82 results
Search Results
Now showing 1 - 10 of 82
- ItemSonication-assisted liquid phase exfoliation of two-dimensional CrTe3 under inert conditions(Amsterdam [u.a.] : Elsevier Science, 2023) Synnatschke, Kevin; Moses Badlyan, Narine; Wrzesińska, Angelika; Lozano Onrubia, Guillermo; Hansen, Anna–Lena; Wolff, Stefan; Tornatzky, Hans; Bensch, Wolfgang; Vaynzof, Yana; Maultzsch, Janina; Backes, ClaudiaLiquid phase exfoliation (LPE) has been used for the successful fabrication of nanosheets from a large number of van der Waals materials. While this allows to study fundamental changes of material properties’ associated with reduced dimensions, it also changes the chemistry of many materials due to a significant increase of the effective surface area, often accompanied with enhanced reactivity and accelerated oxidation. To prevent material decomposition, LPE and processing in inert atmosphere have been developed, which enables the preparation of pristine nanomaterials, and to systematically study compositional changes over time for different storage conditions. Here, we demonstrate the inert exfoliation of the oxidation-sensitive van der Waals crystal, CrTe3. The pristine nanomaterial was purified and size-selected by centrifugation, nanosheet dimensions in the fractions quantified by atomic force microscopy and studied by Raman, X-ray photoelectron spectroscopy (XPS), energy-dispersive X-ray spectroscopy (EDX) and photo spectroscopic measurements. We find a dependence of the relative intensities of the CrTe3 Raman modes on the propagation direction of the incident light, which prevents a correlation of the Raman spectral profile to the nanosheet dimensions. XPS and EDX reveal that the contribution of surface oxides to the spectra is reduced after exfoliation compared to the bulk material. Further, the decomposition mechanism of the nanosheets was studied by time-dependent extinction measurements after water titration experiments to initially dry solvents, which suggest that water plays a significant role in the material decomposition.
- ItemThermal annealing to influence the vapor sensing behavior of co-continuous poly(lactic acid)/polystyrene/multiwalled carbon nanotube composites(Amsterdam [u.a.] : Elsevier Science, 2020) Li, Yilong; Pionteck, Jürgen; Pötschke, Petra; Voit, BrigitteWith the main purpose of being used as vapor leakage detector, the volatile organic compound (VOC) vapor sensing properties of conductive polymer blend composites were studied. Poly(lactic acid)/polystyrene/multi-walled carbon nanotube (PLA/PS/MWCNT) based conductive polymer composites (CPCs) in which the polymer components exhibit different interactions with the vapors, were prepared by melt mixing. CPCs with a blend composition of 50/50 wt% resulted in the finest co-continuous structure and selective MWCNT localization in PLA. Therefore, these composites were selected for sensor tests. Thermal annealing was applied aiming to maintain the blend structure but improving the sensing reversibility of CPC sensors towards high vapor concentrations. Different sensing protocols were applied using acetone (good solvent for PS and PLA) and cyclohexane (good solvent for PS but poor solvent for PLA) vapors. Increasing acetone vapor concentration resulted in increased relative resistance change (Rrel) of CPCs. Saturated cyclohexane vapor resulted in lower response than nearly saturated acetone vapor. The thermal annealing at 150 °C did not change the blend morphology but increased the PLA crystallinity, making the CPC sensors more resistant to vapor stimulation, resulting in lower Rrel but better reversibility after vapor exposure.
- ItemGround reaction forces and external hip joint moments predict in vivo hip contact forces during gait(Amsterdam [u.a.] : Elsevier Science, 2022) Alves, Sónia A.; Polzehl, Jörg; Brisson, Nicholas M.; Bender, Alwina; Agres, Alison N.; Damm, Philipp; Duda, Georg N.Younger patients increasingly receive total hip arthroplasty (THA) as therapy for end-stage osteoarthritis. To maintain the long-term success of THA in such patients, avoiding extremely high hip loads, i.e., in vivo hip contact force (HCF), is considered essential. However, in vivo HCFs are difficult to determine and their direct measurement is limited to instrumented joint implants. It remains unclear whether external measurements of ground reaction forces (GRFs), a non-invasive, markerless and clinic-friendly measure can estimate in vivo HCFs. Using data from eight patients with instrumented hip implants, this study determined whether GRF time series data, alone or combined with other scalar variables such as hip joint moments (HJMs) and lean muscle volume (LMV), could predict the resultant HCF (rHCF) impulse using a functional linear modeling approach. Overall, single GRF time series data did not predict in vivo rHCF impulses. However, when GRF time series data were combined with LMV of the gluteus medius or sagittal HJM using a functional linear modeling approach, the in vivo rHCF impulse could be predicted from external measures only. Accordingly, this approach can predict in vivo rHCF impulses, and thus provide patients with useful insight regarding their gait behavior to avoid hip joint overloading.
