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- ItemAmmonia and greenhouse gas emissions from slurry storage : A review(Amsterdam [u.a.] : Elsevier, 2020) Kupper, Thomas; Häni, Christoph; Neftel, Albrecht; Kincaid, Chris; Bühler, Marcel; Amon, Barbara; VanderZaag, AndrewStorage of slurry is an important emission source for ammonia (NH3), nitrous oxide (N2O), methane (CH4), carbon dioxide (CO2) and hydrogen sulfide (H2S) from livestock production. Therefore, this study collected published emission data from stored cattle and pig slurry to determine baseline emission values and emission changes due to slurry treatment and coverage of stores. Emission data were collected from 120 papers yielding 711 records of measurements conducted at farm-, pilot- and laboratory-scale. The emission data reported in a multitude of units were standardized and compiled in a database. Descriptive statistics of the data from untreated slurry stored uncovered revealed a large variability in emissions for all gases. To determine baseline emissions, average values based on a weighting of the emission data according to the season and the duration of the emission measurements were constructed using the data from farm-scale and pilot-scale studies. Baseline emissions for cattle and pig slurry stored uncovered were calculated. When possible, it was further distinguished between storage in tanks without slurry treatment and storage in lagoons which implies solid-liquid separation and biological treatment. The baseline emissions on an area or volume basis are: for NH3: 0.12 g m−2 h-1 and 0.15 g m−2 h-1 for cattle and pig slurry stored in lagoons, and 0.08 g m−2 h-1 and 0.24 g m−2 h-1 for cattle and pig slurry stored in tanks; for N2O: 0.0003 g m−2 h-1 for cattle slurry stored in lagoons, and 0.002 g m−2 h-1 for both slurry types stored in tanks; for CH4: 0.95 g m-3 h-1 and 3.5 g m-3 h-1 for cattle and pig slurry stored in lagoons, and 0.58 g m-3 h-1 and 0.68 g m-3 h-1 for cattle and pig slurry stored in tanks; for CO2: 6.6 g m−2 h-1 and 0.3 g m−2 h-1 for cattle and pig slurry stored in lagoons, and 8.0 g m−2 h-1 for both slurry types stored in tanks; for H2S: 0.04 g m−2 h-1 and 0.01 g m−2 h-1 for cattle and pig slurry stored in lagoons. Related to total ammoniacal nitrogen (TAN), baseline emissions for tanks are 16% and 15% of TAN for cattle and pig slurry, respectively. Emissions of N2O and CH4 relative to nitrogen (N) and volatile solids (VS) are 0.13% of N and 0.10% of N and 2.9% of VS and 4.7% of VS for cattle and pig slurry, respectively. Total greenhouse gas emissions from slurry stores are dominated by CH4. The records on slurry treatment using acidification show a reduction of NH3 and CH4 emissions during storage while an increase occurs for N2O and a minor change for CO2 as compared to untreated slurry. Solid-liquid separation causes higher losses for NH3 and a reduction in CH4, N2O and CO2 emissions. Anaerobically digested slurry shows higher emissions during storage for NH3 while losses tend to be lower for CH4 and little changes occur for N2O and CO2 compared to untreated slurry. All cover types are found to be efficient for emission mitigation of NH3 from stores. The N2O emissions increase in many cases due to coverage. Lower CH4 emissions occur for impermeable covers as compared to uncovered slurry storage while for permeable covers the effect is unclear or emissions tend to increase. Limited and inconsistent data regarding emission changes with covering stores are available for CO2 and H2S. The compiled data provide a basis for improving emission inventories and highlight the need for further research to reduce uncertainty and fill data gaps regarding emissions from slurry storage.
- ItemThermal annealing to influence the vapor sensing behavior of co-continuous poly(lactic acid)/polystyrene/multiwalled carbon nanotube composites(Amsterdam [u.a.] : Elsevier Science, 2020) Li, Yilong; Pionteck, Jürgen; Pötschke, Petra; Voit, BrigitteWith the main purpose of being used as vapor leakage detector, the volatile organic compound (VOC) vapor sensing properties of conductive polymer blend composites were studied. Poly(lactic acid)/polystyrene/multi-walled carbon nanotube (PLA/PS/MWCNT) based conductive polymer composites (CPCs) in which the polymer components exhibit different interactions with the vapors, were prepared by melt mixing. CPCs with a blend composition of 50/50 wt% resulted in the finest co-continuous structure and selective MWCNT localization in PLA. Therefore, these composites were selected for sensor tests. Thermal annealing was applied aiming to maintain the blend structure but improving the sensing reversibility of CPC sensors towards high vapor concentrations. Different sensing protocols were applied using acetone (good solvent for PS and PLA) and cyclohexane (good solvent for PS but poor solvent for PLA) vapors. Increasing acetone vapor concentration resulted in increased relative resistance change (Rrel) of CPCs. Saturated cyclohexane vapor resulted in lower response than nearly saturated acetone vapor. The thermal annealing at 150 °C did not change the blend morphology but increased the PLA crystallinity, making the CPC sensors more resistant to vapor stimulation, resulting in lower Rrel but better reversibility after vapor exposure.
