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- ItemCrystal structure of (2S,4S,7S)-7,7-dichloro-4-(1-chloro-1-methylethyl)-1- (2,2,2-trichloroethyl)bicyclo[4.1.0]heptane, C12H16Cl 6(Berlin : de Gruyter, 2009) Boualy, B.; el Firdoussi, L.; Ali, M.A.; Karim, A.; Spannenberg, A.C12H16Cl6, orthorhombic, P2 12121 (no. 19), a = 6.0742(3) Å, b = 9.7189(6) Å, c = 26.700(1) Å, V = 1576.2 Å3, Z = 4, Rgt(F) = 0.019, wRref(F2) = 0.045, T= 200 K. © by Oldenbourg Wissenschaftsverlag.
- ItemDifferentialgeometrie im Grossen (hybrid meeting)(Zürich : EMS Publ. House, 2021) Hamenstädt, Ursula; Lang, Urs; Weinkove, BenThe field of classical differential geometry has expanded enormously over the last several decades, helped by the development of tools from neighboring fields such as partial differential equations, complex analysis and geometric topology. In the spirit of the previous meetings in the series, this meeting will bring together researchers from apparently separate subfields of differential geometry, but whose work is linked by common themes. In particular, this meeting will emphasize intrinsic geometric questions motivated by the classification and rigidity of global geometric structures and the interaction of curvature with the underlying geometry and topology.
- ItemArbeitsgemeinschaft mit aktuellem Thema: Polylogarithms(Zürich : EMS Publ. House, 2004) Kings, Guido; Wildeshaus, Jörg[no abstract available]
- ItemEffects of (complementary) polyelectrolytes characteristics on composite calcium carbonate microparticles properties(Bucureşti : [Verlag nicht ermittelbar], 2017) Mic, Cristian Barbu; Mihai, Marcela; Varganici, Cristian Dragos; Schwarz, Simona; Scutaru, Dan; Simionescu, Bogdan C.This study follows the possibility to tune the thermal stability of some CaCO3/polymer composites by crystal growth from supersaturated solutions controlled by polymer structure or by using nonstoichiometric polyelectrolyte complexes (NPECs). As the ratio between the organic and inorganic parts in the composites controls the Ca2+/polymer network crosslinking density, the CaCO3/polymer weight ratio was kept constant at 50/1, varying the initial concentration of the polyanions solutions (0.05 or 0.06 wt.%), the NPECs molar ratio , n+/n- (0.2 or 0.4), or the inorganic precursors concentration (0.25 or 0.3 M). Poly(2-acrylamido-2-methylpropanesulfonic acid-co-acrylic acid) (PSA) and chondroitin-4-sulfate (CSA) were used as polyanions. Some NPEC dispersions, prepared with the same polyanions and poly(allylamine hydrochloride) (PAH), were also used for calcium carbonate crystallization. The characteristics of the prepared composites were investigated by scanning electron microscopy (SEM), flow particle image analysis (FPIA), particles charge density (CD), zeta-potential (ZP). The thermal stability of the composite particles was investigated as compared to bare CaCO3 microparticles prepared at the same initial inorganic concentrations.
- ItemA new bifunctional hybrid nanostructure as an active platform for photothermal therapy and MR imaging(London : Nature Publishing Group, 2016) Khafaji, Mona; Vossoughi, Manouchehr; Hormozi-Nezhad, M. Reza; Dinarvand, Rassoul; Börrnert, Felix; Irajizad, AzamAs a bi-functional cancer treatment agent, a new hybrid nanostructure is presented which can be used for photothermal therapy by exposure to one order of magnitude lower laser powers compared to similar nanostructures in addition to substantial enhancment in magnetic resonance imaging (MRI) contrast. This gold-iron oxide hybrid nanostructure (GIHN) is synthesized by a cost-effective and high yield water-based approach. The GIHN is sheilded by PEG. Therefore, it shows high hemo and biocompatibility and more than six month stability. Alongside earlier nanostructures, the heat generation rate of GIHN is compareable with surfactnat-capped gold nanorods (GNRs). Two reasons are behind this enhancement: Firstly the distance between GNRs and SPIONs is adjusted in a way that the surface plasmon resonance of the new nanostructure is similar to bare GNRs and secondly the fraction of GNRs is raised in the hybrid nanostructure. GIHN is then applied as a photothermal agent using laser irradiation with power as low as 0.5 W.cm−2 and only 32% of human breast adenocarcinoma cells could survive. The GIHN also acts as a dose-dependent transvers relaxation time (T2) MRI contrast agent. The results show that the GINH can be considered as a good candidate for multimodal photothermal therapy and MRI.
