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Now showing 1 - 10 of 15
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    Development of an electrochemical sensor for in-situ monitoring of reactive species produced by cold physical plasma
    (Amsterdam [u.a.] : Elsevier Science, 2021) Nasri, Zahra; Bruno, Giuliana; Bekeschus, Sander; Weltmann, Klaus-Dieter; von Woedtke, Thomas; Wende, Kristian
    The extent of clinical applications of oxidative stress-based therapies such as photodynamic therapy (PDT) or respiratory chain disruptors are increasing rapidly, with cold physical plasma (CPP) emerging as a further option. According to the current knowledge, the biological effects of CPP base on reactive oxygen and nitrogen species (RONS) relevant in cell signaling. To monitor the safety and the biological impact of the CPP, determining the local generation of RONS in the same environment in which they are going to be applied is desirable. Here, for the first time, the development of an electrochemical sensor for the simple, quick, and parallel determination of plasma-generated reactive species is described. The proposed sensor consists of a toluidine blue redox system that is covalently attached to a gold electrode surface. By recording chronoamperometry at different potentials, it is possible to follow the in-situ production of the main long-lived reactive oxygen and nitrogen species like hydrogen peroxide, nitrite, hypochlorite, and chloramine with time. The applicability of this electrochemical sensor for the in-situ assessment of reactive species in redox-based therapies is demonstrated by the precise analysis of hydrogen peroxide dynamics in the presence of blood cancer cells.
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    An AI-based open recommender system for personalized labor market driven education
    (Amsterdam [u.a.] : Elsevier Science, 2022) Tavakoli, Mohammadreza; Faraji, Abdolali; Vrolijk, Jarno; Molavi, Mohammadreza; Mol, Stefan T.; Kismihók, Gábor
    Attaining those skills that match labor market demand is getting increasingly complicated, not in the last place in engineering education, as prerequisite knowledge, skills, and abilities are evolving dynamically through an uncontrollable and seemingly unpredictable process. Anticipating and addressing such dynamism is a fundamental challenge to twenty-first century education. The burgeoning availability of data, not only on the demand side but also on the supply side (in the form of open educational resources) coupled with smart technologies, may provide a fertile ground for addressing this challenge. In this paper, we propose a novel, Artificial Intelligence (AI) driven approach to the development of an open, personalized, and labor market oriented learning recommender system, called eDoer. We discuss the complete system development cycle starting with a systematic user requirements gathering, and followed by system design, implementation, and validation. Our recommender prototype (1) derives the skill requirements for particular occupations through an analysis of online job vacancy announcements
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    Electrohydrodynamic drying versus conventional drying methods: A comparison of key performance indicators
    (Amsterdam [u.a.] : Elsevier Science, 2023) Iranshahi, Kamran; Rubinetti, Donato; Onwude, Daniel I.; Psarianos, Marios; Schlüter, Oliver K.; Defraeye, Thijs
    Preserving fruits and vegetables by drying is a traditional yet effective way of reducing food waste. Existing drying methods are either energy-intensive or lead to a significant reduction in product quality. Electrohydrodynamic (EHD) drying is an energy-efficient low-temperature drying method that presents an opportunity to comply with the current challenges of existing drying methods. However, despite its promising characteristics, EHD drying is yet to be accepted by industry and farmers. The adoption of EHD drying is hindered due to different reasons, such as uncertainties surrounding its scalability, quality of dried product, cost of operation, and sustainability compared to conventional drying methods. To address these concerns, this study quantifies and benchmarks the Key Performance Indicators (KPIs) of EHD drying compared to the standard conventional drying methods based on lab-scale experiments. These drying methods include hot-air, freeze, microwave, and solar drying. The results show that drying food using EHD is at least 1.6, 20, and 70 times more energy-efficient than the microwave, freeze, and hot-air, respectively. Similar results could be observed for exergy efficiency. EHD drying has superior product quality compared to other drying methods. For instance, it could retain 62% higher total phenolic content with 21% less color degradation than freeze-drying. Although microwave drying resulted in significantly higher drying kinetics than other techniques, EHD performed better than solar and freeze-drying but was comparable with hot-air drying. EHD drying also shows promising results in economic performance assessment. It is the cheapest drying method after solar drying and has the highest estimated net present value (NPV) after hot-air drying. Overall, compared to the currently used drying methods for small to medium-scale drying, EHD was found to be a more exergy and energy-efficient, cost-effective, and sustainable alternative that can provide higher-quality dried products. However, its drying kinetics should be improved for industrial applications.