- ItemDesigning the microstructural constituents of an additively manufactured near β Ti alloy for an enhanced mechanical and corrosion response(Amsterdam [u.a.] : Elsevier Science, 2022) Hariharan, Avinash; Goldberg, Phil; Gustmann, Tobias; Maawad, Emad; Pilz, Stefan; Schell, Frederic; Kunze, Tim; Zwahr, Christoph; Gebert, AnnettAdditive manufacturing of near β-type Ti-13Nb-13Zr alloys using the laser powder bed fusion process (LPBF) opens up new avenues to tailor the microstructure and subsequent macro-scale properties that aids in developing new generation patient-specific, load-bearing orthopedic implants. In this work, we investigate a wide range of LPBF parameter space to optimize the volumetric energy density, surface characteristics and melt track widths to achieve a stable process and part density of greater than 99 %. Further, optimized sample states were achieved via thermal post-processing using standard capability aging, super-transus (900 °C) and sub-transus (660 °C) heat treatment strategies with varying quenching mediums (air, water and ice). The applied heat treatment strategies induce various fractions of α, martensite (α', α'') in combination with the β phase and strongly correlated with the observed enhanced mechanical properties and a relatively low elastic modulus. In summary, our work highlights a practical strategy for optimizing the mechanical and corrosion properties of a LPBF produced near β-type Ti-13Nb-13Zr alloy via careful evaluation of processing and post-processing steps and the interrelation to the corresponding microstructures. Corrosion studies revealed excellent corrosion resistances of the heat-treated LPBF samples comparable to wrought Ti-13Nb-13Zr alloys.
- ItemA new strategy to improve viscoelasticity, crystallization and mechanical properties of polylactide(Amsterdam [u.a.] : Elsevier Science, 2021) Huang, Ying; Müller, Michael Thomas; Boldt, Regine; Zschech, Carsten; Gohs, Uwe; Wießner, SvenBiodegradable polylactide/masticated natural rubber (PLA/mNR) blends were prepared by electron induced reactive processing (EIReP) without using any chemical additives. The PLA/mNR blends showed droplet-matrix morphology with decreased mNR particle size after EIReP treatment. The absolute value of complex viscosity and storage modulus increased significantly for the EIReP modified blends, suggesting the improved melt strength and elasticity. The crystallization investigation showed that the cold crystallization peak of PLA phase gradually disappeared after EIReP modification. Instead, the crystallization peak arose during melt cooling process. Consequently, the crystallinity of PLA phase increased from 6.2% to 39.0% as the mNR content increased from 0 to 20 wt%. It was found that the softening temperature of PLA examined by dynamic mechanical analysis increased effectively with the characters of higher modulus compared to the non-modified blends. The EIReP modified blends exhibited excellent mechanical properties with 7-fold increase of impact toughness compared with neat PLA, implying a superior interfacial adhesion and chain interactions between the two polymer phases. Furthermore, the thermogravimetric analysis demonstrated that the thermal stability was slightly enhanced for the EIReP modified blends.
- ItemSpecial issue on “Ultrasound-assisted engineering of materials for biomedical uses”(Amsterdam [u.a.] : Elsevier Science, 2022) Besford, Quinn A.; Cavalieri, Francesca[no abstract available]
- ItemLong term trends of mesopheric ice layers: A model study(Amsterdam [u.a.] : Elsevier Science, 2021) Lübken, Franz-Josef; Baumgarten, Gerd; Berger, UweTrends derived from the Leibniz-Institute Middle Atmosphere Model (LIMA) and the MIMAS ice particle model (Mesospheric Ice Microphysics And tranSport model) are presented for a period of 138 years (1871–2008) and for middle, high, and arctic latitudes, namely 58°N, 69°N, and 78°N, respectively. We focus on the analysis of mesospheric ice layers (NLC, noctilucent clouds) in the main summer season (July) and on yearly mean values. Model runs with and without an increase of carbon dioxide and water vapor (from methane oxidation) concentrations are performed. Trends are most prominent after ~1960 when the increase of both CO2 and H2O accelerates. It is important to distinguish between tendencies on geometric altitudes and on given pressure levels converted to altitudes (‘pressure altitudes’). Negative trends of (geometric) NLC altitudes are primarily due to cooling below NLC altitudes caused by CO2 increase. Increases of ice particle radii and NLC brightness with time are mainly caused by an enhancement of water vapor. Several ice layer and background parameter trends are similar at high and arctic latitudes but are substantially different at middle latitudes. This concerns, for example, occurrence rates, ice water content (IWC), and number of ice particles in a column. Considering the time period after 1960, geometric altitudes of NLC decrease by approximately 260 m per decade, and brightness increases by roughly 50% (1960–2008), independent of latitude. NLC altitudes decrease by approximately 15–20 m per increase of CO2 by 1 ppmv. The number of ice particles in a column and also at the altitude of maximum backscatter is nearly constant with time. At all latitudes, yearly mean NLC appear at altitudes where temperatures are close to 145±1 K. Ice particles are present nearly all the time at high and arctic latitudes, but are much less common at middle latitudes. Ice water content and maximum backscatter (βmax) are highly correlated, where the slope depends on latitude. This allows to combine data sets from satellites and lidars. Furthermore, IWC and the concentration of water vapor at βmax are also strongly correlated. Nearly all trends depend on a lower limit applied for βmax, e.g., IWC and occurrence rates. Results from LIMA/MIMAS are in very good agreement with observations.
