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- ItemValorising agro-industrial wastes within the circular bioeconomy concept: The case of defatted rice bran with emphasis on bioconversion strategies(Basel : MDPI AG, 2020) Alexandri, Maria; López-Gómez, José Pablo; Olszewska-Widdrat, Agata; Venus, JoachimThe numerous environmental problems caused by the extensive use of fossil resources have led to the formation of the circular bioeconomy concept. Renewable resources will constitute the cornerstone of this new, sustainable model, with biomass presenting a huge potential for the production of fuels and chemicals. In this context, waste and by-product streams from the food industry will be treated not as "wastes" but as resources. Rice production generates various by-product streams which currently are highly unexploited, leading to environmental problems especially in the countries that are the main producers. The main by-product streams include the straw, the husks, and the rice bran. Among these streams, rice bran finds applications in the food industry and cosmetics, mainly due to its high oil content. The high demand for rice bran oil generates huge amounts of defatted rice bran (DRB), the main by-product of the oil extraction process. The sustainable utilisation of this by-product has been a topic of research, either as a food additive or via its bioconversion into value-added products and chemicals. This review describes all the processes involved in the efficient bioconversion of DRB into biotechnological products. The detailed description of the production process, yields and productivities, as well as strains used for the production of bioethanol, lactic acid and biobutanol, among others, are discussed. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.
- ItemImpacts of meeting minimum access on critical earth systems amidst the Great Inequality(London : Springer Nature, 2022) Rammelt, Crelis F.; Gupta, Joyeeta; Liverman, Diana; Scholtens, Joeri; Ciobanu, Daniel; Abrams, Jesse F.; Bai, Xuemei; Gifford, Lauren; Gordon, Christopher; Hurlbert, Margot; Inoue, Cristina Y. A.; Jacobson, Lisa; Lade, Steven J.; Lenton, Timothy M.; McKay, David I. Armstrong; Nakicenovic, Nebojsa; Okereke, Chukwumerije; Otto, Ilona M.; Pereira, Laura M.; Prodani, Klaudia; Rockström, Johan; Stewart-Koster, Ben; Verburg, Peter H.; Zimm, CarolineThe Sustainable Development Goals aim to improve access to resources and services, reduce environmental degradation, eradicate poverty and reduce inequality. However, the magnitude of the environmental burden that would arise from meeting the needs of the poorest is under debate—especially when compared to much larger burdens from the rich. We show that the ‘Great Acceleration’ of human impacts was characterized by a ‘Great Inequality’ in using and damaging the environment. We then operationalize ‘just access’ to minimum energy, water, food and infrastructure. We show that achieving just access in 2018, with existing inequalities, technologies and behaviours, would have produced 2–26% additional impacts on the Earth’s natural systems of climate, water, land and nutrients—thus further crossing planetary boundaries. These hypothetical impacts, caused by about a third of humanity, equalled those caused by the wealthiest 1–4%. Technological and behavioural changes thus far, while important, did not deliver just access within a stable Earth system. Achieving these goals therefore calls for a radical redistribution of resources.
- ItemOvercoming global inequality is critical for land-based mitigation in line with the Paris Agreement([London] : Nature Publishing Group UK, 2022) Humpenöder, Florian; Popp, Alexander; Schleussner, Carl-Friedrich; Orlov, Anton; Windisch, Michael Gregory; Menke, Inga; Pongratz, Julia; Havermann, Felix; Thiery, Wim; Luo, Fei; v. Jeetze, Patrick; Dietrich, Jan Philipp; Lotze-Campen, Hermann; Weindl, Isabelle; Lejeune, QuentinTransformation pathways for the land sector in line with the Paris Agreement depend on the assumption of globally implemented greenhouse gas (GHG) emission pricing, and in some cases also on inclusive socio-economic development and sustainable land-use practices. In such pathways, the majority of GHG emission reductions in the land system is expected to come from low- and middle-income countries, which currently account for a large share of emissions from agriculture, forestry and other land use (AFOLU). However, in low- and middle-income countries the economic, financial and institutional barriers for such transformative changes are high. Here, we show that if sustainable development in the land sector remained highly unequal and limited to high-income countries only, global AFOLU emissions would remain substantial throughout the 21st century. Our model-based projections highlight that overcoming global inequality is critical for land-based mitigation in line with the Paris Agreement. While also a scenario purely based on either global GHG emission pricing or on inclusive socio-economic development would achieve the stringent emissions reductions required, only the latter ensures major co-benefits for other Sustainable Development Goals, especially in low- and middle-income regions.
