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- ItemLong-time resistivity monitoring of a freshwater/saltwater transition zone using the vertical electrode system SAMOS(Les Ulis : EDP Sciences, 2018) Grinat, Michael; Epping, Dieter; Meyer, Robert; Szymkiewicz, Adam; Sadurski, A.; Jaworska-Szulc, B.In September 2009 two newly developed vertical electrode systems were installed in boreholes in the water catchment areas Waterdelle and Ostland at the North Sea island Borkum to monitor possible changes of the transition zone between the freshwater lens and the underlying saltwater. The vertical electrode systems, which were both installed between 44 m and 65 m below ground level, are used for geoelectrical multi-electrode measurements carried out automatically several times per day; the measurements are still ongoing. The whole system consisting of a vertical electrode system in a borehole and the measuring unit at ground level is called SAMOS (Saltwater Monitoring System). At both locations the data show a clear resistivity decrease that indicates the transition zone between freshwater and saltwater. The depth of the transition zone as well as the kind of resistivity decrease is very stable since 2010. Temporal changes are visible if single depths are considered. In 2015 Miriam Ibenthal used a vertical 2D density-dependent groundwater flow model to explain the long-term resistivity measurements and showed that the temporal changes at CLIWAT 2 (Ostland) could be explained by variations of the groundwater level, changing groundwater recharge rates and changing pumping rates of the nearby located drinking water supply wells.
- ItemSaltwater intrusion under climate change in North-Western Germany - mapping, modelling and management approaches in the projects TOPSOIL and go-CAM(Les Ulis : EDP Sciences, 2018) Wiederhold, Helga; Scheer, Wolfgang; Kirsch, Reinhard; Azizur Rahman, M.; Ronczka, Mathias; Szymkiewicz, Adam; Sadurski, A.; Jaworska-Szulc, B.Climate change will result in rising sea level and, at least for the North Sea region, in rising groundwater table. This leads to a new balance at the fresh–saline groundwater boundary and a new distribution of saltwater intrusions with strong regional differentiations. These effects are investigated in several research projects funded by the European Union and the German Federal Ministry of Education and Research (BMBF). Objectives and some results from the projects TOPSOIL and go-CAM are presented in this poster.
- ItemModeling saltwater intrusion scenarios for a coastal aquifer at the German North Sea(Les Ulis : EDP Sciences, 2018) Schneider, A.; Zhao, H.; Wolf, J.; Logashenko, D.; Reiter, S.; Howahr, M.; Eley, M.; Gelleszun, M.; Wiederhold, H.; Szymkiewicz, Adam; Sadurski, A.; Jaworska-Szulc, B.A 3d regional density-driven flow model of a heterogeneous aquifer system at the German North Sea Coast is set up within the joint project NAWAK (“Development of sustainable adaption strategies for the water supply and distribution infrastructure on condition of climatic and demographic change”). The development of the freshwater-saltwater interface is simulated for three climate and demographic scenarios. Groundwater flow simulations are performed with the finite volume code d3f++ (distributed density driven flow) that has been developed with a view to the modelling of large, complex, strongly density-influenced aquifer systems over long time periods.
- ItemCharacterization of a regional coastal zone aquifer using an interdisciplinary approach – an example from Weser-Elbe region, Lower Saxony, Germany(Les Ulis : EDP Sciences, 2018) Rahman, Mohammad Azizur; González, Eva; Wiederhold, Helga; Deus, Nico; Elbracht, Jörg; Siemon, Bernhard; Szymkiewicz, Adam; Sadurski, A.; Jaworska-Szulc, B.In this study, interdisciplinary approaches are considered to characterize the coastal zone aquifer of the Elbe-Weser region in the North of Lower Saxony, Germany. Geological, hydrogeological, geochemical and geophysical information have been considered to analyze the current status of the aquifers. All the information collectively states that the salinity distribution in the subsurface is heterogeneous both horizontally and vertically. Early age flooding also contributed to this heterogeneity. No general classification of groundwater quality (according to some piper diagrams) could be identified. Helicopter-borne electro-magnetic data clearly show the presence of freshwater reserves below the sea near the west coast. Groundwater recharge largely happens in the moraine ridges (west side of the area) where both the surface elevation and the groundwater level are high. Consequently, submarine groundwater discharge occurs from the same place. All these information will facilitate to develop the planned density driven groundwater flow and transport model for the study area.