- ItemMechanisms of bonding effected by nanoparticles in zirconia coatings applied by spraying of suspensions(Saarbrücke : Leibniz-Institut für Neue Materialien, 2008) Adam, Jens; Aslan, Mesut; Drumm, Robert; Veith, MichaelZirconia coatings consisting of a mixture of coarse and fine grained zirconia powders prepared by spraying of suspensions and subsequent thermal treatment at limited temperatures (up to 500°C) are poor in adherence and in intrinsic mechanical strength. We have shown elsewhere that mechanical properties of these coatings can be improved clearly by adding a small amount of nanoscaled zirconia. Here, the structural and the chemical development of this coating material and of the nanoparticles is examined to gain information about the underlying bonding mechanisms. The applied temperature is relatively low in comparison to the usual onset temperature of accelerated sintering. Nevertheless, the results show that diffusion controlled material transport mechanisms play their role in bonding. The condensation of surface OH groups may participate in bonding, too. These first results confirm the potential of nanoparticles to act as inorganic binder. Additional research effort to clarify the underlying mechanisms in detail is of interest. For the practical side, it can be concluded that the resulting effect of mechanical consolidation of ceramic structures at relatively low temperatures enables new ceramic applications, for example a new type of ceramic coatings on metallic substrates.
- ItemDirect nitrous oxide emissions from oilseed rape cropping – a meta-analysis(Milton Park : Taylor & Francis, 2014) Walter, Katja; Don, Axel; Fuß, Roland; Kern, Jürgen; Drewer, Julia; Flessa, HeinzOilseed rape is one of the leading feedstocks for biofuel production in Europe. The climate change mitigation effect of rape methyl ester (RME) is particularly challenged by the greenhouse gas (GHG) emissions during crop production, mainly as nitrous oxide (N2O) from soils. Oilseed rape requires high nitrogen fertilization and crop residues are rich in nitrogen, both potentially causing enhanced N2O emissions. However, GHG emissions of oilseed rape production are often estimated using emission factors that account for crop-type specifics only with respect to crop residues. This meta-analysis therefore aimed to assess annual N2O emissions from winter oilseed rape, to compare them to those of cereals and to explore the underlying reasons for differences. For the identification of the most important factors, linear mixed effects models were fitted with 43 N2O emission data points deriving from 12 different field sites. N2O emissions increased exponentially with N-fertilization rates, but interyear and site-specific variability were high and climate variables or soil parameters did not improve the prediction model. Annual N2O emissions from winter oilseed rape were 22% higher than those from winter cereals fertilized at the same rate. At a common fertilization rate of 200 kg N ha−1 yr−1, the mean fraction of fertilizer N that was lost as N2O-N was 1.27% for oilseed rape compared to 1.04% for cereals. The risk of high yield-scaled N2O emissions increased after a critical N surplus of about 80 kg N ha−1 yr−1. The difference in N2O emissions between oilseed rape and cereal cultivation was especially high after harvest due to the high N contents in oilseed rape's crop residues. However, annual N2O emissions of winter oilseed rape were still lower than predicted by the Stehfest and Bouwman model. Hence, the assignment of oilseed rape to the crop-type classes of cereals or other crops should be reconsidered.
