margriet L.; Laurin, Jiří; Li, Mingsong; Liebrand, Diederik; Ma, Chao; Meyers, Stephen R.; Monkenbusch, Johannes; Montanari, Alessandro; Nohl, Theresa; Pälike, Heiko; Pas, Damien; Ruhl, Micha; Thibault, Nicolas; Vahlenkamp, Maximilian; Valero, Luis; Wouters, Sébastien; Wu, Huaichun; Claeys, Philippe
    Cyclostratigraphy is an important tool for understanding astronomical climate forcing and reading geological time in sedimentary sequences, provided that an imprint of insolation variations caused by Earth’s orbital eccentricity, obliquity and/or precession is preserved (Milankovitch forcing). Numerous stratigraphic and paleoclimate studies have applied cyclostratigraphy, but the robustness of the methodology and its dependence on the investigator have not been systematically evaluated. We developed the Cyclostratigraphy Intercomparison Project (CIP) to assess the robustness of cyclostratigraphic methods using an experimental design of three artificial cyclostratigraphic case studies with known input parameters. Each case study is designed to address specific challenges that are relevant to cyclostratigraphy. Case 1 represents an offshore research vessel environment, as only a drill-core photo and the approximate position of a late Miocene stage boundary are available for analysis. In Case 2, the Pleistocene proxy record displays clear nonlinear cyclical patterns and the interpretation is complicated by the presence of a hiatus. Case 3 represents a Late Devonian proxy record with a low signal-to-noise ratio with no specific theoretical astronomical solution available for this age. Each case was analyzed by a test group of 17-20 participants, with varying experience levels, methodological preferences and dedicated analysis time. During the CIP 2018 meeting in Brussels, Belgium, the ensuing analyses and discussion demonstrated that most participants did not arrive at a perfect solution, which may be partly explained by the limited amount of time spent on the exercises (∼4.5 hours per case). However, in all three cases, the median solution of all submitted analyses accurately approached the correct result and several participants obtained the exact correct answers. Interestingly, systematically better performances were obtained for cases that represented the data type and stratigraphic age that were closest to the individual participants’ experience. This experiment demonstrates that cyclostratigraphy is a powerful tool for deciphering time in sedimentary successions and, importantly, that it is a trainable skill. Finally, we emphasize the importance of an integrated stratigraphic approach and provide flexible guidelines on what good practices in cyclostratigraphy should include. Our case studies provide valuable insight into current common practices in cyclostratigraphy, their potential merits and pitfalls. Our work does not provide a quantitative measure of reliability and uncertainty of cyclostratigraphy, but rather constitutes a starting point for further discussions on how to move the maturing field of cyclostratigraphy forward.
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    A post-IR IRSL chronology and dust mass accumulation rates of the Nosak loess-palaeosol sequence in northeastern Serbia
    (Oxford [u.a.] : Wiley-Blackwell, 2020) Perić, Zoran M.; Marković, Slobodan B.; Sipos, György; Gavrilov, Milivoj B.; Thiel, Christine; Zeeden, Christian; Murray, Andrew S.
    In the Middle Danube Basin, Quaternary deposits are widely distributed in the Vojvodina region where they cover about 95% of the area. Major research during the last two decades has been focused on loess deposits in the Vojvodina region. During this period, loess in the Vojvodina region has become one of the most important Pleistocene European continental climatic and environmental records. Here we present the dating results of 15 samples taken from the Nosak loess-palaeosol sequence in northeastern Serbia in order to establish a chronology over the last three glacial–interglacial cycles. We use the pIRIR290 signal of the 4–11 μm polymineral grains. The calculated ages are within the error limits partially consistent with the proposed multi-millennial chronostratigraphy for Serbian loess. The average mass accumulation rate for the last three glacial–interglacial cycles is 265 g m−2 a−1, which is in agreement with the values of most sites in the Carpathian Basin. Our results indicate a highly variable deposition rate of loess, especially during the MIS 3 and MIS 6 stages, which is contrary to most studies conducted in Serbia where linear sedimentation rates were assumed. © 2020 The Authors. Boreas published by John Wiley & Sons Ltd on behalf of The Boreas Collegium
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    Ice-marginal forced regressive deltas in glacial lake basins: geomorphology, facies variability and large-scale depositional architecture