- ItemHow activated carbon improves the performance of non-thermal plasma removing methyl ethyl ketone from a gas stream([Amsterdam] : Elsevier B.V., 2021) Schmidt, Michael; Kettlitz, Manfred; Kolb, Juergen F.The combination of non-thermal plasma (NTP), operated at room temperature and at atmospheric pressure in air and in combination with activated carbon filters offers a more efficient removal of VOCs from gas streams than each individual method alone. Efficiencies, synergies and mechanisms of this combination were investigated by means of comprehensive quantitative Fourier transform infrared spectroscopy analysis. Therefore, dry and wet synthetic air containing about 90 ppm of methyl ethyl ketone (MEK) were treated with non-thermal plasma (NTP) and an intentionally undersized activated carbon (AC) filter, separately and in combination. As a result, removal of about 50 % was achieved for NTP or AC alone but a removal close to 95 % was found for the combination. Ozone, generated by the NTP, was reduced by 55 % with the AC-filter. For the operation of the NTP with humid air, a decomposition of the pollutant on AC was observed even after the plasma was switched off.
- ItemChapter scientists in the IPCC AR5-experience and lessons learned(Amsterdam [u.a.] : Elsevier, 2015) Schulte-Uebbing, Lena; Hansen, Gerrit; Hernández, Ariel Macaspac; Winter, MartenIPCC Assessment Reports provide timely and accurate information on anthropogenic climate change to policy makers and the public. The reports are written by hundreds of scientists in a voluntary, collaborative effort. Growing amounts of literature and complex procedural and administrative requirements, however, make this effort a substantial management challenge next to a scientific one. During the 5th Assessment Cycle, IPCC Working Groups II and III initiated a program that recruited volunteer scientific assistants who provided technical and logistical support to author teams. In this paper we describe and analyze strengths and weaknesses of this ‘Chapter Scientist program’, based on an extensive survey among Chapter Scientists (CS) and interviews with other stakeholders. We conclude that the program was a useful innovation that that enabled authors to focus more on their core scientific tasks and that contributed to improving the quality of the assessment. We highly recommend similar programs for future scientific assessments. Key criteria for success that we identified are (a) involvement of early-career scientists as CS, (b) close integration of CS in the assessment process, (c) recruitment of CS through an open call to achieve transparency, and (d) provision of funds for such a program to support travel costs and compensation of CS.
- ItemCarbon materials for stable Li metal anodes: Challenges, solutions, and outlook(Hoboken, NJ : Wiley, 2021) Lu, Q.; Jie, Y.; Meng, X.; Omar, A.; Mikhailova, D.; Cao, R.; Jiao, S.; Lu, Y.; Xu, Y.Lithium (Li) metal is regarded as the ultimate anode for next-generation Li-ion batteries due to its highest specific capacity and lowest electrochemical potential. However, the Li metal anode has limitations, including virtually infinite volume change, nonuniform Li deposition, and an unstable electrode–electrolyte interface, which lead to rapid capacity degradation and poor cycling stability, significantly hindering its practical application. To address these issues, intensive efforts have been devoted toward accommodating and guiding Li deposition as well as stabilizing the interface using various carbon materials, which have demonstrated excellent effectiveness, benefiting from their vast variety and excellent tunability of the structure–property relationship. This review is intended as a guide through the fundamental challenges of Li metal anodes to the corresponding solutions utilizing carbon materials. The specific functionalities and mechanisms of carbon materials for stabilizing Li metal anodes in these solutions are discussed in detail. Apart from the stabilization of the Li metal anode in liquid electrolytes, attention has also been paid to the review of anode-free Li metal batteries and solid-state batteries enabled by strategies based on carbon materials. Furthermore, we have reviewed the unresolved challenges and presented our outlook on the implementation of carbon materials for stabilizing Li metal anodes in practical applications.