- ItemEfficient Synthesis of Novel Plasticizers by Direct Palladium-Catalyzed Di- or Multi-carbonylations(Weinheim : Wiley-VCH, 2022) Hu, Yuya; Sang, Rui; Vroemans, Robby; Mollaert, Guillaume; Razzaq, Rauf; Neumann, Helfried; Junge, Henrik; Franke, Robert; Jackstell, Ralf; Maes, Bert U. W.; Beller, MatthiasDiesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium-catalyzed direct carbonylation of di- or polyols with readily available alkenes. Key-to-success is the use of a specific palladium catalyst with the “built-in-base” ligand L16 providing esterification of all alcohols and a high n/iso ratio. The synthesized diesters were evaluated as potential plasticizers in PVC films by measuring the glass transition temperature (Tg) via differential scanning calorimetry (DSC).
- ItemElectrohydrodynamic drying versus conventional drying methods: A comparison of key performance indicators(Amsterdam [u.a.] : Elsevier Science, 2023) Iranshahi, Kamran; Rubinetti, Donato; Onwude, Daniel I.; Psarianos, Marios; Schlüter, Oliver K.; Defraeye, ThijsPreserving fruits and vegetables by drying is a traditional yet effective way of reducing food waste. Existing drying methods are either energy-intensive or lead to a significant reduction in product quality. Electrohydrodynamic (EHD) drying is an energy-efficient low-temperature drying method that presents an opportunity to comply with the current challenges of existing drying methods. However, despite its promising characteristics, EHD drying is yet to be accepted by industry and farmers. The adoption of EHD drying is hindered due to different reasons, such as uncertainties surrounding its scalability, quality of dried product, cost of operation, and sustainability compared to conventional drying methods. To address these concerns, this study quantifies and benchmarks the Key Performance Indicators (KPIs) of EHD drying compared to the standard conventional drying methods based on lab-scale experiments. These drying methods include hot-air, freeze, microwave, and solar drying. The results show that drying food using EHD is at least 1.6, 20, and 70 times more energy-efficient than the microwave, freeze, and hot-air, respectively. Similar results could be observed for exergy efficiency. EHD drying has superior product quality compared to other drying methods. For instance, it could retain 62% higher total phenolic content with 21% less color degradation than freeze-drying. Although microwave drying resulted in significantly higher drying kinetics than other techniques, EHD performed better than solar and freeze-drying but was comparable with hot-air drying. EHD drying also shows promising results in economic performance assessment. It is the cheapest drying method after solar drying and has the highest estimated net present value (NPV) after hot-air drying. Overall, compared to the currently used drying methods for small to medium-scale drying, EHD was found to be a more exergy and energy-efficient, cost-effective, and sustainable alternative that can provide higher-quality dried products. However, its drying kinetics should be improved for industrial applications.
- ItemJanus particles: from concepts to environmentally friendly materials and sustainable applications(Berlin ; Heidelberg : Springer, 2020) Marschelke, Claudia; Fery, Andreas; Synytska, AllaJanus particles represent a unique group of patchy particles combining two or more different physical or chemical functionalities at their opposite sides. Especially, individual Janus particles (JPs) with both chemical and geometrical anisotropy as well as their assembled layers provide considerable advantages over the conventional monofunctional particles or surfactant molecules offering (a) a high surface-to-volume ratio; (b) high interfacial activity; (c) target controlling and manipulation of their interfacial activity by external signals such as temperature, light, pH, or ionic strength and achieving switching between stable emulsions and macro-phase separation; (d) recovery and recycling; (e) controlling the mass transport across the interface between the two phases; and finally (f) tunable several functionalities in one particle allowing their use either as carrier materials for immobilized catalytically active substances or, alternatively, their site-selective attachment to substrates keeping another functionality active for further reactions. All these advantages of JPs make them exclusive materials for application in (bio-)catalysis and (bio-)sensing. Considering “green chemistry” aspects covering biogenic materials based on either natural or fully synthetic biocompatible and biodegradable polymers for the design of JPs may solve the problem of toxicity of some existing materials and open new paths for the development of more environmentally friendly and sustainable materials in the very near future. Considering the number of contributions published each year on the topic of Janus particles in general, the number of contributions regarding their environmentally friendly and sustainable applications is by far smaller. This certainly pinpoints an important challenge and is addressed in this review article. The first part of the review focuses on the synthesis of sustainable biogenic or biocompatible Janus particles, as well as strategies for their recovery, recycling, and reusability. The second part addresses recent advances in applications of biogenic/biocompatible and non-biocompatible JPs in environmental and biotechnological fields such as sensing of hazardous pollutants, water decontamination, and hydrogen production. Finally, we provide implications for the rational design of environmentally friendly and sustainable materials based on Janus particles. [Figure not available: see fulltext.]. © 2020, The Author(s).