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    Reviewing the Market Stability Reserve in light of more ambitious EU ETS emission targets
    (Amsterdam [u.a.] : Elsevier Science, 2021) Osorio, Sebastian; Tietjen, Oliver; Pahle, Michael; Pietzcker, Robert C.; Edenhofer, Ottmar
    The stringency of the EU's Emission Trading System (ETS) is bound to be ratcheted-up to deliver on more ambitious goals as formulated in the EU's Green Deal. Tightening the cap needs to consider the interactions with the Market Stability Reserve (MSR), which will be reviewed in 2021. We analyse these issues using the model LIMES-EU. First, we examine how revising MSR parameters impacts allowance cancellations. We find that varying key design parameters leads to cancellations in the range of 2.6–7.9 Gt – compared to 5.1 Gt under current regulation. Overall, the bank thresholds, which define when there is intake to/outtake from the MSR, have the highest impact. Intake rates above 12% only have a limited effect, and cause oscillatory intake behaviour. Second, we analyse how more ambitious climate 2030 targets can be achieved by adjusting the linear reduction factor (LRF). We find that the LRF increases MSR cancellations substantially up to 10.0 Gt. This implies that increasing its value from currently 2.2% to only 2.6% could be consistent with an EU-wide target of −55% by 2030. However, MSR cancellations are subject to large uncertainty, which increases the complexity of the market and induces high price uncertainty.
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    Future changes in consumption: The income effect on greenhouse gas emissions
    (Amsterdam [u.a.] : Elsevier Science, 2021) Bjelle, Eivind Lekve; Wiebe, Kirsten S.; Többen, Johannes; Tisserant, Alexandre; Ivanova, Diana; Vita, Gibran; Wood, Richard
    The scale and patterns of household consumption are important determinants of environmental impacts. Whilst affluence has been shown to have a strong correlation with environmental impact, they do not necessarily grow at the same rate. Given the apparent contradiction between the sustainable development goals of economic growth and environmental protection, it is important to understand the effect of rising affluence and concurrent changing consumption patterns on future environmental impacts. Here we develop an econometric demand model based on the data available from a global multiregional input-output dataset. We model future household consumption following scenarios of population and GDP growth for 49 individual regions. The greenhouse gas (GHG) emissions resulting from the future household demand is then explored both with and without consideration of the change in expenditure over time on different consumption categories. Compared to a baseline scenario where final demand grows in line with the 2011 average consumption pattern up until 2030, we find that changing consumer preferences with increasing affluence has a small negative effect on global cumulative GHG emissions. The differences are more profound on both a regional and a product level. For the demand model scenario, we find the largest decrease in GHG emissions for the BRICS and other developing countries, while emissions in North America and the EU remain unchanged. Decreased spending and resulting emissions on food are cancelled out by increased spending and emissions on transportation. Despite relatively small global differences between the scenarios, the regional and sectoral wedges indicate that there is a large untapped potential in environmental policies and lifestyle changes that can complement the technological transition towards a low-emitting society.
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    Mitigating poverty: The patterns of multiple carbon tax and recycling regimes for Peru
    (Amsterdam [u.a.] : Elsevier Science, 2021) Malerba, Daniele; Gaentzsch, Anja; Ward, Hauke
    Carbon taxes are an economically effective and efficient policy measure to address climate change mitigation. However, they can have severe adverse distributional effects. Recycling parts of the fiscal revenues to vulnerable, lower income households through cash transfers (social assistance) is an option to also overcome associated political difficulties. This paper simulates the distributional impacts of such a combined policy reform in Peru. In a first step, we assess the distributional impacts of varying carbon tax rates. In a second step, we evaluate different scenarios of recycling revenues through existing or expanded transfer schemes towards vulnerable households. The results indicate that a national carbon tax, without compensation, would increase poverty but have no significant impact on inequality. When tax revenues are recycled through transfer schemes, however, poverty would actually decrease. Depending on the amount to be redistributed and the design of the cash transfer scheme, our simulations show a proportional reduction in the poverty headcount of up to around 17%. In addition, the paper underlines how crucial it is to go beyond aggregate measures of poverty to better identify losers from such reform; and assure that the “leave no one behind” principle of the Sustainable Development Goals (SDGs) is addressed.
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    S-wave seismic imaging of near-surface sediments using tailored processing strategies
    (Amsterdam [u.a.] : Elsevier Science, 2020) Burschil, Thomas; Buness, Hermann
    Reflection seismic imaging using horizontally-polarized S-waves (SH) can increase resolution and it could be cost-efficient compared to the common use of P-waves. However, since S-wave application often delivers varying data quality, appropriate processing schemes are required for particular imaging and interpretation purposes. In this paper, we present four tailored processing strategies that are applied to SH-wave data acquired in an overdeepened Quaternary basin in the Alpine foreland, the Tannwald Basin. The applied processing schemes consist of (1) processing using a short automatic gain control window that enhances structural details and highlights small-scale structures, (2) offset restriction indicating that relative small offsets are sufficient for adequate imaging, which offers reduced field operation costs, (3) coherency-enhancement that reveals large-scale structures for interpretation, and (4) adapted amplitude scaling that enables structural comparison of P-wave and S-wave seismic sections. With respect to P-wave data measured on the same profile, we demonstrate the benefits of the S-wave seismic reflection method. P-waves offer robust imaging results, but S-waves double the resolution, better depict shallow reflections, and may image reflectors in areas where the P-wave struggles. At least for the Tannwald Basin, S-wave imaging is also more cost-efficient than P-wave imaging. © 2020 The Authors
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    Non-invasive prospection techniques and direct push sensing as high-resolution validation tools in wetland geoarchaeology – Artificial water supply at a Carolingian canal in South Germany?