    (Oxford [u.a.] : Wiley-Blackwell, 2018) Winsemann, Jutta; Lang, Jörg; Polom, Ulrich; Loewer, Markus; Igel, Jan; Pollok, Lukas; Brandes, Christian
    This study presents a synthesis of the geomorphology, facies variability and depositional architecture of ice-marginal deltas affected by rapid lake-level change. The integration of digital elevation models, outcrop, borehole, ground-penetrating radar and high-resolution shear-wave seismic data allows for a comprehensive analysis of these delta systems and provides information about the distinct types of deltaic facies and geometries generated under different lake-level trends. The exposed delta sediments record mainly the phase of maximum lake level and subsequent lake drainage. The stair-stepped profiles of the delta systems reflect the progressive basinward lobe deposition during forced regression when the lakes successively drained. Depending on the rate and magnitude of lake-level fall, fan-shaped, lobate or more digitate tongue-like delta morphologies developed. Deposits of the stair-stepped transgressive delta bodies are buried, downlapped and onlapped by the younger forced regressive deposits. The delta styles comprise both Gilbert-type deltas and shoal-water deltas. The sedimentary facies of the steep Gilbert-type delta foresets include a wide range of gravity-flow deposits. Delta deposits of the forced-regressive phase are commonly dominated by coarse-grained debrisflow deposits, indicating strong upslope erosion and cannibalization of older delta deposits. Deposits of supercritical turbidity currents are particularly common in sand-rich Gilbert-type deltas that formed during slow rises in lake level and during highstands. Foreset beds consist typically of laterally and vertically stacked deposits of antidunes and cyclic steps. The trigger mechanisms for these supercritical turbidity currents were both hyperpycnal meltwater flows and slope-failure events. Shoal-water deltas formed at low water depths during both low rates of lake-level rise and forced regression. Deposition occurred from tractional flows. Transgressive mouthbars form laterally extensive sand-rich delta bodies with a digitate, multi-tongue morphology. In contrast, forced regressive gravelly shoal-water deltas show a high dispersion of flow directions and form laterally overlapping delta lobes. Deformation structures in the forced-regressive ice-marginal deltas are mainly extensional features, including normal faults, small graben or half-graben structures and shear-deformation bands, which are related to gravitational delta tectonics, postglacial faulting during glacial-isostatic adjustment, and crestal collapse above salt domes. A neotectonic component cannot be ruled out in some cases. © 2018 The Authors. Boreas published by John Wiley & Sons Ltd on behalf of The Boreas Collegium
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    Assessment and Public Reporting of Geothermal Resources in Germany: Review and Outlook
    (Basel : MDPI, 2018) Agemar, Thorsten; Weber, Josef; Moeck, Inga S.
    Any geothermal resource assessment requires consistent and widely accepted terminology, methods, and reporting schemes that facilitate the comparison of geothermal resource estimates. This paper reviews common resource assessment methods, as well as reporting codes and terminology. Based on a rigorous analysis of the portrayed concepts and methods, it discusses the appropriateness of the existing reporting codes for sustainable utilization of geothermal resources in Germany. Since the last quantitative geothermal resource assessment in Germany was done 15 years ago, a revised report is overdue. Unlike fossil energy commodities, geothermal energy replenishes naturally and heat recuperation increases in created heat sinks. This replenishment process offers the opportunity for sustainable reservoir management in the case of moderate production rates or cyclic operation. Existing reporting codes, however, regard geothermal resources in a similar way to fossil resources or focus too much on field development rather than on the whole assessment process. In order to emphasize the renewability of geothermal energy, we propose the reporting of geothermal capacities (per doublet or per km2) instead of recoverable heat energy which depends very much on project lifetime and other factors. As a first step, a new classification scheme for geothermal resources and reserves is outlined.
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    Predictability of properties of a fractured geothermal reservoir: the opportunities and limitations of an outcrop analogue study
    (Berlin ; Heidelberg [u.a.] : SpringerOpen, 2017) Bauer, Johanna F.; Krumbholz, Michael; Meier, Silke; Tanner, David C.
