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- ItemA new method to measure real-world respiratory tract deposition of inhaled ambient black carbon(Amsterdam [u.a.] : Elsevier Science, 2019) Madueño, Leizel; Kecorius, Simonas; Löndahl, Jakob; Müller, Thomas; Pfeifer, Sascha; Haudek, Andrea; Mardoñez, Valeria; Wiedensohler, AlfredIn this study, we present the development of a mobile system to measure real-world total respiratory tract deposition of inhaled ambient black carbon (BC). Such information can be used to supplement the existing knowledge on air pollution-related health effects, especially in the regions where the use of standard methods and intricate instrumentation is limited. The study is divided in two parts. Firstly, we present the design of portable system and methodology to evaluate the exhaled air BC content. We demonstrate that under real-world conditions, the proposed system exhibit negligible particle losses, and can additionally be used to determine the minute ventilation. Secondly, exemplary experimental data from the system is presented. A feasibility study was conducted in the city of La Paz, Bolivia. In a pilot experiment, we found that the cumulative total respiratory tract deposition dose over 1-h commuting trip would result in approximately 2.6 μg of BC. This is up to 5 times lower than the values obtained from conjectural approach (e.g. using physical parameters from previously reported worksheets). Measured total respiratory tract deposited BC fraction varied from 39% to 48% during walking and commuting inside a micro-bus, respectively. To the best of our knowledge, no studies focusing on experimental determination of real-world deposition dose of BC have been performed in developing regions. This can be especially important because the BC mass concentration is significant and determines a large fraction of particle mass concentration. In this work, we propose a potential method, recommendations, as well as the limitations in establishing an easy and relatively cheap way to estimate the respiratory tract deposition of BC. In this study we present a novel method to measure real-world respiratory tract deposition dose of Black Carbon. Results from a pilot study in La Paz, Bolivia, are presented. © 2019 The Authors
- ItemCylindrospermopsin is effectively degraded in water by pulsed corona-like and dielectric barrier discharges(Amsterdam [u.a.] : Elsevier Science, 2020) Schneider, Marcel; Rataj, Raphael; Kolb, Juergen F.; Bláha, LuděkCylindrospermopsin (CYN) is an important cyanobacterial toxin posing a major threat to surface waters during cyanobacterial blooms. Hence, methods for cyanotoxin removal are required to confront seasonal or local incidences to sustain the safety of potable water reservoirs. Non-thermal plasmas provide the possibility for an environmentally benign treatment which can be adapted to specific concentrations and environmental conditions without the need of additional chemicals. We therefore investigated the potential of two different non-thermal plasma approaches for CYN degradation, operated either in a water mist, i.e. in air, or submerged in water. A degradation efficacy of 0.03 ± 0.00 g kWh−1 L−1 was found for a dielectric barrier discharge (DBD) operated in air, while a submerged pulsed corona-like discharge resulted in an efficacy of 0.24 ± 0.02 g kWh−1 L−1. CYN degradation followed a pseudo zeroth order or pseudo first order reaction kinetic, respectively. Treatment efficacy of the corona-like discharge submerged in water increased with pH values of the initial solution changing from 5.0 to 7.5. Notably, a pH-depending residual oxidative effect was observed for the submerged discharge, resulting in ongoing CYN degradation, even without further plasma treatment. In this case hydroxyl radicals were identified as the dominant oxidants of CYN at acidic pH values. In comparison, degradation by the DBD could be related primarily to the generation of ozone. © 2020 The AuthorsThe degradation of cylindrospermopsin by a pulsed corona-like discharge in water was more effective compared with a pulsed dielectric barrier discharge in air around a water mist. © 2020 The Authors
- ItemEffect of 1-Methyl Cyclopropane and Modified Atmosphere Packaging on the Storage of Okra (Abelmoschus esculentus L.) : Theory and Experiments(Basel : MDPI, 2020) Kanwal, Rabia; Ashraf, Hadeed; Sultan, Muhammad; Babu, Irrum; Yasmin, Zarina; Nadeem, Muhammad; Asghar, Muhammad; Shamshiri, Redmond R.; Ibrahim, Sobhy M.; Ahmad, Nisar; Imran, Muhammad A.; Zhou, Yuguang; Ahmad, RiazOkra possesses a short shelf-life which limits its marketability, thereby, the present study investigates the individual and combined effect of 1-methylcyclopropene (1-MCP) and modified atmosphere packaging (MAP) on the postharvest storage life of okra. The treated/ untreated okra samples were stored at ambient (i.e., 27 °C) and low (i.e., 7 °C) temperatures for eight and 20 days, respectively. Results revealed that the 1-MCP and/or MAP treatment successfully inhibited fruit softening, reduction in mucilage viscosity, and color degradation (hue angle, ∆E, and BI) in the product resulting in a longer period of shelf-life. However, MAP with or without 1-MCP was more effective to reduce weight loss in okra stored at both ambient and cold storage conditions. Additionally, ascorbic acid and total antioxidants were also retained in 1-MCP with MAP during cold storage. The 1-MCP in combination with MAP effectively suppressed respiration rate and ethylene production for four days and eight days at 27 °C and 7 °C temperature conditions, respectively. According to the results, relatively less chilling injury stress also resulted when 1-MCP combined with MAP. The combined treatment of okra pods with 1-MCP and MAP maintained the visual quality of the product in terms of overall acceptability for four days at 20 °C and 20 days at 7 °C.