    (Amsterdam [u.a.] : Elsevier Science, 2020) Rabiger-Völlmer, Johannes; Schmidt, Johannes; Linzen, Sven; Schneider, Michael; Werban, Ulrike; Dietrich, Peter; Wilken, Dennis; Wunderlich, Tina; Fediuk, Annika; Berg, Stefanie; Werther, Lukas; Zielhofer, Christoph
    The prospection of (geo-)archaeological sites yield important knowledge about the concept and the utilisation of pre-historical and historical infrastructure. The satisfactory conduction of classical prospection methods like archaeological excavations or geoarchaeological vibra-coring might be challenging in the case of large sites or difficult underground conditions. This is particularly problematic in wetlands featuring a high groundwater table and high compaction rates of organic layers. In this study, we provide an alternative and non- to minimal-invasive exploration approach to discover hydro-engineering structures for artificial water supply in the surrounding of a Carolingian summit canal in South Germany. The Early Medieval Fossa Carolina was intended 792/793 CE to bridge the Central European watershed between Rhine-Main and Danube catchments. As the canal was constructed as a summit canal, an artificial water supply at the highest levels seemed very likely or even obligatory. In order to explore these obligatory hydro-engineering features, we use a wide range of on-site and off-site tools in a spatial hierarchical way. Our approach includes the large-scale SQUID magnetic survey and the sighting of historical maps. Furthermore, we integrate high-resolution direct push colour logs, and subsequent vibra-coring for small-scale stratigraphical verification and sedimentological analyses. The SQUID magnetic survey and related depth models discover two pronounced linear anomalies that might represent potential artificial water inlets in the North-Eastern and Northern Sections of the canal. I) In the North-Eastern Section, direct push colour logs, vibra-coring and 14C dating provide no evidence for a Carolingian hydro-engineering feature but reveal a natural lenticular structure of Early Holocene age. II) The linear magnetic anomaly in the Northern Section can be excluded with high probability as a hydro-engineering structure as well. Here, direct push colour logs, vibra-coring, 14C dating and the comparison with a historic map reveal evidence for a historic gravel road. Thus, we have nicely verified the magnetic information but have no prove for an artificial Carolingian water inlet from the Swabian Rezat River that contradicts with assumptions of former studies. © 2020 The Authors
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    Non-remote reference noise cancellation - using reference data in the presence of surface-NMR signals
    (Amsterdam [u.a.] : Elsevier Science, 2020) Müller-Petke, Mike
    Surface-NMR measurements commonly suffer from low signal-to-noise ratios. In recent years, with the introduction of multi-channel surface-NMR instruments, the technique of remote-reference noise cancellation (RNC) was developed and significantly improved the applicability of surface-NMR. The current formulation of RNC requires a reference loop to be placed a remote distance from the transmitter loop such that no NMR signal is recorded. Reference loops placed at non-remote distances have been envisaged to provide both improved noise cancellation performance and field efficiency; however, the concept has not been previously applied because the theoretical framework was missing. In this paper, the theoretical framework is presented. It is demonstrated that reference loops placed at non-remote distances provide superior noise cancellation performance. Considerations for placing the reference loop relative to the transmitter loop are provided, and the theoretical framework is evaluated based on a semi-synthetic example using real field noise and synthetic surface-NMR data. © 2020
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    Evaluation of spectral induced polarization field measurements in time and frequency domain
    (Amsterdam [u.a.] : Elsevier Science, 2020) Martin, Tina; Günther, Thomas; Orozco, Adrian Flores; Dahlin, Torleif
    Spectral induced polarization (SIP) measurements have been demonstrated to correlate with important parameters in hydrogeological and environmental investigations. Although SIP measurements were often collected in the frequency domain (FDIP), recent developments have demonstrated the capabilities to solve for the frequency-dependence of the complex conductivity through measurements collected in the time domain (TDIP). Therefore, the aim of our field investigations is a comparison of the measured frequency-dependence at a broad frequency range resolved through FDIP and TDIP. In contrast to previous studies, we conducted measurements with different instruments and measuring technologies for both FDIP and TDIP. This allows for investigating the robustness of different measurements and assessing various sources of errors, for the assessment of the advantages and drawbacks from different measuring techniques. Our results demonstrate that data collected through different instruments are consistent. Apparent resistivity measurements as well as the inversion results revealed quantitatively the same values for all instruments. The measurements of the IP effect are also comparable, particularly FDIP readings in the low frequencies (< 10 Hz) revealed to be quantitatively the same for different instruments. TDIP measurements are consistent for data collected with both devices. As expected, the spatial distribution of the values is also consistent for low frequency data (in FDIP) and late times measurements in TDIP (> 0.1 s). However, data quality for higher frequencies in FDIP (i.e., early times in TDIP) show larger variations, which reflects the differences between the instruments to deal with the electromagnetic contamination of the IP data. Concluded in general, the different instruments and measuring techniques can provide consistent responses for varying signal-to-noise ratio and measuring configurations. © 2020 The Authors