    Minimizing exploration risk in deep geothermics is of great economic importance. Especially, knowledge about temperature and permeability of the reservoir is essential. We test the potential of an outcrop analogue study to minimize uncertainties in prediction of the rock properties of a fractured reservoir in the Upper Rhine Graben. Our results show that although mineralogical composition, clay content, grain size, and fabric type are basically comparable, porosity and quartz cementation are not. Young’s modulus, as observed in the outcrop closest to the reservoir is about twice as high (~ 64 GPa) as observed in the reservoir (~ 34 GPa). Most importantly, however, the parameters that describe the fracture system, which are essential to predict reservoir permeability, differ significantly. While the outcrops are dominated by perpendicular fracture sets (striking NE–SW and NW–SE), two different conjugate fracture sets (striking NW–SE and N–S) occur in the reservoir. Fracture apertures, as reported from the FMI, are one order of magnitude wider than in the outcrop. We conclude that our outcrop analogue study fails to predict important properties of the reservoir (such as permeability and porosity). This must be in part because of the tectonically complex setting of the reservoir. We propose that analogue studies are important, but they must be treated with care when attempting to predict the controlling parameters of a fractured reservoir.
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    A new method for correcting temperature log profiles in low-enthalpy plays
    (Berlin ; Heidelberg [u.a.] : Springer Open, 2020) Schumacher, Sandra; Moeck, Inga
    Temperature logs recorded shortly after drilling operations can be the only temperature information from deep wells. However, these measurements are still influenced by the thermal disturbance caused by drilling and therefore do not represent true rock temperatures. The magnitude of the thermal disturbance is dependent on many factors such as drilling time, logging procedure or mud temperature. However, often old well reports lack this crucial information so that conventional corrections on temperature logs cannot be performed. This impedes the re-evaluation of well data for new exploration purposes, e.g. for geothermal resources. This study presents a new method to correct log temperatures in low-enthalpy play types which only requires a knowledge of the final depth of the well as an input parameter. The method was developed and verified using existing well data from an intracratonic sedimentary basin, the eastern part of the North German Basin. It can be transferred to other basins with little or no adjustment. © 2020, The Author(s).
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    Predictability and controlling factors of overpressure in the North Alpine Foreland Basin, SE Germany: an interdisciplinary post-drill analysis of the Geretsried GEN-1 deep geothermal well
    (Berlin ; Heidelberg [u.a.] : Springer Open, 2020) Drews, Michael C.; Hofstetter, Peter; Zosseder, Kai; Shipilin, Vladimir; Stollhofen, Harald
    The North Alpine Foreland Basin in SE Germany is Germany’s most active deep geothermal province. However, in its southern and eastern part the basin is considerably overpressured, which is a significant challenge for drilling deep geothermal wells. In this study, we combine drilling data and velocity-based pore pressure analyses with 3D basin modeling to assess the predictability and controlling factors of overpressure in the sub-regional context (area of 80 km × 50 km) around the Geretsried GEN-1 well, a deep geothermal exploration well in the southern part of the North Alpine Foreland Basin in SE Germany. Drilling data and velocity-based pore pressure analyses indicate overpressure maxima in the Lower Oligocene (Rupelian and Schoeneck Formation) and up to mild overpressure in the Upper Oligocene (Chattian) and Upper Cretaceous, except for the hydrostatically pressured northwestern part of the study area. 3D basin modeling calibrated to four hydrocarbon wells surrounding the Geretsried GEN-1 well demonstrates the dominating role of disequilibrium compaction and low permeability units related to overpressure generation in the North Alpine Foreland Basin. However, secondary overpressure generation mechanisms are likely contributing. Also, the impact of Upper Cretaceous shales, which are eroded in the northwestern part of the study area, on overpressure maintenance is investigated. The calibrated basin model is tested against the drilling history and velocity (VSP) data-based pore pressure estimate of the Geretsried GEN-1 well and reveals that pore pressure prediction is generally possible using 3D basin modeling in the North Alpine Foreland Basin, but should be improved with more detailed analysis of lateral drainage systems and facies variations in the future. The results of the study are of relevance to future well planning and drilling as well as to geomechanical modeling of subsurface stresses and deep geothermal production in the North Alpine Foreland Basin. © 2020, The Author(s).
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    Probability of success studies for geothermal projects in clastic reservoirs: From subsurface data to geological risk analysis
    (Amsterdam [u.a.] : Elsevier Science, 2020) Schumacher, Sandra; Pierau, Roberto; Wirth, Wolfgang
    In the realisation of a geothermal project, an important step is the quantification of the geological risk of a well not achieving the economically necessary cut-off values with respect to temperature and flowrate/drawdown. In this paper, we present a new method for calculating this risk via a probability of success study by using all available types of hydraulic data, including porosity values derived from core samples or borehole logs. This method has been developed for geothermal projects in fluvial sandstones of the North German Basin but can be applied to any clastic, not fracture-dominated reservoir worldwide. © 2019 The Authors