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    Ion dynamics in Al-Stabilized Li7La3Zr2O12 single crystals – Macroscopic transport and the elementary steps of ion hopping
    (Amsterdam : Elsevier, 2020) Posch, Patrick; Lunghammer, Sarah; Berendts, Stefan; Ganschow, Steffen; Redhammer, Günther J.; Wilkening, Alexandra; Lerch, Martin; Gadermaier, Bernhard; Rettenwander, Daniel; Wilkening, H. Martin R.
    Li7La3Zr2O12 (LLZO) garnet-type ceramics are considered as very promising candidates for solid electrolytes and have been extensively studied in the past few years. Several studies report on an increase in ionic conductivity by doping with ions, such as Al3+ and Ga3+, to stabilize the cubic modification of LLZO. Unfortunately, so far ion dynamics have mainly been studied using powdered samples. Such studies may suffer from chemical heterogeneities concerning Al distribution. Here, we took advantage of Al-stabilized LLZO single crystals to throw light on the elementary steps of ion hopping. We used 7Li nuclear magnetic resonance (NMR) spin-lattice relaxation measurements and conductivity spectroscopy to probe dynamic parameters from both a microscopic and macroscopic point of view. At 293 K the total conductivity turned out to be 0.082 mS cm−1, which is remarkably good for LLZO exhibiting an Al-content of only 0.37 wt%. Most importantly, 7Li NMR spin-lock transients revealed two overlapping diffusion-induced processes. Overall, activation energies from spin-lock NMR excellently agree with that from conductivity measurements; both techniques yield values around 0.36 eV. The corresponding diffusion coefficients deduced from NMR and conductivity measurements almost coincide. The magnetic spin fluctuations sensed by NMR provide an in-depth look at the elementary jump processes, which can barely be revealed by macroscopic impedance spectroscopy providing average values. In particular, we were able to precisely measure the local hopping barrier (0.20 eV) characterizing forward-backward jumps between the sites 24d and 96h. © 2019 The Author(s)
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    Challenges of data availability: Analysing the water-energy nexus in electricity generation
    (Amsterdam [u.a.] : Elsevier, 2019) Larsen, M.A.D.; Petrovic, S.; Engström, R.E.; Drews, M.; Liersch, S.; Karlsson, K.B.; Howells, M.
    Water is paramount for the operation of energy systems, for securing food supply and for the industry and municipalities. Intersectoral competition for water resources can negatively affect water scarce regions by e.g. power plants shutdowns, poor agricultural yields, and lack of potable water. Future economic and population growth as well as climate change is likely to exacerbate these patterns. However, models used for energy system management and planning in general do not properly include water availability which can lead to improper representations of water-energy interlinkages. The paper initially highlights the water usage rates of current technologies within electricity generation and technologies with a potential to reduce water usage, electricity consumption or GHG emissions. Secondly, the paper presents currently available data on current and future projected water resources as well as data on energy statistics relevant to water-energy nexus studies. Thirdly, implementation cases are presented showing examples of water-energy nexus studies for the data presented. Finally, the paper highlights main challenges in studying the linkage between water and energy. We find a substantial gap in the general availability and quality of regional and global data for detailed quantitative analyses and also identify a need for standardization of formats and data collection methodologies across data and disciplines. An effort towards a coordinated, and sustained open-access data framework with energy sector water usage at fine spatio-temporal scales alongside hydro-climatic observation and model data using common forcings and scenarios for future projections (of climate, socio-economy and technology) is therefore recommended for future water-energy nexus studies. © 2019 The Authors
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    Energy system changes in 1.5 °C, well below 2 °C and 2 °C scenarios
    (Amsterdam : Elsevier, 2019) Gambhir, Ajay; Rogelj, Joeri; Luderer, Gunnar; Few, Sheridan; Napp, Tamaryn
    Meeting the Paris Agreement's goal to limit global warming to well below 2 °C and pursuing efforts towards 1.5 °C is likely to require more rapid and fundamental energy system changes than the previously-agreed 2 °C target. Here we assess over 200 integrated assessment model scenarios which achieve 2 °C and well-below 2 °C targets, drawn from the IPCC's fifth assessment report database combined with a set of 1.5 °C scenarios produced in recent years. We specifically assess differences in a range of near-term indicators describing CO2 emissions reductions pathways, changes in primary energy and final energy across the economy's major sectors, in addition to more detailed metrics around the use of carbon capture and storage (CCS), negative emissions, low-carbon electricity and hydrogen. © 2018 The Authors