- ItemLivWell: a sub-national Dataset on the Living Conditions of Women and their Well-being for 52 Countries(London : Nature Publ. Group, 2022) Belmin, Camille; Hoffmann, Roman; Elkasabi, Mahmoud; Pichler, Peter-PaulData on women’s living conditions and socio-economic development are important for understanding and addressing the pronounced challenges and inequalities faced by women worldwide. While such information is increasingly available at the national level, comparable data at the sub-national level are missing. We here present the LivWell global longitudinal dataset, which includes a set of key indicators on women’s socio-economic status, health and well-being, access to basic services and demographic outcomes. It covers 447 regions in 52 countries and includes a total of 265 different indicators. The majority of these are based on 199 Demographic and Health Surveys (DHS) for the period 1990–2019 and are complemented by extensive information on socio-economic and climatic conditions in the respective regions. The resulting dataset offers various opportunities for policy-relevant research on gender inequality, inclusive development and demographic trends at the sub-national level.
- ItemEvaluating Three-Pillar Sustainability Modelling Approaches for Dairy Cattle Production Systems(Basel : MDPI, 2021) Díaz de Otálora, Xabier; del Prado, Agustín; Dragoni, Federico; Estellés, Fernando; Amon, BarbaraMilk production in Europe is facing major challenges to ensure its economic, environmental, and social sustainability. It is essential that holistic concepts are developed to ensure the future sustainability of the sector and to assist farmers and stakeholders in making knowledge-based decisions. In this study, integrated sustainability assessment by means of whole-farm modelling is presented as a valuable approach for identifying factors and mechanisms that could be used to improve the three pillars (3Ps) of sustainability in the context of an increasing awareness of economic profitability, social well-being, and environmental impacts of dairy production systems (DPS). This work aims (i) to create an evaluation framework that enables quantitative analysis of the level of integration of 3P sustainability indicators in whole-farm models and (ii) to test this method. Therefore, an evaluation framework consisting of 35 indicators distributed across the 3Ps of sustainability was used to evaluate three whole-farm models. Overall, the models integrated at least 40% of the proposed indicators. Different results were obtained for each sustainability pillar by each evaluated model. Higher scores were obtained for the environmental pillar, followed by the economic and the social pillars. In conclusion, this evaluation framework was found to be an effective tool that allows potential users to choose among whole-farm models depending on their needs. Pathways for further model development that may be used to integrate the 3P sustainability assessment of DPS in a more complete and detailed way were identified.
- ItemFrom Transfer to Knowledge Co-Production: A Transdisciplinary Research Approach to Reduce Black Carbon Emissions in Metro Manila, Philippines(Basel : MDPI, 2020) Tõnisson, Liina; Kunz, Yvonne; Kecorius, Simonas; Madueño, Leizel; Tamayo, Everlyn Gayle; Casanova, Dang Marviluz; Zhao, Qi; Schikowski, Tamara; Hornidge, Anna-Katharina; Wiedensohler, Alfred; Macke, AndreasAir pollution, which kills an estimated 7 million people every year, is one of the greatest environmental health risks of our times. Finding solutions to this threat poses challenges to practitioners and policymakers alike. Increasing awareness on the benefits of transdisciplinary research in solution-oriented sustainable development projects has led to the establishment of the research project “A Transdisciplinary Approach to Mitigate Emissions of Black Carbon” (TAME-BC). This paper introduces the TAME-BC research setup that took place with Metro Manila, Philippines, case study. The approach integrates BC measurements with technological, socio-political, and health aspects to improve the scientific state of the art, policymaking, transport sector planning, and clinical studies related to air pollution health effects. The first pillar in the setup presents an (1) air quality assessment through aerosol measurements and instrumentation, complemented by a (2) description and assessment of the current policies, technologies, and practices of the transport sector that is responsible for pollution levels in the Philippines, as well as a (3) BC exposure and associated health impacts assessment. The fourth pillar is intercrossing, fostering (4) knowledge co-creation through stakeholder involvement across scales. We argue that this transdisciplinary approach is useful for research endeavors aiming for emission mitigation in rapidly urbanizing regions beyond Metro Manila.
- ItemEthical Artificial Intelligence in Chemical Research and Development: A Dual Advantage for Sustainability(Dordrecht : Springer Netherlands, 2021) Hermann, Erik; Hermann, Gunter; Tremblay, Jean-ChristopheArtificial intelligence can be a game changer to address the global challenge of humanity-threatening climate change by fostering sustainable development. Since chemical research and development lay the foundation for innovative products and solutions, this study presents a novel chemical research and development process backed with artificial intelligence and guiding ethical principles to account for both process- and outcome-related sustainability. Particularly in ethically salient contexts, ethical principles have to accompany research and development powered by artificial intelligence to promote social and environmental good and sustainability (beneficence) while preventing any harm (non-maleficence) for all stakeholders (i.e., companies, individuals, society at large) affected.