- ItemTransparent model concrete with tunable rheology for investigating flow and particle-migration during transport in pipes(Amsterdam [u.a.] : Elsevier Science, 2020) Auernhammer, Günter K.; Fataei, Shirin; Haustein, Martin A.; Patel, Himanshu P.; Schwarze, Rüdiger; Secrieru, Egor; Mechtcherine, ViktorThe article describes the adaption and properties of a model concrete for detailed flow studies. To adapt the yield stress and plastic viscosity of the model concrete to the corresponding rheological properties of real concrete, the model concrete is made of a mixture of glass beads and a non-Newtonian fluid. The refractive index of the non-Newtonian fluid is adjusted to the refractive index of the glass beads by the addition of a further constituent. The rheological properties of the model concrete are characterised by measurements in concrete rheometers. Finally, the first exemplary results from experiments with the model concrete are presented, which give incipient impressions of the complex internal dynamics in flowing concrete.
- ItemPhase and grain size engineering in Ge-Sb-Te-O by alloying with La-Sr-Mn-O towards improved material properties(Oxford : Elsevier Science, 2020) Kraft, Nikolas; Wang, Guoxiang; Bryja, Hagen; Prager, Andrea; Griebel, Jan; Lotnyk, AndriyGe-Sb-Te alloys are promising materials for non-volatile memory applications. Alloying of the materials with various elements is considered as prospective approach to enhance material properties. This work reports on the preparation and characterization of pure Ge-Sb-Te-O (GSTO) and alloyed with La-Sr-Mn-O (LSMO) thin films. Thermal heating of amorphous thin films to different temperatures show distinct crystallization behavior. A general trend is the decrease in the size of GSTO crystallites and the suppression in the formation of stable trigonal GSTO phase with increasing content of LSMO. Microstructural studies by transmission electron microscopy show the formation of metastable GSTO nanocrystallites dispersed in the amorphous matrix. Analysis of local chemical bonding by X-ray spectroscopy reveal the presence of different oxides in the GSTO-LSMO composites. Moreover, the composites with a high LSMO content exhibit higher crystallization temperature and significant larger sheet resistance in amorphous and crystalline phase, while a memory device made of GSTO-LSMO alloy reveals bipolar switching and synaptic behavior. In addition, the amount of LSMO in GSTO-LSMO thin films influences their optical properties and band gap. Overall, the results of this work reveal the highly promising potential of GSTO-LSMO nanocomposites for data storage and reconfigurable photonic applications as well as neuro-inspired computing.
- ItemCorrelated power time series of individual wind turbines: A data driven model approach(Woodbury, NY : American Inst. of Physics, 2020) Braun, Tobias; Waechter, Matthias; Peinke, Joachim; Guhr, ThomasWind farms can be regarded as complex systems that are, on the one hand, coupled to the nonlinear, stochastic characteristics of weather and, on the other hand, strongly influenced by supervisory control mechanisms. One crucial problem in this context today is the predictability of wind energy as an intermittent renewable resource with additional non-stationary nature. In this context, we analyze the power time series measured in an offshore wind farm for a total period of one year with a time resolution of 10 min. Applying detrended fluctuation analysis, we characterize the autocorrelation of power time series and find a Hurst exponent in the persistent regime with crossover behavior. To enrich the modeling perspective of complex large wind energy systems, we develop a stochastic reduced-form model of power time series. The observed transitions between two dominating power generation phases are reflected by a bistable deterministic component, while correlated stochastic fluctuations account for the identified persistence. The model succeeds to qualitatively reproduce several empirical characteristics such as the autocorrelation function and the bimodal probability density function. © 2020 Author(s).
- ItemPhysico-chemical and bacteriological quality of groundwater in a rural area of Western Niger: A case study of Bonkoukou(London : IWA Publishing, 2020) Adamou, Hassane; Ibrahim, Boubacar; Salack, Seyni; Adamou, Rabani; Sanfo, Safietou; Liersch, StefanThe precariousness of the rural population in Africa is often symbolized by the lack of potable and safe drinking water. This study investigates the physico-chemical and bacteriological characteristics of 32 water samples with respect to WHO standards. The water samples were collected from wells, boreholes and small drinking water supply systems (DWS) in and around the township of Bonkoukou (Niger). The Water Quality Index (WQI) tool was used to assess the overall water quality with different physico-chemical parameters. Where the pH of the samples was acceptable, the samples showed higher levels of mineralization and deoxygenation. Overall, the samples were slightly hard, chlorinated and sulfated but much alkaline and contained nitrate and nitrite ions 2-16 times higher than the WHO standards. The use of WQI shows that samples in the DWS are safe for drinking. Samples coming from wells are the most polluted (58.50%) compared to those taken from boreholes (53.00%), while the percentage of samples from boreholes, unfit for drinking, is higher (41.00%) than that of the samples taken from wells (25.00%). Moreover, water in this area was characterized by the presence of total germs indicating bacteriological pollution. Hence, for the supply of safe drinking water to the larger number of people in such a rural area, the capacity of actual DWS must be improved and widespread. © 2020 The Authors.