- ItemLaser powder bed fusion of a superelastic Cu-Al-Mn shape memory alloy(Amsterdam [u.a.] : Elsevier Science, 2021) Babacan, N.; Pauly, S.; Gustmann, T.Dense and crack-free specimens of the shape memory alloy Cu71.6Al17Mn11.4 (at.%) were produced via laser powder bed fusion across a wide range of process parameters. The microstructure, viz. grain size, can be directly tailored within the process and with it the transformation temperatures (TTs) shifted to higher values by raising the energy input. The microstructure, and the superelastic behavior of additively manufactured samples were assessed by a detailed comparison with induction melted material. The precipitation of the α phase, which inhibit the martensitic transformation, were not observed in the additively manufactured samples owing to the high intrinsic cooling rates during the fabrication process. Fine columnar grains with a strong [001]-texture along the building direction lead to an enhanced yield strength compared to the coarse-grained cast samples. A maximum recoverable strain of 2.86% was observed after 5% compressive loading. The first results of our approach imply that laser powder bed fusion is a promising technique to directly produce individually designed Cu-Al-Mn shape memory parts with a pronounced superelasticity at room temperature.
- ItemMethods increasing inherent resistance of ECC designs against horizontal attacks(Amsterdam [u.a.] : Elsevier Science, 2020) Kabin, Ievgen; Dyka, Zoya; Klann, Dan; Langendoerfer, PeterDue to the nature of applications such as critical infrastructure and the Internet of Things etc. side channel analysis attacks are becoming a serious threat. Side channel analysis attacks take advantage from the fact that the behaviour of crypto implementations can be observed and provides hints that simplify revealing keys. A new type of SCA is the so called horizontal differential SCA. In this paper we investigate two different approaches to increase the inherent resistance of our hardware accelerator for the kP operation. The first approach aims at reducing the impact of the addressing in our design by realizing a regular schedule of the addressing. In the second approach, we investigated how the formula used to implement the multiplication of GF(2n)-elements influences the results of horizontal DPA attacks against a Montgomery kP-implementation. We implemented 5 designs with different partial multipliers, i.e. based on different multiplication formulae. We used two different technologies, i.e. a 130 and a 250 nm technology, to simulate power traces for our analysis. We show that the implemented multiplication formula influences the success of horizontal attacks significantly. The combination of these two approaches leads to the most resistant design. For the 250 nm technology only 2 key candidates could be revealed with a correctness of about 70% which is a huge improvement given the fact that for the original design 7 key candidates achieved a correctness of more than 90%. For our 130 nm technology no key candidate was revealed with a correctness of more than 60%.
- ItemBayesian approach for auroral oval reconstruction from ground-based observations(Amsterdam [u.a.] : Elsevier Science, 2022) Wagner, D.; Neuhäuser, R.; Arlt, R.Naked eye observations of aurorae might be used to obtain information on the large-scale magnetic field of the Earth at historic times. Their abundance may also help bridge gaps in observational time-series of proxies for solar activity such as the sunspot number or cosmogenic isotopes. With information derived from aurora observations like observing site, time of aurora sighting and position on the sky we can reconstruct the auroral oval. Since aurorae are correlated with geomagnetic indices like the Kp index, it is possible to obtain information about the terrestrial magnetic field in the form of the position of the magnetic poles as well as the magnetic disturbance level. Here we present a Bayesian approach to reconstruct the auroral oval from ground-based observations by using two different auroral oval models. With this method we can estimate the position of the magnetic poles in corrected geomagnetic coordinates as well as the Kp index. The method is first validated on synthetic observations before it is applied to four modern geomagnetic storms between 2003 and 2017 where ground-based reports and photographs were used to obtain the necessary information. Based on the four modern geomagnetic storms we have shown, that we are able to reconstruct the pole location with an average accuracy of ≈2° in latitude and ≈11° in longitude. The Kp index can be inferred with a precision of one class. The future goal is to employ the method to historical storms, where we expect somewhat higher uncertainties, since observations may be less accurate or not favorably distributed.