- ItemInvestigating Solid and Liquid Desiccant Dehumidification Options for Room Air-Conditioning and Drying Applications(Basel : MDPI, 2020) Naik, B. Kiran; Joshi, Mullapudi; Muthukumar, Palanisamy; Sultan, Muhammad; Miyazaki, Takahiko; Shamshiri, Redmond R.; Ashraf, HadeedThis study reports on the investigation of the performance of single and two-stage liquid and solid desiccant dehumidification systems and two-stage combined liquid and solid desiccant dehumidification systems with reference to humid climates. The research focus is on a dehumidification system capacity of 25 kW designed for room air conditioning application using the thermal models reported in the literature. RD-type silica gel and LiCl are used as solid and liquid desiccant materials, respectively. In this study, the application of proposed system for deep drying application is also explored. Condensation rate and moisture removal efficiency are chosen as performance parameters for room air conditioning application, whereas air outlet temperature is chosen as performance parameter for deep drying application. Further, for a given range of operating parameters, influences of air inlet humidity ratio, flow rate, and inlet temperature on performance parameters of the systems are investigated. In humid climatic conditions, it has been observed that a two-stage liquid desiccant dehumidification system is more effective for room air conditioning application, and two-stage solid desiccant dehumidification system is more suitable for deep drying application in the temperature range of 50 to 70 °C, while single-stage solid desiccant and two-stage combined liquid and solid desiccant dehumidification systems are more effective for low temperature, i.e., 30 to 50 °C deep drying application.
- ItemSpatial-Explicit Climate Change Vulnerability Assessments Based on Impact Chains. Findings from a Case Study in Burundi(Basel : MDPI, 2020) Schneiderbauer, Stefan; Baunach, Daniel; Pedoth, Lydia; Renner, Kathrin; Fritzsche, Kerstin; Bollin, Christina; Pregnolato, Marco; Zebisch, Marc; Liersch, Stefan; Rivas López, María del Rocío; Ruzima, SalvatorClimate change vulnerability assessments are an essential instrument to identify regions most vulnerable to adverse impacts of climate change and to determine appropriate adaptation measures. Vulnerability assessments directly support countries in developing adaptation plans and in identifying possible measures to reduce adverse consequences of changing climate conditions. Against this background, this paper describes a vulnerability assessment using an integrated and participatory approach that builds on standardized working steps of previously developed ‘Vulnerability Sourcebook’ guidelines. The backbone of this approach is impact chains as a conceptual model of cause–effect relationships as well as a structured selection of indicators according to the three main components of vulnerability, namely exposure, sensitivity and adaptive capacity. We illustrate our approach by reporting the results of a vulnerability assessment conducted in Burundi focusing on climate change impacts on water and soil resources. Our work covers two analysis scales: a national assessment with the aim to identify climate change ‘hotspot regions’ through vulnerability mapping; and a local assessment aiming at identifying local-specific drivers of vulnerability and appropriate adaptation measures. Referring to this vulnerability assessment in Burundi, we discuss the potentials and constraints of the approach. We stress the need to involve stakeholders in every step of the assessment and to communicate limitations and uncertainties of the applied methods, indicators and maps in order to increase the comprehension of the approach and the acceptance of the results by different stakeholders. The study proved the practical usability of the approach at the national level by the selection of three particularly vulnerable areas. The results at a local scale supported the identification of adaption measures through intensive engagement of local rural populations.