- ItemIntegrating climate change adaptation in coastal governance of the Barcelona metropolitan area(Dordrecht [u.a.] : Springer Science + Business Media B.V, 2021) Sauer, Inga J.; Roca, Elisabet; Villares, MíriamCoastal cities are exposed to high risks due to climate change, as they are potentially affected by both rising sea levels and increasingly intense and frequent coastal storms. Socio-economic drivers also increase exposure to natural hazards, accelerate environmental degradation, and require adaptive governance structures to moderate negative impacts. Here, we use a social network analysis (SNA) combined with further qualitative information to identify barriers and enablers of adaptive governance in the Barcelona metropolitan area. By analyzing how climate change adaptation is mainstreamed between different administrative scales as well as different societal actors, we can determine the governance structures and external conditions that hamper or foster strategical adaptation plans from being used as operational adaptation tools. We identify a diverse set of stakeholders acting at different administrative levels (local to national), in public administration, science, civil society, and the tourism economy. The metropolitan administration acts as an important bridging organization by promoting climate change adaptation to different interest groups and by passing knowledge between actors. Nonetheless, national adaptation planning fails to take into account local experiences in coastal protection, which leads to an ineffective science policy interaction and limits adaptive management and learning opportunities. Overcoming this is difficult, however, as the effectiveness of local adaptation strategies in the Barcelona metropolitan area is very limited due to a strong centralization of power at the national level and a lack of polycentricity. Due to the high touristic pressure, the legal framework is currently oriented to primarily meet the demands of recreational use and tourism, prioritizing these aspects in daily management practice. Therefore, touristic and economic activities need to be aligned to adaptation efforts, to convert them from barriers into drivers for adaptation action. Our work strongly suggests that more effectively embedding adaptation planning and action into existing legal structures of coastal management would allow strategic adaptation plans to be an effective operational tool for local coastal governance.
- ItemDeclining glaciers endanger sustainable development of the oases along the Aksu-Tarim River (Central Asia)(London : Taylor & Francis, 2021) Bolch, Tobias; Duethmann, Doris; Wortmann, Michel; Liu, Shiyin; Disse, MarkusTarim River basin is the largest endorheic river basin in China. Due to the extremely arid climate the water supply solely depends on water originating from the glacierised mountains with about 75% stemming from the transboundary Aksu River. The water demand is linked to anthropogenic (specifically agriculture) and natural ecosystems, both competing for water. Ongoing climate change significantly impacts the cryosphere. The mass balance of the glaciers in Aksu River basin was clearly negative since 1975. The discharge of the Aksu headwaters has been increasing over the last decades mainly due to the glacier contribution. The average glacier melt contribution to total runoff is 30–37% with an estimated glacier imbalance contribution of 8–16%. Modelling using future climate scenarios indicate a glacier area loss of at least 50% until 2100. River discharge will first increase concomitant with glacier shrinkage until about 2050, but likely decline thereafter. The irrigated area doubled in the Aksu region between the early 1990s and 2020, causing at least a doubling of water demand. The current water surplus is comparable to the glacial runoff. Hence, even if the water demand will not grow further in the future a significant water shortage can be expected with declining glacial runoff. However, with the further expansion of irrigated agriculture and related industries, the water demand is expected to even further increase. Both improved discharge projections and planning of efficient and sustainable water use are necessary for further socioeconomic development in the region along with the preservation of natural ecosystems.
- ItemLifetime vs. rate capability: Understanding the role of FEC and VC in high-energy Li-ion batteries with nano-silicon anodes(Amsterdam : Elsevier, 2016) Jaumann, Tony; Balach, Juan; Langklotz, Ulrike; Sauchuk, Viktar; Fritsch, Marco; Michaelis, Alexander; Teltevskij, Valerij; Mikhailova, Daria; Oswald, Steffen; Klose, Markus; Stephani, Guenter; Hauser, Ralf; Eckert, Jürgen; Giebeler, LarsFluoroethylene carbonate (FEC) and vinylene carbonate (VC) are the most frequently used electrolyte components to enhance the lifetime of anode materials in Li-ion batteries, but for silicon it is still ambiguous when FEC or VC is more beneficial. Herein, a nanostructured silicon/carbon anode derived from low-cost HSiCl3 is tailored by the rational choice of the electrolyte component, to obtain an anode material outperforming current complex silicon structures. We demonstrate highly reversible areal capacities of up to 5 mA h/cm2 at 4.4 mg/cm2 mass loading, a specific capacity of 1280 mA h/gElectrode, a capacity retention of 81% after 500 deep-discharge cycles versus lithium metal and successful full-cell tests with high-voltage cathodes meeting the requirements for real application. Electrochemical impedance spectroscopy and post-mortem investigation provide new insights in tailoring the interfacial properties of silicon-based anodes for high performance anode materials based on an alloying mechanism with large volume changes. The role of fluorine in the FEC-derived interfacial layer is discussed in comparison with the VC-derived layer and possible degradation mechanisms are proposed. We believe that this study gives a valuable understanding and provides new strategies on the facile use of additives for highly reversible silicon anodes in Li-ion batteries.