- ItemThe impact of atmospheric boundary layer, opening configuration and presence of animals on the ventilation of a cattle barn(Amsterdam [u.a.] : Elsevier Science, 2020) Nosek, Štěpán; Kluková, Zuzana; Jakubcová, Michaela; Yi, Qianying; Janke, David; Demeyer, Peter; Jaňour, ZbyněkNaturally ventilated livestock buildings (NVLB) represent one of the most significant sources of ammonia emissions. However, even the dispersion of passive gas in an NVLB is still not well understood. In this paper, we present a detailed investigation of passive pollutant dispersion in a model of a cattle barn using the wind tunnel experiment method. We simulated the pollution of the barn by a ground-level planar source. We used the time-resolved particle image velocimetry (TR-PIV) and the fast flame ionisation detector (FFID) to study the flow and dispersion processes at high spatial and temporal resolution. We employed the Proper Orthogonal Decomposition (POD) and Oscillating Patterns Decomposition (OPD) methods to detect the coherent structures of the flow. The results show that the type of atmospheric boundary layer (ABL) and sidewall opening height have a significant impact on the pollutant dispersion in the barn, while the presence of animals and doors openings are insignificant under conditions of winds perpendicular to the sidewall openings. We found that the dynamic coherent structures, developed by the Kelvin-Helmholtz instability, contribute to the pollutant transport in the barn. We demonstrate that in any of the studied cases the pollutant was not well mixed within the barn and that a significant underestimation (up to by a factor 3) of the barn ventilation might be obtained using, e.g. tracer gas method. © 2020 The Authors
- ItemGreenhouse gas emissions from broiler manure treatment options are lowest in well-managed biogas production(Amsterdam [u.a.] : Elsevier Science, 2020) Kreidenweis, Ulrich; Breier, Jannes; Herrmann, Christiane; Libra, Judy; Prochnow, AnnetteThe production of broiler meat has increased significantly in the last decades in Germany and worldwide, and is projected to increase further in the future. As the number of animals raised increases, so too does the amount of manure produced. The identification of manure treatment options that cause low greenhouse gas emissions becomes ever more important. This study compares four treatment options for broiler manure followed by field spreading: storage before distribution, composting, anaerobic digestion in a biogas plant and production of biochar. For these options potential direct and indirect greenhouse gas emissions were assessed for the situation in Germany. Previous analyses have shown that greenhouse gas balances of manure management are often strongly influenced by a small number of processes. Therefore, in this study major processes were represented with several variants and the sensitivity of model results to different management decisions and uncertain parameters was assessed. In doing so, correlations between processes were considered, in which higher emissions earlier on in the process chain reduce emissions later. The results show that biogas production from broiler manure leads to the lowest greenhouse gas emissions in most of the analysed cases, mainly due to the emission savings related to the substitution of mineral fertilizers and the production of electricity. Pyrolysis of the manure and subsequent field spreading as a soil amendment can lead to similarly low emissions due to the long residence time of the biochar, and may even be the better option than poorly managed biogas production. Composting is the treatment option resulting in highest emissions of greenhouse gases, due to high ammonia volatilization, and is likely worse than untreated storage in this respect. These results are relatively insensitive to the length of transport required for field spreading, but high uncertainties are associated with the use of emission factors.
- ItemPreventing airborne transmission of SARS-CoV-2 in hospitals and nursing homes(Basel : MDPI AG, 2020) Ahlawat, Ajit; Mishra, Sumit Kumar; Birks, John W.; Costabile, Francesca; Wiedensohler, Alfred[No abstract available]
- ItemRevisiting economic burdens of malaria in the face of climate change: a conceptual analysis for Ethiopia(Bradford : Emerald, 2020) Yalew, Amsalu WoldiePurpose: Climate change affects the geographic and seasonal range of malaria incidence, especially, in poor tropical countries. This paper aims to attempt to conceptualize the potential economic repercussions of such effects with its focus on Ethiopia. Design/methodology/approach: The paper is conceptual and descriptive in its design. It first reviews existing literature and evidence on the economic burdens of malaria, and the impacts of climate change on malaria disease. It then draws the economic implications of the expected malaria risk under the future climate. This is accompanied by a discussion on a set of methods that can be used to quantify the economic effects of malaria with or without climate change. Findings: A review of available evidence shows that climate change is likely to increase the geographic and seasonal range of malaria incidence in Ethiopia. The economic consequences of even a marginal increase in malaria risk will be substantial as one considers the projected impacts of climate change through other channels, the current population exposed to malaria risk and the country’s health system, economic structure and level of investment. The potential effects have the potency to require more household and public spending for health, to perpetuate poverty and inequality and to strain agricultural and regional development. Originality/value: This paper sheds light on the economic implications of climate change impacts on malaria, particularly, in Agrarian countries laying in the tropics. It illustrates how such impacts will interact with other impact channels of climate change, and thus evolve to influence the macro-economy. The paper also proposes a set of methods that can be used to quantify the potential economic effects of malaria. The paper seeks to stimulate future research on this important topic which rather has been neglected. © 2020, Amsalu Woldie Yalew.