- ItemInterplay between Diets, Health, and Climate Change(Basel : MDPI, 2020) Pradhan, Prajal; Kropp, Jürgen P.The world is facing a triple burden of undernourishment, obesity, and environmental impacts from agriculture while nourishing its population. This burden makes sustainable nourishment of the growing population a global challenge. Addressing this challenge requires an understanding of the interplay between diets, health, and associated environmental impacts (e.g., climate change). For this, we identify 11 typical diets that represent dietary habits worldwide for the last five decades. Plant-source foods provide most of all three macronutrients (carbohydrates, protein, and fat) in developing countries. In contrast, animal-source foods provide a majority of protein and fat in developed ones. The identified diets deviate from the recommended healthy diet with either too much (e.g., red meat) or too little (e.g., fruits and vegetables) food and nutrition supply. The total calorie supplies are lower than required for two diets. Sugar consumption is higher than recommended for five diets. Three and five diets consist of larger-than-recommended carbohydrate and fat shares, respectively. Four diets with a large share of animal-source foods exceed the recommended value of red meat. Only two diets consist of at least 400 gm/cap/day of fruits and vegetables while accounting for food waste. Prevalence of undernourishment and underweight dominates in the diets with lower calories. In comparison, a higher prevalence of obesity is observed for diets with higher calories with high shares of sugar, fat, and animal-source foods. However, embodied emissions in the diets do not show a clear relation with calorie supplies and compositions. Two high-calorie diets embody more than 1.5 t CO 2 eq/cap/yr, and two low-calorie diets embody around 1 t CO 2 eq/cap/yr. Our analysis highlights that sustainable and healthy diets can serve the purposes of both nourishing the population and, at the same time, reducing the environmental impacts of agriculture.
- ItemFrom Transfer to Knowledge Co-Production: A Transdisciplinary Research Approach to Reduce Black Carbon Emissions in Metro Manila, Philippines(Basel : MDPI, 2020) Tõnisson, Liina; Kunz, Yvonne; Kecorius, Simonas; Madueño, Leizel; Tamayo, Everlyn Gayle; Casanova, Dang Marviluz; Zhao, Qi; Schikowski, Tamara; Hornidge, Anna-Katharina; Wiedensohler, Alfred; Macke, AndreasAir pollution, which kills an estimated 7 million people every year, is one of the greatest environmental health risks of our times. Finding solutions to this threat poses challenges to practitioners and policymakers alike. Increasing awareness on the benefits of transdisciplinary research in solution-oriented sustainable development projects has led to the establishment of the research project “A Transdisciplinary Approach to Mitigate Emissions of Black Carbon” (TAME-BC). This paper introduces the TAME-BC research setup that took place with Metro Manila, Philippines, case study. The approach integrates BC measurements with technological, socio-political, and health aspects to improve the scientific state of the art, policymaking, transport sector planning, and clinical studies related to air pollution health effects. The first pillar in the setup presents an (1) air quality assessment through aerosol measurements and instrumentation, complemented by a (2) description and assessment of the current policies, technologies, and practices of the transport sector that is responsible for pollution levels in the Philippines, as well as a (3) BC exposure and associated health impacts assessment. The fourth pillar is intercrossing, fostering (4) knowledge co-creation through stakeholder involvement across scales. We argue that this transdisciplinary approach is useful for research endeavors aiming for emission mitigation in rapidly urbanizing regions beyond Metro Manila.