- ItemSimulation of the future sea level contribution of Greenland with a new glacial system model(Katlenburg-Lindau : Copernicus, 2018) Calov, Reinhard; Beyer, Sebastian; Greve, Ralf; Beckmann, Johanna; Willeit, Matteo; Kleiner, Thomas; Rückamp, Martin; Humbert, Angelika; Ganopolski, AndreyWe introduce the coupled model of the Greenland glacial system IGLOO 1.0, including the polythermal ice sheet model SICOPOLIS (version 3.3) with hybrid dynamics, the model of basal hydrology HYDRO and a parameterization of submarine melt for marine-terminated outlet glaciers. The aim of this glacial system model is to gain a better understanding of the processes important for the future contribution of the Greenland ice sheet to sea level rise under future climate change scenarios. The ice sheet is initialized via a relaxation towards observed surface elevation, imposing the palaeo-surface temperature over the last glacial cycle. As a present-day reference, we use the 1961-1990 standard climatology derived from simulations of the regional atmosphere model MAR with ERA reanalysis boundary conditions. For the palaeo-part of the spin-up, we add the temperature anomaly derived from the GRIP ice core to the years 1961-1990 average surface temperature field. For our projections, we apply surface temperature and surface mass balance anomalies derived from RCP 4.5 and RCP 8.5 scenarios created by MAR with boundary conditions from simulations with three CMIP5 models. The hybrid ice sheet model is fully coupled with the model of basal hydrology. With this model and the MAR scenarios, we perform simulations to estimate the contribution of the Greenland ice sheet to future sea level rise until the end of the 21st and 23rd centuries. Further on, the impact of elevation-surface mass balance feedback, introduced via the MAR data, on future sea level rise is inspected. In our projections, we found the Greenland ice sheet to contribute between 1.9 and 13.0 cm to global sea level rise until the year 2100 and between 3.5 and 76.4 cm until the year 2300, including our simulated additional sea level rise due to elevation-surface mass balance feedback. Translated into additional sea level rise, the strength of this feedback in the year 2100 varies from 0.4 to 1.7 cm, and in the year 2300 it ranges from 1.7 to 21.8 cm. Additionally, taking the Helheim and Store glaciers as examples, we investigate the role of ocean warming and surface runoff change for the melting of outlet glaciers. It shows that ocean temperature and subglacial discharge are about equally important for the melting of the examined outlet glaciers.
- ItemInferring causation from time series in Earth system sciences([London] : Nature Publishing Group UK, 2019) Runge, Jakob; Bathiany, Sebastian; Bollt, Erik; Camps-Valls, Gustau; Coumou, Dim; Deyle, Ethan; Glymour, Clark; Kretschmer, Marlene; Mahecha, Miguel D.; Muñoz-Marí, Jordi; van Nes, Egbert H.; Peters, Jonas; Quax, Rick; Reichstein, Markus; Scheffer, Marten; Schölkopf, Bernhard; Spirtes, Peter; Sugihara, George; Sun, Jie; Zhang, Kun; Zscheischler, JakobThe heart of the scientific enterprise is a rational effort to understand the causes behind the phenomena we observe. In large-scale complex dynamical systems such as the Earth system, real experiments are rarely feasible. However, a rapidly increasing amount of observational and simulated data opens up the use of novel data-driven causal methods beyond the commonly adopted correlation techniques. Here, we give an overview of causal inference frameworks and identify promising generic application cases common in Earth system sciences and beyond. We discuss challenges and initiate the benchmark platform causeme.net to close the gap between method users and developers. © 2019, The Author(s).
- ItemThermoelectric Properties of N-Type Poly (Ether Ether Ketone)/Carbon Nanofiber Melt-Processed Composites(Basel : MDPI, 2022) Paleo, Antonio Jose; Krause, Beate; Soares, Delfim; Melle-Franco, Manuel; Muñoz, Enrique; Pötschke, Petra; Rocha, Ana MariaThe thermoelectric properties, at temperatures from 30 °C to 100 °C, of melt-processed poly(ether ether ketone) (PEEK) composites prepared with 10 wt.% of carbon nanofibers (CNFs) are discussed in this work. At 30 °C, the PEEK/CNF composites show an electrical conductivity (σ) of ~27 S m−1 and a Seebeck coefficient (S) of −3.4 μV K−1, which means that their majority charge carriers are electrons. The origin of this negative Seebeck is deduced because of the impurities present in the as-received CNFs, which may cause sharply varying and localized states at approximately 0.086 eV above the Fermi energy level (EF) of CNFs. Moreover, the lower S, in absolute value, found in PEEK/CNF composites, when compared with the S of as-received CNFs (−5.3 μV K−1), is attributed to a slight electron withdrawing from the external layers of CNFs by the PEEK matrix. At temperatures from 30 °C to 100 °C, the σ (T) of PEEK/CNF composites, in contrast to the σ (T) of as-received CNFs, shows a negative temperature effect, understood through the 3D variable-range hopping (VRH) model, as a thermally activated hopping mechanism across a random network of potential wells. Moreover, their nonlinear S (T) follows the same behavior reported before for polypropylene composites melt-processed with similar CNFs at the same interval of temperatures.