- ItemUnderstanding Business Environments and Success Factors for Emerging Bioeconomy Enterprises through a Comprehensive Analytical Framework(Basel : MDPI, 2020) Adamseged, Muluken Elias; Grundmann, PhilippThe development toward the bioeconomy requires, among others, generating and institutionalizing knowledge that contributes to technical and nontechnical inventions and innovations. Efforts to support innovation are often linked with the development of business models that facilitate the development in bioeconomy. However, the interdependences between the business models and their business environments are not sufficiently well understood in a way where misalignments that can obstruct the development can be dealt with adequately. Given this lacuna, this research aims to contribute to the development of a comprehensive analytical framework for better understanding the conditions of business environment as well as empirically apply the framework in an empirical study on cases of bioeconomy enterprises in Europe. In this paper, a comprehensive business environment framework is developed and applied for analyzing over 80 cases, thereby allowing for critical action arenas and crucial success factors to be identified. The findings are derived from a systematic application of the framework to relevant action arenas for business development: institutional development, technology and knowledge, consumers’ agency, market structure, funding, resource and infrastructure, and training and education. The results show that businesses in the bioeconomy, unlike other businesses, have to deal with more and very specific constraining legislative issues, infant and non-adapted technology and knowledge, as well as unclear values and perceptions of consumers. Due to this, businesses have to develop new forms of cooperation with different stakeholders. Successful businesses are characterized by the fact that they develop specific strategies, steering structures, and processes with a particular focus on learning and innovation to overcome misalignments between the business environment and their business models. Focusing efforts on learning and innovation in institutional development, technology and knowledge, consumers’ agency, and funding are especially promising as these turned out to be particularly critical and in particular need of institutional alignment for reducing different kinds of transaction costs in the development of bioeconomy.
- ItemConsistency in Vulnerability Assessments of Wheat to Climate Change—A District-Level Analysis in India(Basel : MDPI, 2020) Dhamija, Vanshika; Shukla, Roopam; Gornott, Christoph; Joshi, PKIn India, a reduction in wheat crop yield would lead to a widespread impact on food security. In particular, the most vulnerable people are severely exposed to food insecurity. This study estimates the climate change vulnerability of wheat crops with respect to heterogeneities in time, space, and weighting methods. The study uses the Intergovernmental Panel on Climate Change (IPCC) framework of vulnerability while using composite indices of 27 indicators to explain exposure, sensitivity, and adaptive capacity. We used climate projections under current (1975–2005) conditions and two future (2021–2050) Representation Concentration Pathways (RCPs), 4.5 and 8.5, to estimate exposure to climatic risks. Consistency across three weighting methods (Analytical Hierarchy Process (AHP), Principal Component Analysis (PCA), and Equal Weights (EWs)) was evaluated. Results of the vulnerability profile suggest high vulnerability of the wheat crop in northern and central India. In particular, the districts Unnao, Sirsa, Hardoi, and Bathinda show high vulnerability and high consistency across current and future climate scenarios. In total, 84% of the districts show more than 75% consistency in the current climate, and 83% and 68% of the districts show more than 75% consistency for RCP 4.5 and RCP 8.5 climate scenario for the three weighting methods, respectively. By using different weighting methods, it was possible to quantify “method uncertainty” in vulnerability assessment and enhance robustness in identifying most vulnerable regions. Finally, we emphasize the importance of communicating uncertainties, both in data and methods in vulnerability research, to effectively guide adaptation planning. The results of this study would serve as the basis for designing climate impacts adjusted adaptation measures for policy interventions.
- ItemNo polarization–Expected Values of Climate Change Impacts among European Forest Professionals and Scientists(Basel : MDPI, 2020) Persson, Johannes; Blennow, Kristina; Gonçalves, Luísa; Borys, Alexander; Dutcă, Ioan; Hynynen, Jari; Janeczko, Emilia; Lyubenova, Mariyana; Martel, Simon; Merganic, Jan; Merganičová, Katarína; Peltoniemi, Mikko; Petr, Michal; Reboredo, Fernando H.; Vacchiano, Giorgio; Reyer, Christopher P.O.The role of values in climate-related decision-making is a prominent theme of climate communication research. The present study examines whether forest professionals are more driven by values than scientists are, and if this results in value polarization. A questionnaire was designed to elicit and assess the values assigned to expected effects of climate change by forest professionals and scientists working on forests and climate change in Europe. The countries involved covered a north-to-south and west-to-east gradient across Europe, representing a wide range of bio-climatic conditions and a mix of economic–social–political structures. We show that European forest professionals and scientists do not exhibit polarized expectations about the values of specific impacts of climate change on forests in their countries. In fact, few differences between forest professionals and scientists were found. However, there are interesting differences in the expected values of forest professionals with regard to climate change impacts across European countries. In Northern European countries, the aggregated values of the expected effects are more neutral than they are in Southern Europe, where they are more negative. Expectations about impacts on timber production, economic returns, and regulatory ecosystem services are mostly negative, while expectations about biodiversity and energy production are mostly positive.